Stereoselective synthesis and reactions of 1-seleno-4-tert-butyl cyclohexyllithiums

A. Krief, G. Evrard, E. Badaoui, V. De Beys, R. Dieden

Research output: Contribution to journalArticlepeer-review

Abstract

The axial C-Se bond of seleno- and mixed selenoacetals derived from 4-tert-butyl cyclohexanones exhibit a high tendency to be cleaved by n-butyllithium. The resulting 1-seleno-4-tert-butyl cyclohexyllithiums are selectively protonated or selenylated via axial attack.
Original languageEnglish
Pages (from-to)5635-5638
Number of pages4
JournalTetrahedron Letters
Volume30
Issue number41
Publication statusPublished - 1 Jan 1989

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