Polymer-Supported Bis-1,2,4-triazolium Ionic Tag Framework for an Efficient Pd(0) Catalytic System in Biomass Derived γ-Valerolactone

Federica Valentini; Hamed Mahmoudi; Lucia Anna Bivona; Oriana Piermatti; Mojtaba Bagherzadeh; Luca Fusaro; Carmela Aprile; Assunta Marrocchi; Luigi Vaccaro

doi:10.1021/acssuschemeng.8b06502

Polymer-Supported Bis-1,2,4-triazolium Ionic Tag Framework for an Efficient Pd(0) Catalytic System in Biomass Derived γ-Valerolactone

Federica Valentini, Hamed Mahmoudi, Lucia Anna Bivona, Oriana Piermatti, Mojtaba Bagherzadeh, Luca Fusaro, Carmela Aprile, Assunta Marrocchi, Luigi Vaccaro

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

A resin-bound 1,2,4-triazolium ionic tag has been used as support for the preparation of solid palladium nanoparticles (Pd(0)-POLI-TAG-Pd). Owing to the pincer-type architecture of the triazolium ligand, the stabilization of a high amount of palladium nanoparticles (16 wt %) has been possible. The catalytic system has been fully characterized and used in low amounts (i.e., 0.1 mol % palladium loading) in representative Heck-Mizoroki cross-coupling processes. A negligible release of the metal was demonstrated, and a high activity was obtained over more runs. Besides, the protocol has been optimized for the use of safe biomass-derived γ-valerolactone reaction medium.

langue originale	Anglais
Pages (de - à)	6939-6946
Nombre de pages	8
journal	ACS Sustainable Chemistry and Engineering
Volume	7
Numéro de publication	7
Les DOIs	https://doi.org/10.1021/acssuschemeng.8b06502
Etat de la publication	Publié - 1 avr. 2019

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10.1021/acssuschemeng.8b06502

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Valentini, F., Mahmoudi, H., Bivona, L. A., Piermatti, O., Bagherzadeh, M., Fusaro, L., Aprile, C., Marrocchi, A., & Vaccaro, L. (2019). Polymer-Supported Bis-1,2,4-triazolium Ionic Tag Framework for an Efficient Pd(0) Catalytic System in Biomass Derived γ-Valerolactone. ACS Sustainable Chemistry and Engineering, 7(7), 6939-6946. https://doi.org/10.1021/acssuschemeng.8b06502

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title = "Polymer-Supported Bis-1,2,4-triazolium Ionic Tag Framework for an Efficient Pd(0) Catalytic System in Biomass Derived γ-Valerolactone",

abstract = "A resin-bound 1,2,4-triazolium ionic tag has been used as support for the preparation of solid palladium nanoparticles (Pd(0)-POLI-TAG-Pd). Owing to the pincer-type architecture of the triazolium ligand, the stabilization of a high amount of palladium nanoparticles (16 wt %) has been possible. The catalytic system has been fully characterized and used in low amounts (i.e., 0.1 mol % palladium loading) in representative Heck-Mizoroki cross-coupling processes. A negligible release of the metal was demonstrated, and a high activity was obtained over more runs. Besides, the protocol has been optimized for the use of safe biomass-derived γ-valerolactone reaction medium.",

keywords = "Cross-coupling, Green solvents, Heterogeneous catalysis, Polymeric supports",

author = "Federica Valentini and Hamed Mahmoudi and Bivona, {Lucia Anna} and Oriana Piermatti and Mojtaba Bagherzadeh and Luca Fusaro and Carmela Aprile and Assunta Marrocchi and Luigi Vaccaro",

year = "2019",

month = apr,

day = "1",

doi = "10.1021/acssuschemeng.8b06502",

language = "English",

volume = "7",

pages = "6939--6946",

journal = "ACS Sustainable Chemistry and Engineering",

issn = "2168-0485",

publisher = "American Chemical Society",

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Valentini, F, Mahmoudi, H, Bivona, LA, Piermatti, O, Bagherzadeh, M, Fusaro, L , Aprile, C, Marrocchi, A & Vaccaro, L 2019, 'Polymer-Supported Bis-1,2,4-triazolium Ionic Tag Framework for an Efficient Pd(0) Catalytic System in Biomass Derived γ-Valerolactone', ACS Sustainable Chemistry and Engineering, VOL. 7, Numéro 7, p. 6939-6946. https://doi.org/10.1021/acssuschemeng.8b06502

Polymer-Supported Bis-1,2,4-triazolium Ionic Tag Framework for an Efficient Pd(0) Catalytic System in Biomass Derived γ-Valerolactone. / Valentini, Federica; Mahmoudi, Hamed; Bivona, Lucia Anna et al.
Dans: ACS Sustainable Chemistry and Engineering, Vol 7, Numéro 7, 01.04.2019, p. 6939-6946.

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

TY - JOUR

T1 - Polymer-Supported Bis-1,2,4-triazolium Ionic Tag Framework for an Efficient Pd(0) Catalytic System in Biomass Derived γ-Valerolactone

AU - Valentini, Federica

AU - Mahmoudi, Hamed

AU - Bivona, Lucia Anna

AU - Piermatti, Oriana

AU - Bagherzadeh, Mojtaba

AU - Fusaro, Luca

AU - Aprile, Carmela

AU - Marrocchi, Assunta

AU - Vaccaro, Luigi

PY - 2019/4/1

Y1 - 2019/4/1

N2 - A resin-bound 1,2,4-triazolium ionic tag has been used as support for the preparation of solid palladium nanoparticles (Pd(0)-POLI-TAG-Pd). Owing to the pincer-type architecture of the triazolium ligand, the stabilization of a high amount of palladium nanoparticles (16 wt %) has been possible. The catalytic system has been fully characterized and used in low amounts (i.e., 0.1 mol % palladium loading) in representative Heck-Mizoroki cross-coupling processes. A negligible release of the metal was demonstrated, and a high activity was obtained over more runs. Besides, the protocol has been optimized for the use of safe biomass-derived γ-valerolactone reaction medium.

AB - A resin-bound 1,2,4-triazolium ionic tag has been used as support for the preparation of solid palladium nanoparticles (Pd(0)-POLI-TAG-Pd). Owing to the pincer-type architecture of the triazolium ligand, the stabilization of a high amount of palladium nanoparticles (16 wt %) has been possible. The catalytic system has been fully characterized and used in low amounts (i.e., 0.1 mol % palladium loading) in representative Heck-Mizoroki cross-coupling processes. A negligible release of the metal was demonstrated, and a high activity was obtained over more runs. Besides, the protocol has been optimized for the use of safe biomass-derived γ-valerolactone reaction medium.

KW - Cross-coupling

KW - Green solvents

KW - Heterogeneous catalysis

KW - Polymeric supports

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ER -

Polymer-Supported Bis-1,2,4-triazolium Ionic Tag Framework for an Efficient Pd(0) Catalytic System in Biomass Derived γ-Valerolactone

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