Selective and reusable iron(II)-based molecular sensor for the vapor-phase detection of alcohols

Anil D. Naik; Koen Robeyns; Christophe F. Meunier; Alexandre F. Léonard; Aurelian Rotaru; Bernard Tinant; Yaroslav Filinchuk; Bao Lian Su; Yann Garcia

doi:10.1021/ic402816a

Selective and reusable iron(II)-based molecular sensor for the vapor-phase detection of alcohols

Anil D. Naik, Koen Robeyns, Christophe F. Meunier, Alexandre F. Léonard, Aurelian Rotaru, Bernard Tinant, Yaroslav Filinchuk, Bao Lian Su, Yann Garcia

Unite de recherche en chimie des nanomateriaux

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

A mononuclear iron(II) neutral complex (1) is screened for sensing abilities for a wide spectrum of chemicals and to evaluate the response function toward physical perturbation like temperature and mechanical stress. Interestingly, 1 precisely detects methanol among an alcohol series. The sensing process is visually detectable, fatigue-resistant, highly selective, and reusable. The sensing ability is attributed to molecular sieving and subsequent spin-state change of iron centers, after a crystal-to-crystal transformation.

langue originale	Anglais
Pages (de - à)	1263-1265
Nombre de pages	3
journal	Inorganic Chemistry
Volume	53
Numéro de publication	3
Les DOIs	https://doi.org/10.1021/ic402816a
Etat de la publication	Publié - 3 févr. 2014

Accès au document

10.1021/ic402816a

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CCDC 913252: Experimental Crystal Structure Determination
Filinchuk, Y. (Contributeur), Garcia, Y. (Contributeur), Leonard, A. (Contributeur), Meunier, C. (Contributeur), Naik, A. D. (Contributeur), Robeyns, K. (Contributeur), Rotaru, A. (Contributeur), SU, B. L. (Contributeur) & Tinant, B. (Contributeur), Cambridge Crystallographic Data Centre, 1 janv. 2014
DOI: 10.5517/cczn9rn, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cczn9rn&sid=DataCite
Ensemble de données

Contient cette citation

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title = "Selective and reusable iron(II)-based molecular sensor for the vapor-phase detection of alcohols",

abstract = "A mononuclear iron(II) neutral complex (1) is screened for sensing abilities for a wide spectrum of chemicals and to evaluate the response function toward physical perturbation like temperature and mechanical stress. Interestingly, 1 precisely detects methanol among an alcohol series. The sensing process is visually detectable, fatigue-resistant, highly selective, and reusable. The sensing ability is attributed to molecular sieving and subsequent spin-state change of iron centers, after a crystal-to-crystal transformation.",

author = "Naik, {Anil D.} and Koen Robeyns and Meunier, {Christophe F.} and L{\'e}onard, {Alexandre F.} and Aurelian Rotaru and Bernard Tinant and Yaroslav Filinchuk and Su, {Bao Lian} and Yann Garcia",

year = "2014",

month = feb,

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doi = "10.1021/ic402816a",

language = "English",

volume = "53",

pages = "1263--1265",

journal = "Inorganic Chemistry",

issn = "0020-1669",

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T1 - Selective and reusable iron(II)-based molecular sensor for the vapor-phase detection of alcohols

AU - Naik, Anil D.

AU - Robeyns, Koen

AU - Meunier, Christophe F.

AU - Léonard, Alexandre F.

AU - Rotaru, Aurelian

AU - Tinant, Bernard

AU - Filinchuk, Yaroslav

AU - Su, Bao Lian

AU - Garcia, Yann

PY - 2014/2/3

Y1 - 2014/2/3

N2 - A mononuclear iron(II) neutral complex (1) is screened for sensing abilities for a wide spectrum of chemicals and to evaluate the response function toward physical perturbation like temperature and mechanical stress. Interestingly, 1 precisely detects methanol among an alcohol series. The sensing process is visually detectable, fatigue-resistant, highly selective, and reusable. The sensing ability is attributed to molecular sieving and subsequent spin-state change of iron centers, after a crystal-to-crystal transformation.

AB - A mononuclear iron(II) neutral complex (1) is screened for sensing abilities for a wide spectrum of chemicals and to evaluate the response function toward physical perturbation like temperature and mechanical stress. Interestingly, 1 precisely detects methanol among an alcohol series. The sensing process is visually detectable, fatigue-resistant, highly selective, and reusable. The sensing ability is attributed to molecular sieving and subsequent spin-state change of iron centers, after a crystal-to-crystal transformation.

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U2 - 10.1021/ic402816a

DO - 10.1021/ic402816a

M3 - Article

AN - SCOPUS:84893339780

SN - 0020-1669

VL - 53

SP - 1263

EP - 1265

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 3

ER -

Selective and reusable iron(II)-based molecular sensor for the vapor-phase detection of alcohols

Résumé

Accès au document

Autres fichiers et liens

Empreinte digitale

Équipement

Physico-chimie et caractérisation (PC2)

Ensembles de données

CCDC 913252: Experimental Crystal Structure Determination

Contient cette citation