Molybdenum disulfide quantum dots directing zinc indium sulfide heterostructures for enhanced visible light hydrogen production

Yang Liu; Chao Fan Li; Xiao Yun Li; Wen Bei Yu; Wen Da Dong; Heng Zhao; Zhi Yi Hu; Zhao Deng; Chao Wang; Si Jia Wu; Hao Chen; Jing Liu; Zhao Wang; Li Hua Chen; Yu Li; Bao Lian Su

doi:10.1016/j.jcis.2019.05.001

Molybdenum disulfide quantum dots directing zinc indium sulfide heterostructures for enhanced visible light hydrogen production

Yang Liu, Chao Fan Li, Xiao Yun Li, Wen Bei Yu, Wen Da Dong, Heng Zhao, Zhi Yi Hu, Zhao Deng, Chao Wang, Si Jia Wu, Hao Chen, Jing Liu, Zhao Wang, Li Hua Chen, Yu Li, Bao Lian Su

Research output: Contribution to journal › Article › peer-review

Abstract

Photocatalytic hydrogen (H ₂ )production based on semiconductors is important to utilize solar light for clean energy and environment. Herein, we report a visible light responsive heterostructure, designed and constructed by molybdenum disulfide quantum dots (MoS ₂ -QDs)in-situ seeds-directing growth and self-assemble of zinc indium sulfide (ZnIn ₂ S ₄ )nanosheet to ensure their full contact through a simple one-step solvothermal method for highly improved visible light H ₂ production. The MoS ₂ -QDs in-situ seeds-directing ZnIn ₂ S ₄ heterostructure not only builds heterojunctions between MoS ₂ and ZnIn ₂ S ₄ to spatially separate the photogenerated electrons and holes, but also serves as the active sites trapping photogenerated electrons to facilitate H ₂ evolution. As a result, MoS ₂ -QDs/ZnIn ₂ S ₄ exhibits high photocatalytic activity for H ₂ production, and the optimized 2 wt% MoS ₂ -QDs/ZnIn ₂ S ₄ (2MoS ₂ -QDs/ZnIn ₂ S ₄ )heterostructure exhibits the highest H ₂ evolution rate of 7152 umol·h ⁻¹ ·g ⁻¹ under visible light, ∼9 times of pure ZnIn ₂ S ₄ . Our strategy here could shed some lights on developing noble-metal free heterostructures for highly efficient photocatalytic H ₂ production.

Original language	English
Pages (from-to)	111-118
Number of pages	8
Journal	Journal of Colloid and Interface Science
Volume	551
DOIs	https://doi.org/10.1016/j.jcis.2019.05.001
Publication status	Published - 1 Sept 2019

Keywords

Heterostructure
MoS
Photocatalytic hydrogen production
Quantum dots
ZnIn S

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1016/j.jcis.2019.05.001

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Liu, Y., Li, C. F., Li, X. Y., Yu, W. B., Dong, W. D., Zhao, H., Hu, Z. Y., Deng, Z., Wang, C., Wu, S. J., Chen, H., Liu, J., Wang, Z., Chen, L. H., Li, Y., & Su, B. L. (2019). Molybdenum disulfide quantum dots directing zinc indium sulfide heterostructures for enhanced visible light hydrogen production. Journal of Colloid and Interface Science, 551, 111-118. https://doi.org/10.1016/j.jcis.2019.05.001

@article{1b96b7a32b6b42169cad0f114dfca650,

title = "Molybdenum disulfide quantum dots directing zinc indium sulfide heterostructures for enhanced visible light hydrogen production",

abstract = " Photocatalytic hydrogen (H 2 )production based on semiconductors is important to utilize solar light for clean energy and environment. Herein, we report a visible light responsive heterostructure, designed and constructed by molybdenum disulfide quantum dots (MoS 2 -QDs)in-situ seeds-directing growth and self-assemble of zinc indium sulfide (ZnIn 2 S 4 )nanosheet to ensure their full contact through a simple one-step solvothermal method for highly improved visible light H 2 production. The MoS 2 -QDs in-situ seeds-directing ZnIn 2 S 4 heterostructure not only builds heterojunctions between MoS 2 and ZnIn 2 S 4 to spatially separate the photogenerated electrons and holes, but also serves as the active sites trapping photogenerated electrons to facilitate H 2 evolution. As a result, MoS 2 -QDs/ZnIn 2 S 4 exhibits high photocatalytic activity for H 2 production, and the optimized 2 wt% MoS 2 -QDs/ZnIn 2 S 4 (2MoS 2 -QDs/ZnIn 2 S 4 )heterostructure exhibits the highest H 2 evolution rate of 7152 umol·h −1 ·g −1 under visible light, ∼9 times of pure ZnIn 2 S 4 . Our strategy here could shed some lights on developing noble-metal free heterostructures for highly efficient photocatalytic H 2 production. ",

keywords = "Heterostructure, MoS, Photocatalytic hydrogen production, Quantum dots, ZnIn S",

author = "Yang Liu and Li, {Chao Fan} and Li, {Xiao Yun} and Yu, {Wen Bei} and Dong, {Wen Da} and Heng Zhao and Hu, {Zhi Yi} and Zhao Deng and Chao Wang and Wu, {Si Jia} and Hao Chen and Jing Liu and Zhao Wang and Chen, {Li Hua} and Yu Li and Su, {Bao Lian}",

note = "Funding Information: Y. Li acknowledges Hubei Provincial Department of Education for the “Chutian Scholar” program. B. L. Su acknowledges the Chinese Central Government for an “Expert of the State” position in the Program of the “Thousand Talents”. This work is supported by National Natural Science Foundation of China ( U1663225 , 21671155 , 21805216 , 21805220 ), Natural Science Foundation of Hubei Province ( 2018CFB242 , 2018CFA054 ), Major programs of technical innovation in Hubei ( 2018AAA012 ) and Program for Changjiang Scholars Innovative Research Team in University ( IRT_15R52 ). Publisher Copyright: {\textcopyright} 2019 Elsevier Inc. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",

year = "2019",

month = sep,

day = "1",

doi = "10.1016/j.jcis.2019.05.001",

language = "English",

volume = "551",

pages = "111--118",

journal = "Journal of Colloid and Interface Science",

issn = "0021-9797",

publisher = "Academic Press Inc.",

}

Liu, Y, Li, CF , Li, XY, Yu, WB, Dong, WD, Zhao, H, Hu, ZY, Deng, Z, Wang, C, Wu, SJ, Chen, H, Liu, J, Wang, Z, Chen, LH, Li, Y & Su, BL 2019, 'Molybdenum disulfide quantum dots directing zinc indium sulfide heterostructures for enhanced visible light hydrogen production', Journal of Colloid and Interface Science, vol. 551, pp. 111-118. https://doi.org/10.1016/j.jcis.2019.05.001

TY - JOUR

T1 - Molybdenum disulfide quantum dots directing zinc indium sulfide heterostructures for enhanced visible light hydrogen production

AU - Liu, Yang

AU - Li, Chao Fan

AU - Li, Xiao Yun

AU - Yu, Wen Bei

AU - Dong, Wen Da

AU - Zhao, Heng

AU - Hu, Zhi Yi

AU - Deng, Zhao

AU - Wang, Chao

AU - Wu, Si Jia

AU - Chen, Hao

AU - Liu, Jing

AU - Wang, Zhao

AU - Chen, Li Hua

AU - Li, Yu

AU - Su, Bao Lian

N1 - Funding Information: Y. Li acknowledges Hubei Provincial Department of Education for the “Chutian Scholar” program. B. L. Su acknowledges the Chinese Central Government for an “Expert of the State” position in the Program of the “Thousand Talents”. This work is supported by National Natural Science Foundation of China ( U1663225 , 21671155 , 21805216 , 21805220 ), Natural Science Foundation of Hubei Province ( 2018CFB242 , 2018CFA054 ), Major programs of technical innovation in Hubei ( 2018AAA012 ) and Program for Changjiang Scholars Innovative Research Team in University ( IRT_15R52 ). Publisher Copyright: © 2019 Elsevier Inc. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.

PY - 2019/9/1

Y1 - 2019/9/1

N2 - Photocatalytic hydrogen (H 2 )production based on semiconductors is important to utilize solar light for clean energy and environment. Herein, we report a visible light responsive heterostructure, designed and constructed by molybdenum disulfide quantum dots (MoS 2 -QDs)in-situ seeds-directing growth and self-assemble of zinc indium sulfide (ZnIn 2 S 4 )nanosheet to ensure their full contact through a simple one-step solvothermal method for highly improved visible light H 2 production. The MoS 2 -QDs in-situ seeds-directing ZnIn 2 S 4 heterostructure not only builds heterojunctions between MoS 2 and ZnIn 2 S 4 to spatially separate the photogenerated electrons and holes, but also serves as the active sites trapping photogenerated electrons to facilitate H 2 evolution. As a result, MoS 2 -QDs/ZnIn 2 S 4 exhibits high photocatalytic activity for H 2 production, and the optimized 2 wt% MoS 2 -QDs/ZnIn 2 S 4 (2MoS 2 -QDs/ZnIn 2 S 4 )heterostructure exhibits the highest H 2 evolution rate of 7152 umol·h −1 ·g −1 under visible light, ∼9 times of pure ZnIn 2 S 4 . Our strategy here could shed some lights on developing noble-metal free heterostructures for highly efficient photocatalytic H 2 production.

AB - Photocatalytic hydrogen (H 2 )production based on semiconductors is important to utilize solar light for clean energy and environment. Herein, we report a visible light responsive heterostructure, designed and constructed by molybdenum disulfide quantum dots (MoS 2 -QDs)in-situ seeds-directing growth and self-assemble of zinc indium sulfide (ZnIn 2 S 4 )nanosheet to ensure their full contact through a simple one-step solvothermal method for highly improved visible light H 2 production. The MoS 2 -QDs in-situ seeds-directing ZnIn 2 S 4 heterostructure not only builds heterojunctions between MoS 2 and ZnIn 2 S 4 to spatially separate the photogenerated electrons and holes, but also serves as the active sites trapping photogenerated electrons to facilitate H 2 evolution. As a result, MoS 2 -QDs/ZnIn 2 S 4 exhibits high photocatalytic activity for H 2 production, and the optimized 2 wt% MoS 2 -QDs/ZnIn 2 S 4 (2MoS 2 -QDs/ZnIn 2 S 4 )heterostructure exhibits the highest H 2 evolution rate of 7152 umol·h −1 ·g −1 under visible light, ∼9 times of pure ZnIn 2 S 4 . Our strategy here could shed some lights on developing noble-metal free heterostructures for highly efficient photocatalytic H 2 production.

KW - Heterostructure

KW - MoS

KW - Photocatalytic hydrogen production

KW - Quantum dots

KW - ZnIn S

UR - http://www.scopus.com/inward/record.url?scp=85065189320&partnerID=8YFLogxK

U2 - 10.1016/j.jcis.2019.05.001

DO - 10.1016/j.jcis.2019.05.001

M3 - Article

C2 - 31078096

AN - SCOPUS:85065189320

SN - 0021-9797

VL - 551

SP - 111

EP - 118

JO - Journal of Colloid and Interface Science

JF - Journal of Colloid and Interface Science

ER -

Molybdenum disulfide quantum dots directing zinc indium sulfide heterostructures for enhanced visible light hydrogen production

Abstract

Keywords

UN SDGs

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Molybdenum disulfide quantum dots directing zinc indium sulfide heterostructures for enhanced visible light hydrogen production

Abstract

Keywords

UN SDGs

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Physical Chemistry and characterization(PC2)

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