The effect of charge transfer on the NLO response of some porphyrin-[60]fullerene dyads

V. Filidou; G. Chatzikyriakos; K. Iliopoulos; S. Couris; D. Bonifazi

doi:10.1063/1.3521356

The effect of charge transfer on the NLO response of some porphyrin-[60]fullerene dyads

V. Filidou, G. Chatzikyriakos, K. Iliopoulos, S. Couris, D. Bonifazi

Research output: Contribution in Book/Catalog/Report/Conference proceeding › Conference contribution

Abstract

In the present work we report on the investigation of the nonlinear optical properties of some newly synthesized [60]fullerene-porphyrin dyads exhibiting important charge-transfer character by means of the Z-scan technique employing 532 nm laser pulses from a 4 ns Q-switched Nd:YAG laser. The third-order susceptibility (χ⁽³⁾) and the second hyperpolarizability (γ) values of the studied derivatives have been determined. The present results have shown a significant enhancement of the nonlinear optical properties of [60]fullerene-porphyrin complexes compared to the unfunctionalized [C ₆₀]fullerene due to the formation of charge transfer intermediates.

Original language	English
Title of host publication	AIP Conference Proceedings
Pages	188-191
Number of pages	4
Volume	1288
DOIs	https://doi.org/10.1063/1.3521356
Publication status	Published - 2010
Event	International Commission for Optics (ICO), Topical Meeting on "Emerging Trends and Novel Materials in Photonics", ICO-Photonics-Delphi2009 - Delphi, Greece Duration: 7 Oct 2009 → 9 Oct 2009

Conference

Conference	International Commission for Optics (ICO), Topical Meeting on "Emerging Trends and Novel Materials in Photonics", ICO-Photonics-Delphi2009
Country/Territory	Greece
City	Delphi
Period	7/10/09 → 9/10/09

Keywords

C
Charge transfer
Fullerene-porphyrin dyads
Fullerenes
Nonlinear optical properties
Porphyrin

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10.1063/1.3521356

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title = "The effect of charge transfer on the NLO response of some porphyrin-[60]fullerene dyads",

abstract = "In the present work we report on the investigation of the nonlinear optical properties of some newly synthesized [60]fullerene-porphyrin dyads exhibiting important charge-transfer character by means of the Z-scan technique employing 532 nm laser pulses from a 4 ns Q-switched Nd:YAG laser. The third-order susceptibility (χ(3)) and the second hyperpolarizability (γ) values of the studied derivatives have been determined. The present results have shown a significant enhancement of the nonlinear optical properties of [60]fullerene-porphyrin complexes compared to the unfunctionalized [C 60]fullerene due to the formation of charge transfer intermediates.",

keywords = "C, Charge transfer, Fullerene-porphyrin dyads, Fullerenes, Nonlinear optical properties, Porphyrin",

author = "V. Filidou and G. Chatzikyriakos and K. Iliopoulos and S. Couris and D. Bonifazi",

year = "2010",

doi = "10.1063/1.3521356",

language = "English",

isbn = "9780735408432",

volume = "1288",

pages = "188--191",

booktitle = "AIP Conference Proceedings",

note = "International Commission for Optics (ICO), Topical Meeting on {"}Emerging Trends and Novel Materials in Photonics{"}, ICO-Photonics-Delphi2009 ; Conference date: 07-10-2009 Through 09-10-2009",

}

Filidou, V, Chatzikyriakos, G, Iliopoulos, K, Couris, S & Bonifazi, D 2010, The effect of charge transfer on the NLO response of some porphyrin-[60]fullerene dyads. in AIP Conference Proceedings. vol. 1288, pp. 188-191, International Commission for Optics (ICO), Topical Meeting on "Emerging Trends and Novel Materials in Photonics", ICO-Photonics-Delphi2009, Delphi, Greece, 7/10/09. https://doi.org/10.1063/1.3521356

TY - GEN

T1 - The effect of charge transfer on the NLO response of some porphyrin-[60]fullerene dyads

AU - Filidou, V.

AU - Chatzikyriakos, G.

AU - Iliopoulos, K.

AU - Couris, S.

AU - Bonifazi, D.

PY - 2010

Y1 - 2010

N2 - In the present work we report on the investigation of the nonlinear optical properties of some newly synthesized [60]fullerene-porphyrin dyads exhibiting important charge-transfer character by means of the Z-scan technique employing 532 nm laser pulses from a 4 ns Q-switched Nd:YAG laser. The third-order susceptibility (χ(3)) and the second hyperpolarizability (γ) values of the studied derivatives have been determined. The present results have shown a significant enhancement of the nonlinear optical properties of [60]fullerene-porphyrin complexes compared to the unfunctionalized [C 60]fullerene due to the formation of charge transfer intermediates.

AB - In the present work we report on the investigation of the nonlinear optical properties of some newly synthesized [60]fullerene-porphyrin dyads exhibiting important charge-transfer character by means of the Z-scan technique employing 532 nm laser pulses from a 4 ns Q-switched Nd:YAG laser. The third-order susceptibility (χ(3)) and the second hyperpolarizability (γ) values of the studied derivatives have been determined. The present results have shown a significant enhancement of the nonlinear optical properties of [60]fullerene-porphyrin complexes compared to the unfunctionalized [C 60]fullerene due to the formation of charge transfer intermediates.

KW - C

KW - Charge transfer

KW - Fullerene-porphyrin dyads

KW - Fullerenes

KW - Nonlinear optical properties

KW - Porphyrin

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U2 - 10.1063/1.3521356

DO - 10.1063/1.3521356

M3 - Conference contribution

AN - SCOPUS:78651061796

SN - 9780735408432

VL - 1288

SP - 188

EP - 191

BT - AIP Conference Proceedings

T2 - International Commission for Optics (ICO), Topical Meeting on "Emerging Trends and Novel Materials in Photonics", ICO-Photonics-Delphi2009

Y2 - 7 October 2009 through 9 October 2009

ER -

The effect of charge transfer on the NLO response of some porphyrin-[60]fullerene dyads

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