Résumé
In the present work we report on the investigation of the nonlinear optical properties of some newly synthesized [60]fullerene-porphyrin dyads exhibiting important charge-transfer character by means of the Z-scan technique employing 532 nm laser pulses from a 4 ns Q-switched Nd:YAG laser. The third-order susceptibility (χ(3)) and the second hyperpolarizability (γ) values of the studied derivatives have been determined. The present results have shown a significant enhancement of the nonlinear optical properties of [60]fullerene-porphyrin complexes compared to the unfunctionalized [C 60]fullerene due to the formation of charge transfer intermediates.
| langue originale | Anglais |
|---|---|
| titre | AIP Conference Proceedings |
| Pages | 188-191 |
| Nombre de pages | 4 |
| Volume | 1288 |
| Les DOIs | |
| état | Publié - 2010 |
| Evénement | International Commission for Optics (ICO), Topical Meeting on "Emerging Trends and Novel Materials in Photonics", ICO-Photonics-Delphi2009 - Delphi, Grèce Durée: 7 oct. 2009 → 9 oct. 2009 |
Une conférence
| Une conférence | International Commission for Optics (ICO), Topical Meeting on "Emerging Trends and Novel Materials in Photonics", ICO-Photonics-Delphi2009 |
|---|---|
| Pays | Grèce |
| La ville | Delphi |
| période | 7/10/09 → 9/10/09 |
Empreinte digitale
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The effect of charge transfer on the NLO response of some porphyrin-[60]fullerene dyads. / Filidou, V.; Chatzikyriakos, G.; Iliopoulos, K.; Couris, S.; Bonifazi, D.
AIP Conference Proceedings. Vol 1288 2010. p. 188-191.Résultats de recherche: Contribution dans un livre/un catalogue/un rapport/dans les actes d'une conférence › Article dans les actes d'une conférence/un colloque
TY - GEN
T1 - The effect of charge transfer on the NLO response of some porphyrin-[60]fullerene dyads
AU - Filidou, V.
AU - Chatzikyriakos, G.
AU - Iliopoulos, K.
AU - Couris, S.
AU - Bonifazi, D.
PY - 2010
Y1 - 2010
N2 - In the present work we report on the investigation of the nonlinear optical properties of some newly synthesized [60]fullerene-porphyrin dyads exhibiting important charge-transfer character by means of the Z-scan technique employing 532 nm laser pulses from a 4 ns Q-switched Nd:YAG laser. The third-order susceptibility (χ(3)) and the second hyperpolarizability (γ) values of the studied derivatives have been determined. The present results have shown a significant enhancement of the nonlinear optical properties of [60]fullerene-porphyrin complexes compared to the unfunctionalized [C 60]fullerene due to the formation of charge transfer intermediates.
AB - In the present work we report on the investigation of the nonlinear optical properties of some newly synthesized [60]fullerene-porphyrin dyads exhibiting important charge-transfer character by means of the Z-scan technique employing 532 nm laser pulses from a 4 ns Q-switched Nd:YAG laser. The third-order susceptibility (χ(3)) and the second hyperpolarizability (γ) values of the studied derivatives have been determined. The present results have shown a significant enhancement of the nonlinear optical properties of [60]fullerene-porphyrin complexes compared to the unfunctionalized [C 60]fullerene due to the formation of charge transfer intermediates.
KW - C
KW - Charge transfer
KW - Fullerene-porphyrin dyads
KW - Fullerenes
KW - Nonlinear optical properties
KW - Porphyrin
UR - http://www.scopus.com/inward/record.url?scp=78651061796&partnerID=8YFLogxK
U2 - 10.1063/1.3521356
DO - 10.1063/1.3521356
M3 - Conference contribution
AN - SCOPUS:78651061796
SN - 9780735408432
VL - 1288
SP - 188
EP - 191
BT - AIP Conference Proceedings
ER -