Ti-MOF single-crystals featuring an intracrystal macro-microporous hierarchy for catalytic oxidative desulfurization

Shen Yu; Yu Xiao; Zhan Liu; Jia Min Lyu; Yi Long Wang; Zhi Yi Hu; Yu Li; Ming Hui Sun; Li Hua Chen; Bao Lian Su

doi:10.1039/d2cc06473a

Ti-MOF single-crystals featuring an intracrystal macro-microporous hierarchy for catalytic oxidative desulfurization

Shen Yu, Yu Xiao, Zhan Liu, Jia Min Lyu, Yi Long Wang, Zhi Yi Hu, Yu Li, Ming Hui Sun, Li Hua Chen, Bao Lian Su

University of Namur

Research output: Contribution to journal › Article › peer-review

Abstract

For the first time, we demonstrate a Ti-MOF (Ti-metal organic framework) single-crystal featuring an intracrystal macro-microporous hierarchy (Hier-NTU-9) by a vapor-assisted polymer-templated method. This Hier-NTU-9 possesses macropores (100-1000 nm) derived from polymer templates and enhanced transport ability of bulky molecules, exhibiting almost double the desulfurization activity compared to the conventional NTU-9.

Original language	English
Pages (from-to)	1801-1804
Number of pages	4
Journal	Chemical Communications
Volume	59
Issue number	13
DOIs	https://doi.org/10.1039/d2cc06473a
Publication status	Published - 18 Jan 2023

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10.1039/d2cc06473a

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title = "Ti-MOF single-crystals featuring an intracrystal macro-microporous hierarchy for catalytic oxidative desulfurization",

abstract = "For the first time, we demonstrate a Ti-MOF (Ti-metal organic framework) single-crystal featuring an intracrystal macro-microporous hierarchy (Hier-NTU-9) by a vapor-assisted polymer-templated method. This Hier-NTU-9 possesses macropores (100-1000 nm) derived from polymer templates and enhanced transport ability of bulky molecules, exhibiting almost double the desulfurization activity compared to the conventional NTU-9.",

author = "Shen Yu and Yu Xiao and Zhan Liu and Lyu, {Jia Min} and Wang, {Yi Long} and Hu, {Zhi Yi} and Yu Li and Sun, {Ming Hui} and Chen, {Li Hua} and Su, {Bao Lian}",

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year = "2023",

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doi = "10.1039/d2cc06473a",

language = "English",

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T1 - Ti-MOF single-crystals featuring an intracrystal macro-microporous hierarchy for catalytic oxidative desulfurization

AU - Yu, Shen

AU - Xiao, Yu

AU - Liu, Zhan

AU - Lyu, Jia Min

AU - Wang, Yi Long

AU - Hu, Zhi Yi

AU - Li, Yu

AU - Sun, Ming Hui

AU - Chen, Li Hua

AU - Su, Bao Lian

PY - 2023/1/18

Y1 - 2023/1/18

N2 - For the first time, we demonstrate a Ti-MOF (Ti-metal organic framework) single-crystal featuring an intracrystal macro-microporous hierarchy (Hier-NTU-9) by a vapor-assisted polymer-templated method. This Hier-NTU-9 possesses macropores (100-1000 nm) derived from polymer templates and enhanced transport ability of bulky molecules, exhibiting almost double the desulfurization activity compared to the conventional NTU-9.

AB - For the first time, we demonstrate a Ti-MOF (Ti-metal organic framework) single-crystal featuring an intracrystal macro-microporous hierarchy (Hier-NTU-9) by a vapor-assisted polymer-templated method. This Hier-NTU-9 possesses macropores (100-1000 nm) derived from polymer templates and enhanced transport ability of bulky molecules, exhibiting almost double the desulfurization activity compared to the conventional NTU-9.

UR - http://www.scopus.com/inward/record.url?scp=85147382066&partnerID=8YFLogxK

U2 - 10.1039/d2cc06473a

DO - 10.1039/d2cc06473a

M3 - Article

C2 - 36722396

AN - SCOPUS:85147382066

SN - 1359-7345

VL - 59

SP - 1801

EP - 1804

JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

Ti-MOF single-crystals featuring an intracrystal macro-microporous hierarchy for catalytic oxidative desulfurization

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Ti-MOF single-crystals featuring an intracrystal macro-microporous hierarchy for catalytic oxidative desulfurization

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