Molecular functionalization of tantalum oxide surface towards development of apatite growth

D. Aubry; C. Volcke; Ch. Arnould; C. Humbert; P.A. Thiry; J. Delhalle; Z. Mekhalif

doi:10.1016/j.apsusc.2008.11.022

Molecular functionalization of tantalum oxide surface towards development of apatite growth

D. Aubry, C. Volcke, Ch. Arnould, C. Humbert, P.A. Thiry, J. Delhalle, Z. Mekhalif

Unit of surface and analytical chemistry and electrochemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We have studied the apatite growth dynamics on tantalum oxide surfaces. This nucleation is obtained via an organosilane intermediate layer between the apatite and the substrate surface. Four organosilane layers (differing by their terminal functionality) were investigated. Their characterization with atomic force microscopy and other techniques such as X-ray photoelectron spectroscopy (XPS) and wetting measurements highlighted the influence of the organosilane terminal groups on the apatite growth rates. Results revealed that apatite is indeed growing faster on phosphate terminal groups than on the three other groups studied (vinyl, hydroxyl and carboxyl). © 2008 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	4765-4772
Number of pages	8
Journal	Applied Surface Science
Volume	255
Issue number	9
DOIs	https://doi.org/10.1016/j.apsusc.2008.11.022
Publication status	Published - 15 Feb 2009

Keywords

Self-Assembled Monolayers
Atomic Force Microscopy
Apatite
Tantalum
Biomaterials
X-ray Photoelectron Spectroscopy

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10.1016/j.apsusc.2008.11.022

Cite this

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title = "Molecular functionalization of tantalum oxide surface towards development of apatite growth",

abstract = "We have studied the apatite growth dynamics on tantalum oxide surfaces. This nucleation is obtained via an organosilane intermediate layer between the apatite and the substrate surface. Four organosilane layers (differing by their terminal functionality) were investigated. Their characterization with atomic force microscopy and other techniques such as X-ray photoelectron spectroscopy (XPS) and wetting measurements highlighted the influence of the organosilane terminal groups on the apatite growth rates. Results revealed that apatite is indeed growing faster on phosphate terminal groups than on the three other groups studied (vinyl, hydroxyl and carboxyl). {\textcopyright} 2008 Elsevier B.V. All rights reserved.",

keywords = " Self-Assembled Monolayers, Atomic Force Microscopy, Apatite, Tantalum, Biomaterials, X-ray Photoelectron Spectroscopy",

author = "D. Aubry and C. Volcke and Ch. Arnould and C. Humbert and P.A. Thiry and J. Delhalle and Z. Mekhalif",

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TY - JOUR

T1 - Molecular functionalization of tantalum oxide surface towards development of apatite growth

AU - Aubry, D.

AU - Volcke, C.

AU - Arnould, Ch.

AU - Humbert, C.

AU - Thiry, P.A.

AU - Delhalle, J.

AU - Mekhalif, Z.

PY - 2009/2/15

Y1 - 2009/2/15

N2 - We have studied the apatite growth dynamics on tantalum oxide surfaces. This nucleation is obtained via an organosilane intermediate layer between the apatite and the substrate surface. Four organosilane layers (differing by their terminal functionality) were investigated. Their characterization with atomic force microscopy and other techniques such as X-ray photoelectron spectroscopy (XPS) and wetting measurements highlighted the influence of the organosilane terminal groups on the apatite growth rates. Results revealed that apatite is indeed growing faster on phosphate terminal groups than on the three other groups studied (vinyl, hydroxyl and carboxyl). © 2008 Elsevier B.V. All rights reserved.

AB - We have studied the apatite growth dynamics on tantalum oxide surfaces. This nucleation is obtained via an organosilane intermediate layer between the apatite and the substrate surface. Four organosilane layers (differing by their terminal functionality) were investigated. Their characterization with atomic force microscopy and other techniques such as X-ray photoelectron spectroscopy (XPS) and wetting measurements highlighted the influence of the organosilane terminal groups on the apatite growth rates. Results revealed that apatite is indeed growing faster on phosphate terminal groups than on the three other groups studied (vinyl, hydroxyl and carboxyl). © 2008 Elsevier B.V. All rights reserved.

KW - Self-Assembled Monolayers

KW - Atomic Force Microscopy

KW - Apatite

KW - Tantalum

KW - Biomaterials

KW - X-ray Photoelectron Spectroscopy

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U2 - 10.1016/j.apsusc.2008.11.022

DO - 10.1016/j.apsusc.2008.11.022

M3 - Article

VL - 255

SP - 4765

EP - 4772

JO - Applied Surface Science

JF - Applied Surface Science

IS - 9

ER -

Molecular functionalization of tantalum oxide surface towards development of apatite growth

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Keywords

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Synthesis, Irradiation and Analysis of Materials (SIAM)

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Molecular functionalization of tantalum oxide surface towards development of apatite growth

Abstract

Keywords

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Synthesis, Irradiation and Analysis of Materials (SIAM)

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