Endo-3,3-Dimethyl-4-oxobicyclo-[3.1.0]hexan-2-yl methane-sulfonate

A. Kremer; B. Norberg; A. Krief; J. Wouters

doi:10.1107/S1600536810010901

Endo-3,3-Dimethyl-4-oxobicyclo-[3.1.0]hexan-2-yl methane-sulfonate

A. Kremer, B. Norberg, A. Krief, J. Wouters

Namur Research Institute for Life Sciences

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

The relative configuration of the endo isomer of the title compound, C HOS, has been established and the conformation of the diastereoisomer is discussed. The five-membered ring adopts an envelope conformation. The conformation of the methane-sulfonate substituent is stabilized by inter-molecular C - H⋯O hydrogen bonds. The crystal packing results in alternating layers of polar methane-sulfonates and stacked bicyclo-hexa-nyl rings parallel to ab.

langue originale	Anglais
journal	Acta crystallographica. Section E: Structure reports
Volume	66
Numéro de publication	4
Les DOIs	https://doi.org/10.1107/S1600536810010901
Etat de la publication	Publié - 1 janv. 2010

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10.1107/S1600536810010901

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title = "Endo-3,3-Dimethyl-4-oxobicyclo-[3.1.0]hexan-2-yl methane-sulfonate",

abstract = "The relative configuration of the endo isomer of the title compound, C HOS, has been established and the conformation of the diastereoisomer is discussed. The five-membered ring adopts an envelope conformation. The conformation of the methane-sulfonate substituent is stabilized by inter-molecular C - H⋯O hydrogen bonds. The crystal packing results in alternating layers of polar methane-sulfonates and stacked bicyclo-hexa-nyl rings parallel to ab.",

author = "A. Kremer and B. Norberg and A. Krief and J. Wouters",

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AU - Kremer, A.

AU - Norberg, B.

AU - Krief, A.

AU - Wouters, J.

PY - 2010/1/1

Y1 - 2010/1/1

N2 - The relative configuration of the endo isomer of the title compound, C HOS, has been established and the conformation of the diastereoisomer is discussed. The five-membered ring adopts an envelope conformation. The conformation of the methane-sulfonate substituent is stabilized by inter-molecular C - H⋯O hydrogen bonds. The crystal packing results in alternating layers of polar methane-sulfonates and stacked bicyclo-hexa-nyl rings parallel to ab.

AB - The relative configuration of the endo isomer of the title compound, C HOS, has been established and the conformation of the diastereoisomer is discussed. The five-membered ring adopts an envelope conformation. The conformation of the methane-sulfonate substituent is stabilized by inter-molecular C - H⋯O hydrogen bonds. The crystal packing results in alternating layers of polar methane-sulfonates and stacked bicyclo-hexa-nyl rings parallel to ab.

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DO - 10.1107/S1600536810010901

M3 - Article

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Endo-3,3-Dimethyl-4-oxobicyclo-[3.1.0]hexan-2-yl methane-sulfonate

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