The effect of charge transfer on the NLO response of some porphyrin-[60]fullerene dyads

V. Filidou; G. Chatzikyriakos; K. Iliopoulos; S. Couris; D. Bonifazi

doi:10.1063/1.3521356

The effect of charge transfer on the NLO response of some porphyrin-[60]fullerene dyads

V. Filidou, G. Chatzikyriakos, K. Iliopoulos, S. Couris, D. Bonifazi

Résultats de recherche: Contribution dans un livre/un catalogue/un rapport/dans les actes d'une conférence › Article dans les actes d'une conférence/un colloque

Résumé

In the present work we report on the investigation of the nonlinear optical properties of some newly synthesized [60]fullerene-porphyrin dyads exhibiting important charge-transfer character by means of the Z-scan technique employing 532 nm laser pulses from a 4 ns Q-switched Nd:YAG laser. The third-order susceptibility (χ⁽³⁾) and the second hyperpolarizability (γ) values of the studied derivatives have been determined. The present results have shown a significant enhancement of the nonlinear optical properties of [60]fullerene-porphyrin complexes compared to the unfunctionalized [C ₆₀]fullerene due to the formation of charge transfer intermediates.

langue originale	Anglais
titre	AIP Conference Proceedings
Pages	188-191
Nombre de pages	4
Volume	1288
Les DOIs	https://doi.org/10.1063/1.3521356
Etat de la publication	Publié - 2010
Evénement	International Commission for Optics (ICO), Topical Meeting on "Emerging Trends and Novel Materials in Photonics", ICO-Photonics-Delphi2009 - Delphi, Grèce Durée: 7 oct. 2009 → 9 oct. 2009

Une conférence

Une conférence	International Commission for Optics (ICO), Topical Meeting on "Emerging Trends and Novel Materials in Photonics", ICO-Photonics-Delphi2009
Pays	Grèce
La ville	Delphi
période	7/10/09 → 9/10/09

Accès au document

10.1063/1.3521356

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Contient cette citation

@inproceedings{5c7c7c98d2d34bbabe50743436f8f5e3,

title = "The effect of charge transfer on the NLO response of some porphyrin-[60]fullerene dyads",

abstract = "In the present work we report on the investigation of the nonlinear optical properties of some newly synthesized [60]fullerene-porphyrin dyads exhibiting important charge-transfer character by means of the Z-scan technique employing 532 nm laser pulses from a 4 ns Q-switched Nd:YAG laser. The third-order susceptibility (χ(3)) and the second hyperpolarizability (γ) values of the studied derivatives have been determined. The present results have shown a significant enhancement of the nonlinear optical properties of [60]fullerene-porphyrin complexes compared to the unfunctionalized [C 60]fullerene due to the formation of charge transfer intermediates.",

keywords = "C, Charge transfer, Fullerene-porphyrin dyads, Fullerenes, Nonlinear optical properties, Porphyrin",

author = "V. Filidou and G. Chatzikyriakos and K. Iliopoulos and S. Couris and D. Bonifazi",

year = "2010",

doi = "10.1063/1.3521356",

language = "English",

isbn = "9780735408432",

volume = "1288",

pages = "188--191",

booktitle = "AIP Conference Proceedings",

note = "International Commission for Optics (ICO), Topical Meeting on {"}Emerging Trends and Novel Materials in Photonics{"}, ICO-Photonics-Delphi2009 ; Conference date: 07-10-2009 Through 09-10-2009",

}

Filidou, V, Chatzikyriakos, G, Iliopoulos, K, Couris, S & Bonifazi, D 2010, The effect of charge transfer on the NLO response of some porphyrin-[60]fullerene dyads. Dans AIP Conference Proceedings. VOL. 1288, p. 188-191, International Commission for Optics (ICO), Topical Meeting on "Emerging Trends and Novel Materials in Photonics", ICO-Photonics-Delphi2009, Delphi, Grèce, 7/10/09. https://doi.org/10.1063/1.3521356

The effect of charge transfer on the NLO response of some porphyrin-[60]fullerene dyads. / Filidou, V.; Chatzikyriakos, G.; Iliopoulos, K.; Couris, S.; Bonifazi, D.

AIP Conference Proceedings. Vol 1288 2010. p. 188-191.

Résultats de recherche: Contribution dans un livre/un catalogue/un rapport/dans les actes d'une conférence › Article dans les actes d'une conférence/un colloque

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AU - Iliopoulos, K.

AU - Couris, S.

AU - Bonifazi, D.

PY - 2010

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N2 - In the present work we report on the investigation of the nonlinear optical properties of some newly synthesized [60]fullerene-porphyrin dyads exhibiting important charge-transfer character by means of the Z-scan technique employing 532 nm laser pulses from a 4 ns Q-switched Nd:YAG laser. The third-order susceptibility (χ(3)) and the second hyperpolarizability (γ) values of the studied derivatives have been determined. The present results have shown a significant enhancement of the nonlinear optical properties of [60]fullerene-porphyrin complexes compared to the unfunctionalized [C 60]fullerene due to the formation of charge transfer intermediates.

AB - In the present work we report on the investigation of the nonlinear optical properties of some newly synthesized [60]fullerene-porphyrin dyads exhibiting important charge-transfer character by means of the Z-scan technique employing 532 nm laser pulses from a 4 ns Q-switched Nd:YAG laser. The third-order susceptibility (χ(3)) and the second hyperpolarizability (γ) values of the studied derivatives have been determined. The present results have shown a significant enhancement of the nonlinear optical properties of [60]fullerene-porphyrin complexes compared to the unfunctionalized [C 60]fullerene due to the formation of charge transfer intermediates.

KW - C

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