Stereoselective synthesis and reactions of 1-seleno-4-tert-butyl cyclohexyllithiums

A. Krief; G. Evrard; E. Badaoui; V. De Beys; R. Dieden

Stereoselective synthesis and reactions of 1-seleno-4-tert-butyl cyclohexyllithiums

A. Krief, G. Evrard, E. Badaoui, V. De Beys, R. Dieden

Unite de recherche en chimie organique

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

The axial C-Se bond of seleno- and mixed selenoacetals derived from 4-tert-butyl cyclohexanones exhibit a high tendency to be cleaved by n-butyllithium. The resulting 1-seleno-4-tert-butyl cyclohexyllithiums are selectively protonated or selenylated via axial attack.

langue originale	Anglais
Pages (de - à)	5635-5638
Nombre de pages	4
journal	Tetrahedron Letters
Volume	30
Numéro de publication	41
Etat de la publication	Publié - 1 janv. 1989

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@article{3993662686fa4690a3a8f452367332bc,

title = "Stereoselective synthesis and reactions of 1-seleno-4-tert-butyl cyclohexyllithiums",

abstract = "The axial C-Se bond of seleno- and mixed selenoacetals derived from 4-tert-butyl cyclohexanones exhibit a high tendency to be cleaved by n-butyllithium. The resulting 1-seleno-4-tert-butyl cyclohexyllithiums are selectively protonated or selenylated via axial attack.",

author = "A. Krief and G. Evrard and E. Badaoui and {De Beys}, V. and R. Dieden",

year = "1989",

month = jan,

day = "1",

language = "English",

volume = "30",

pages = "5635--5638",

journal = "Tetrahedron Letters",

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T1 - Stereoselective synthesis and reactions of 1-seleno-4-tert-butyl cyclohexyllithiums

AU - Krief, A.

AU - Evrard, G.

AU - Badaoui, E.

AU - De Beys, V.

AU - Dieden, R.

PY - 1989/1/1

Y1 - 1989/1/1

N2 - The axial C-Se bond of seleno- and mixed selenoacetals derived from 4-tert-butyl cyclohexanones exhibit a high tendency to be cleaved by n-butyllithium. The resulting 1-seleno-4-tert-butyl cyclohexyllithiums are selectively protonated or selenylated via axial attack.

AB - The axial C-Se bond of seleno- and mixed selenoacetals derived from 4-tert-butyl cyclohexanones exhibit a high tendency to be cleaved by n-butyllithium. The resulting 1-seleno-4-tert-butyl cyclohexyllithiums are selectively protonated or selenylated via axial attack.

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M3 - Article

AN - SCOPUS:0001031336

SN - 0040-4039

VL - 30

SP - 5635

EP - 5638

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 41

ER -

Stereoselective synthesis and reactions of 1-seleno-4-tert-butyl cyclohexyllithiums

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