Research output per year
Research output per year
Abstract
Here, we report on the application of corroles as analytically active compounds in liquid membrane electrodes (ISE) that are sensitive
towards salicylic acid and salicylate.
The potentiometric signals generated by corrole-incorporated ISEs strongly depend on the pH of the aqueous sample solution and the
membrane composition, such as the presence of lipophilic sites. Corrole incorporating ISEs are characterised by a low detection limit
(4.0×10minus5 M) and a wide linear range (4.0×10minus5 to 5.3×10minus3 M). Also, they are free from interference versus other organic anions.
The mechanism of the generation of the potentiometric signals of corrole incorporating ISEs in the presence of salicylate anion, as well
salicylic acid, will be discussed.
| Original language | English |
|---|---|
| Pages (from-to) | 2282-2288 |
| Number of pages | 7 |
| Journal | Electrochimica Acta |
| Volume | 51 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - 2006 |
Keywords
- Potentiometric response
- Salicylic acid
- Liquid membrane
- Corroles
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Determination of interaction strength between corrole and phenol derivatives in aqueous media using atomic force microscopy
Szymanska, I., Dolusic, E., Dehaen, W., Maes, W., Ito, T. & Radecka, H., 2009, In: Supramolecular Chemistry. 21, 7, p. 555-563 9 p.Research output: Contribution to journal › Article › peer-review
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Gold Electrode Incorporating Corrole as an Ion-Channel Mimetic Sensor for Determination of Dopamine
Kurzatkowska, K., Dolusic, E., Dehaen, W., Sieron-Stoltny, K., Sieron, A. & Radecka, H., 2009, In: Analytical Chemistry. 81, 17, p. 7397-7405 9 p.Research output: Contribution to journal › Article › peer-review
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Efficient synthesis of aryldipyrromethanes in water and their application in the synthesis of corroles and dipyrromethenes
Rohand, T., Dolusic, E., Ngo, T. H., Maes, W. & Dehaen, W., 2007, In: ARKIVOC. 2007, x, p. 307-324 18 p.Research output: Contribution to journal › Article › peer-review
Activities
- 1 Participation in conference
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XXVIII International Symposium on Macrocyclic Chemistry
Eduard Dolusic (Poster)
13 Jul 2003 → 18 Jul 2003Activity: Participating in or organising an event types › Participation in conference
Student theses
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PhD in organic chemistry Katholieke Universiteit Leuven, Belgium, 2000 - 2004 (Prof. Wim Dehaen)
Author: Dolusic, E., 2004Student thesis: Doc types › Doctor of Sciences