Anomalous coarsening driven by reversible charge transfer at metal-organic interfaces

Ada Della Pia, Massimo Riello, Andrea Floris, Daphne Stassen, Tim S. Jones, Davide Bonifazi, Alessandro De Vita, Giovanni Costantini

Résultats de recherche: Contribution à un journal/une revueArticle

Résumé

The unique electronic properties and functional tunability of polycyclic aromatic hydrocarbons have recently fostered high hopes for their use in flexible, green, portable, and cheap technologies. Most applications require the deposition of thin molecular films onto conductive electrodes. The growth of the first few molecular layers represents a crucial step in the device fabrication since it determines the structure of the molecular film and the energy level alignment of the metal-organic interface. Here, we explore the formation of this interface by analyzing the interplay between reversible molecule-substrate charge transfer, yielding intermolecular repulsion, and van der Waals attractions in driving the molecular assembly. Using a series of ad hoc designed molecules to balance the two effects, we combine scanning tunnelling microscopy with atomistic simulations to study the self-Assembly behavior. Our systematic analysis identifies a growth mode characterized by anomalous coarsening that we anticipate to occur in a wide class of metal-organic interfaces and which should thus be considered as integral part of the self-Assembly process when depositing a molecule on a conducting surface.

langue originaleAnglais
Pages (de - à)12356-12364
Nombre de pages9
journalACS nano
Volume8
Numéro de publication12
Les DOIs
étatPublié - 23 déc. 2014

Empreinte digitale

Coarsening
Charge transfer
Metals
charge transfer
Self assembly
Molecules
self assembly
metals
molecules
Conductive films
Polycyclic Aromatic Hydrocarbons
Scanning tunneling microscopy
polycyclic aromatic hydrocarbons
Polycyclic aromatic hydrocarbons
Electronic properties
Electron energy levels
attraction
scanning tunneling microscopy
assembly
energy levels

Citer ceci

Della Pia, A., Riello, M., Floris, A., Stassen, D., Jones, T. S., Bonifazi, D., ... Costantini, G. (2014). Anomalous coarsening driven by reversible charge transfer at metal-organic interfaces. ACS nano, 8(12), 12356-12364. https://doi.org/10.1021/nn505063w
Della Pia, Ada ; Riello, Massimo ; Floris, Andrea ; Stassen, Daphne ; Jones, Tim S. ; Bonifazi, Davide ; De Vita, Alessandro ; Costantini, Giovanni. / Anomalous coarsening driven by reversible charge transfer at metal-organic interfaces. Dans: ACS nano. 2014 ; Vol 8, Numéro 12. p. 12356-12364.
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Della Pia, A, Riello, M, Floris, A, Stassen, D, Jones, TS, Bonifazi, D, De Vita, A & Costantini, G 2014, 'Anomalous coarsening driven by reversible charge transfer at metal-organic interfaces', ACS nano, VOL. 8, Numéro 12, p. 12356-12364. https://doi.org/10.1021/nn505063w

Anomalous coarsening driven by reversible charge transfer at metal-organic interfaces. / Della Pia, Ada; Riello, Massimo; Floris, Andrea; Stassen, Daphne; Jones, Tim S.; Bonifazi, Davide; De Vita, Alessandro; Costantini, Giovanni.

Dans: ACS nano, Vol 8, Numéro 12, 23.12.2014, p. 12356-12364.

Résultats de recherche: Contribution à un journal/une revueArticle

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AU - Della Pia, Ada

AU - Riello, Massimo

AU - Floris, Andrea

AU - Stassen, Daphne

AU - Jones, Tim S.

AU - Bonifazi, Davide

AU - De Vita, Alessandro

AU - Costantini, Giovanni

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AB - The unique electronic properties and functional tunability of polycyclic aromatic hydrocarbons have recently fostered high hopes for their use in flexible, green, portable, and cheap technologies. Most applications require the deposition of thin molecular films onto conductive electrodes. The growth of the first few molecular layers represents a crucial step in the device fabrication since it determines the structure of the molecular film and the energy level alignment of the metal-organic interface. Here, we explore the formation of this interface by analyzing the interplay between reversible molecule-substrate charge transfer, yielding intermolecular repulsion, and van der Waals attractions in driving the molecular assembly. Using a series of ad hoc designed molecules to balance the two effects, we combine scanning tunnelling microscopy with atomistic simulations to study the self-Assembly behavior. Our systematic analysis identifies a growth mode characterized by anomalous coarsening that we anticipate to occur in a wide class of metal-organic interfaces and which should thus be considered as integral part of the self-Assembly process when depositing a molecule on a conducting surface.

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