Corroles as receptors in liquid membrane electrodes and their potentiometric response towards salicylic acid

Jerzy Radecki; Iwona Stenka; Eduard Dolusic; Wim Dehaen

doi:10.1016/j.electacta.2005.02.152

Corroles as receptors in liquid membrane electrodes and their potentiometric response towards salicylic acid

Jerzy Radecki, Iwona Stenka, Eduard Dolusic, Wim Dehaen

Namur Research Institute for Life Sciences

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

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Résumé

Here, we report on the application of corroles as analytically active compounds in liquid membrane electrodes (ISE) that are sensitive towards salicylic acid and salicylate. The potentiometric signals generated by corrole-incorporated ISEs strongly depend on the pH of the aqueous sample solution and the membrane composition, such as the presence of lipophilic sites. Corrole incorporating ISEs are characterised by a low detection limit (4.0×10minus5 M) and a wide linear range (4.0×10minus5 to 5.3×10minus3 M). Also, they are free from interference versus other organic anions. The mechanism of the generation of the potentiometric signals of corrole incorporating ISEs in the presence of salicylate anion, as well salicylic acid, will be discussed.

langue originale	Anglais
Pages (de - à)	2282-2288
Nombre de pages	7
journal	Electrochimica Acta
Volume	51
Numéro de publication	11
Les DOIs	https://doi.org/10.1016/j.electacta.2005.02.152
Etat de la publication	Publié - 2006

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10.1016/j.electacta.2005.02.152

1 s2Version finale publiée, 255 KB

http://www.sciencedirect.com/science/article/pii/S001346860500856X

29 Citations
5 Article
3 Poster

Determination of interaction strength between corrole and phenol derivatives in aqueous media using atomic force microscopy
Szymanska, I., Dolusic, E., Dehaen, W., Maes, W., Ito, T. & Radecka, H., 2009, Dans: Supramolecular Chemistry. 21, 7, p. 555-563 9 p.
Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs
Gold Electrode Incorporating Corrole as an Ion-Channel Mimetic Sensor for Determination of Dopamine
Kurzatkowska, K., Dolusic, E., Dehaen, W., Sieron-Stoltny, K., Sieron, A. & Radecka, H., 2009, Dans: Analytical Chemistry. 81, 17, p. 7397-7405 9 p.
Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs
Efficient synthesis of aryldipyrromethanes in water and their application in the synthesis of corroles and dipyrromethenes
Rohand, T., Dolusic, E., Ngo, T. H., Maes, W. & Dehaen, W., 2007, Dans: ARKIVOC. 2007, x, p. 307-324 18 p.
Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

1 Participation à une conférence, un congrès

XXVIII International Symposium on Macrocyclic Chemistry
Eduard Dolusic (Poster)
13 juil. 2003 → 18 juil. 2003
Activité: Participation ou organisation d'un événement › Participation à une conférence, un congrès

PhD in organic chemistry Katholieke Universiteit Leuven, Belgium, 2000 - 2004 (Prof. Wim Dehaen)
Auteur: Dolusic, E., 2004
Student thesis: Doc types › Docteur en Sciences

Contient cette citation

@article{98bc24662e1b4d6ebf550cfe92ddf6cb,

title = "Corroles as receptors in liquid membrane electrodes and their potentiometric response towards salicylic acid",

abstract = "Here, we report on the application of corroles as analytically active compounds in liquid membrane electrodes (ISE) that are sensitive towards salicylic acid and salicylate. The potentiometric signals generated by corrole-incorporated ISEs strongly depend on the pH of the aqueous sample solution and the membrane composition, such as the presence of lipophilic sites. Corrole incorporating ISEs are characterised by a low detection limit (4.0×10minus5 M) and a wide linear range (4.0×10minus5 to 5.3×10minus3 M). Also, they are free from interference versus other organic anions. The mechanism of the generation of the potentiometric signals of corrole incorporating ISEs in the presence of salicylate anion, as well salicylic acid, will be discussed.",

keywords = " Potentiometric response, Salicylic acid, Liquid membrane, Corroles",

author = "Jerzy Radecki and Iwona Stenka and Eduard Dolusic and Wim Dehaen",

year = "2006",

doi = "10.1016/j.electacta.2005.02.152",

language = "English",

volume = "51",

pages = "2282--2288",

journal = "Electrochimica Acta",

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TY - JOUR

T1 - Corroles as receptors in liquid membrane electrodes and their potentiometric response towards salicylic acid

AU - Radecki, Jerzy

AU - Stenka, Iwona

AU - Dolusic, Eduard

AU - Dehaen, Wim

PY - 2006

Y1 - 2006

N2 - Here, we report on the application of corroles as analytically active compounds in liquid membrane electrodes (ISE) that are sensitive towards salicylic acid and salicylate. The potentiometric signals generated by corrole-incorporated ISEs strongly depend on the pH of the aqueous sample solution and the membrane composition, such as the presence of lipophilic sites. Corrole incorporating ISEs are characterised by a low detection limit (4.0×10minus5 M) and a wide linear range (4.0×10minus5 to 5.3×10minus3 M). Also, they are free from interference versus other organic anions. The mechanism of the generation of the potentiometric signals of corrole incorporating ISEs in the presence of salicylate anion, as well salicylic acid, will be discussed.

AB - Here, we report on the application of corroles as analytically active compounds in liquid membrane electrodes (ISE) that are sensitive towards salicylic acid and salicylate. The potentiometric signals generated by corrole-incorporated ISEs strongly depend on the pH of the aqueous sample solution and the membrane composition, such as the presence of lipophilic sites. Corrole incorporating ISEs are characterised by a low detection limit (4.0×10minus5 M) and a wide linear range (4.0×10minus5 to 5.3×10minus3 M). Also, they are free from interference versus other organic anions. The mechanism of the generation of the potentiometric signals of corrole incorporating ISEs in the presence of salicylate anion, as well salicylic acid, will be discussed.

KW - Potentiometric response

KW - Salicylic acid

KW - Liquid membrane

KW - Corroles

U2 - 10.1016/j.electacta.2005.02.152

DO - 10.1016/j.electacta.2005.02.152

M3 - Article

VL - 51

SP - 2282

EP - 2288

JO - Electrochimica Acta

JF - Electrochimica Acta

IS - 11

ER -

Corroles as receptors in liquid membrane electrodes and their potentiometric response towards salicylic acid

Résumé

Accès au document

Empreinte digitale

Résultat de recherche

Determination of interaction strength between corrole and phenol derivatives in aqueous media using atomic force microscopy

Gold Electrode Incorporating Corrole as an Ion-Channel Mimetic Sensor for Determination of Dopamine

Efficient synthesis of aryldipyrromethanes in water and their application in the synthesis of corroles and dipyrromethenes

Activités

XXVIII International Symposium on Macrocyclic Chemistry

Thèses de l'étudiant

PhD in organic chemistry Katholieke Universiteit Leuven, Belgium, 2000 - 2004 (Prof. Wim Dehaen)

Contient cette citation