Stereoselective synthesis and reactions of 1-seleno-4-tert-butyl cyclohexyllithiums

A. Krief; G. Evrard; E. Badaoui; V. De Beys; R. Dieden

Stereoselective synthesis and reactions of 1-seleno-4-tert-butyl cyclohexyllithiums

A. Krief, G. Evrard, E. Badaoui, V. De Beys, R. Dieden

Unit of organic chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The axial C-Se bond of seleno- and mixed selenoacetals derived from 4-tert-butyl cyclohexanones exhibit a high tendency to be cleaved by n-butyllithium. The resulting 1-seleno-4-tert-butyl cyclohexyllithiums are selectively protonated or selenylated via axial attack.

Original language	English
Pages (from-to)	5635-5638
Number of pages	4
Journal	Tetrahedron Letters
Volume	30
Issue number	41
Publication status	Published - 1 Jan 1989

Cite this

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title = "Stereoselective synthesis and reactions of 1-seleno-4-tert-butyl cyclohexyllithiums",

abstract = "The axial C-Se bond of seleno- and mixed selenoacetals derived from 4-tert-butyl cyclohexanones exhibit a high tendency to be cleaved by n-butyllithium. The resulting 1-seleno-4-tert-butyl cyclohexyllithiums are selectively protonated or selenylated via axial attack.",

author = "A. Krief and G. Evrard and E. Badaoui and {De Beys}, V. and R. Dieden",

year = "1989",

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T1 - Stereoselective synthesis and reactions of 1-seleno-4-tert-butyl cyclohexyllithiums

AU - Krief, A.

AU - Evrard, G.

AU - Badaoui, E.

AU - De Beys, V.

AU - Dieden, R.

PY - 1989/1/1

Y1 - 1989/1/1

N2 - The axial C-Se bond of seleno- and mixed selenoacetals derived from 4-tert-butyl cyclohexanones exhibit a high tendency to be cleaved by n-butyllithium. The resulting 1-seleno-4-tert-butyl cyclohexyllithiums are selectively protonated or selenylated via axial attack.

AB - The axial C-Se bond of seleno- and mixed selenoacetals derived from 4-tert-butyl cyclohexanones exhibit a high tendency to be cleaved by n-butyllithium. The resulting 1-seleno-4-tert-butyl cyclohexyllithiums are selectively protonated or selenylated via axial attack.

UR - http://www.scopus.com/inward/record.url?scp=0001031336&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0001031336

SN - 0040-4039

VL - 30

SP - 5635

EP - 5638

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 41

ER -

Stereoselective synthesis and reactions of 1-seleno-4-tert-butyl cyclohexyllithiums

Abstract

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