Copolymerization of vinyl acetate with 1-octene and ethylene by cobalt-mediated radical polymerization

Rayna Bryaskova; Nicolas Willet; Philippe Degée; Philippe Dubois; Robert Jérôme; Christophe Detrembleur

doi:10.1002/pola.21963

Copolymerization of vinyl acetate with 1-octene and ethylene by cobalt-mediated radical polymerization

Rayna Bryaskova, Nicolas Willet, Philippe Degée, Philippe Dubois, Robert Jérôme, Christophe Detrembleur

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

The cobalt-mediated radical polymerization of vinyl acetate was extended to copolymerization with 1-alkenes (ethylene or 1-octene). In agreement with the low amount of 1-alkene that could be incorporated into the copolymer, a gradient structure was predictable, but a rather low polydispersity was observed. A poly(vinyl acetate)-b-poly(octene) copolymer was also successfully synthesized, leading to a poly (vinyl alcohol)-b-poly(octene) amphiphilic copolymer upon the methanolysis of the poly (vinyl acetate) block.

langue originale	Anglais
Pages (de - à)	2532-2542
Nombre de pages	11
journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	45
Numéro de publication	12
Les DOIs	https://doi.org/10.1002/pola.21963
Etat de la publication	Publié - 15 juin 2007
Modification externe	Oui

Accès au document

10.1002/pola.21963

Autres fichiers et liens

Link to publication in Scopus

Contient cette citation

@article{97d4a601c36d49c2aadf59070a12303b,

title = "Copolymerization of vinyl acetate with 1-octene and ethylene by cobalt-mediated radical polymerization",

abstract = "The cobalt-mediated radical polymerization of vinyl acetate was extended to copolymerization with 1-alkenes (ethylene or 1-octene). In agreement with the low amount of 1-alkene that could be incorporated into the copolymer, a gradient structure was predictable, but a rather low polydispersity was observed. A poly(vinyl acetate)-b-poly(octene) copolymer was also successfully synthesized, leading to a poly (vinyl alcohol)-b-poly(octene) amphiphilic copolymer upon the methanolysis of the poly (vinyl acetate) block.",

keywords = "Amphiphiles, Block copolymers, Cobalt-mediated radical polymerization, Controlled radical polymerization, Copolymerization",

author = "Rayna Bryaskova and Nicolas Willet and Philippe Deg{\'e}e and Philippe Dubois and Robert J{\'e}r{\^o}me and Christophe Detrembleur",

year = "2007",

month = jun,

day = "15",

doi = "10.1002/pola.21963",

language = "English",

volume = "45",

pages = "2532--2542",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

publisher = "John Wiley and Sons Inc.",

number = "12",

}

TY - JOUR

T1 - Copolymerization of vinyl acetate with 1-octene and ethylene by cobalt-mediated radical polymerization

AU - Bryaskova, Rayna

AU - Willet, Nicolas

AU - Degée, Philippe

AU - Dubois, Philippe

AU - Jérôme, Robert

AU - Detrembleur, Christophe

PY - 2007/6/15

Y1 - 2007/6/15

N2 - The cobalt-mediated radical polymerization of vinyl acetate was extended to copolymerization with 1-alkenes (ethylene or 1-octene). In agreement with the low amount of 1-alkene that could be incorporated into the copolymer, a gradient structure was predictable, but a rather low polydispersity was observed. A poly(vinyl acetate)-b-poly(octene) copolymer was also successfully synthesized, leading to a poly (vinyl alcohol)-b-poly(octene) amphiphilic copolymer upon the methanolysis of the poly (vinyl acetate) block.

AB - The cobalt-mediated radical polymerization of vinyl acetate was extended to copolymerization with 1-alkenes (ethylene or 1-octene). In agreement with the low amount of 1-alkene that could be incorporated into the copolymer, a gradient structure was predictable, but a rather low polydispersity was observed. A poly(vinyl acetate)-b-poly(octene) copolymer was also successfully synthesized, leading to a poly (vinyl alcohol)-b-poly(octene) amphiphilic copolymer upon the methanolysis of the poly (vinyl acetate) block.

KW - Amphiphiles

KW - Block copolymers

KW - Cobalt-mediated radical polymerization

KW - Controlled radical polymerization

KW - Copolymerization

UR - http://www.scopus.com/inward/record.url?scp=34250349557&partnerID=8YFLogxK

U2 - 10.1002/pola.21963

DO - 10.1002/pola.21963

M3 - Article

AN - SCOPUS:34250349557

SN - 0887-624X

VL - 45

SP - 2532

EP - 2542

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 12

ER -

Copolymerization of vinyl acetate with 1-octene and ethylene by cobalt-mediated radical polymerization

Résumé

Accès au document

Autres fichiers et liens

Empreinte digitale

Contient cette citation