Selective and reusable iron(II)-based molecular sensor for the vapor-phase detection of alcohols

Anil D. Naik; Koen Robeyns; Christophe F. Meunier; Alexandre F. Léonard; Aurelian Rotaru; Bernard Tinant; Yaroslav Filinchuk; Bao Lian Su; Yann Garcia

doi:10.1021/ic402816a

Selective and reusable iron(II)-based molecular sensor for the vapor-phase detection of alcohols

Anil D. Naik, Koen Robeyns, Christophe F. Meunier, Alexandre F. Léonard, Aurelian Rotaru, Bernard Tinant, Yaroslav Filinchuk, Bao Lian Su, Yann Garcia

Unit of nanomaterials chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A mononuclear iron(II) neutral complex (1) is screened for sensing abilities for a wide spectrum of chemicals and to evaluate the response function toward physical perturbation like temperature and mechanical stress. Interestingly, 1 precisely detects methanol among an alcohol series. The sensing process is visually detectable, fatigue-resistant, highly selective, and reusable. The sensing ability is attributed to molecular sieving and subsequent spin-state change of iron centers, after a crystal-to-crystal transformation.

Original language	English
Pages (from-to)	1263-1265
Number of pages	3
Journal	Inorganic Chemistry
Volume	53
Issue number	3
DOIs	https://doi.org/10.1021/ic402816a
Publication status	Published - 3 Feb 2014

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10.1021/ic402816a

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title = "Selective and reusable iron(II)-based molecular sensor for the vapor-phase detection of alcohols",

abstract = "A mononuclear iron(II) neutral complex (1) is screened for sensing abilities for a wide spectrum of chemicals and to evaluate the response function toward physical perturbation like temperature and mechanical stress. Interestingly, 1 precisely detects methanol among an alcohol series. The sensing process is visually detectable, fatigue-resistant, highly selective, and reusable. The sensing ability is attributed to molecular sieving and subsequent spin-state change of iron centers, after a crystal-to-crystal transformation.",

author = "Naik, {Anil D.} and Koen Robeyns and Meunier, {Christophe F.} and L{\'e}onard, {Alexandre F.} and Aurelian Rotaru and Bernard Tinant and Yaroslav Filinchuk and Su, {Bao Lian} and Yann Garcia",

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T1 - Selective and reusable iron(II)-based molecular sensor for the vapor-phase detection of alcohols

AU - Naik, Anil D.

AU - Robeyns, Koen

AU - Meunier, Christophe F.

AU - Léonard, Alexandre F.

AU - Rotaru, Aurelian

AU - Tinant, Bernard

AU - Filinchuk, Yaroslav

AU - Su, Bao Lian

AU - Garcia, Yann

PY - 2014/2/3

Y1 - 2014/2/3

N2 - A mononuclear iron(II) neutral complex (1) is screened for sensing abilities for a wide spectrum of chemicals and to evaluate the response function toward physical perturbation like temperature and mechanical stress. Interestingly, 1 precisely detects methanol among an alcohol series. The sensing process is visually detectable, fatigue-resistant, highly selective, and reusable. The sensing ability is attributed to molecular sieving and subsequent spin-state change of iron centers, after a crystal-to-crystal transformation.

AB - A mononuclear iron(II) neutral complex (1) is screened for sensing abilities for a wide spectrum of chemicals and to evaluate the response function toward physical perturbation like temperature and mechanical stress. Interestingly, 1 precisely detects methanol among an alcohol series. The sensing process is visually detectable, fatigue-resistant, highly selective, and reusable. The sensing ability is attributed to molecular sieving and subsequent spin-state change of iron centers, after a crystal-to-crystal transformation.

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U2 - 10.1021/ic402816a

DO - 10.1021/ic402816a

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JF - Inorganic Chemistry

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ER -

Selective and reusable iron(II)-based molecular sensor for the vapor-phase detection of alcohols

Abstract

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Physical Chemistry and characterization(PC2)

CCDC 913252: Experimental Crystal Structure Determination

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Selective and reusable iron(II)-based molecular sensor for the vapor-phase detection of alcohols

Abstract

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Fingerprint

Equipment

Physical Chemistry and characterization(PC2)

Datasets

CCDC 913252: Experimental Crystal Structure Determination

Cite this