Translocation-coupled transmetalation at the origin of a dinuclear lead porphyrin complex: implication of a hanging-atop coordination mode.

Stephane Le Gac; Btissam Najjari; Luca Fusaro; Thierry Roisnel; Vincent Dorcet; Michel Luhmer; Eric Furet; Jean-Francois Halet; Bernard. Boitrel

doi:10.1039/c2cc00067a

Translocation-coupled transmetalation at the origin of a dinuclear lead porphyrin complex: implication of a hanging-atop coordination mode.

Stephane Le Gac, Btissam Najjari, Luca Fusaro, Thierry Roisnel, Vincent Dorcet, Michel Luhmer, Eric Furet, Jean-Francois Halet, Bernard. Boitrel

Research output: Contribution to journal › Article › peer-review

Abstract

Translocation of a lead cation from the N-core of a porphyrin to a hanging carboxylate group (I) is coupled to a transmetalation process with a 2nd lead cation, leading to a dinuclear species (II). A novel hanging-atop coordination mode is responsible for the dynamic and stereo-controlled binding of lead to the porphyrin core. [on SciFinder(R)]

Original language	English
Pages (from-to)	3724-3726
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	31
DOIs	https://doi.org/10.1039/c2cc00067a
Publication status	Published - 2012
Externally published	Yes

Keywords

translocation coupled transmetalation dinuclear porphyrin hanging atop coordination mode
crystal structure lead porphyrin mononuclear dinuclear

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10.1039/c2cc00067a

CCDC 855999: Experimental Crystal Structure Determination
Boitrel, B. (Contributor), Dorcet, V. (Contributor), Furet, E. (Contributor), Fusaro, L. (Contributor), Halet, J. (Contributor), Le Gac, S. (Contributor), Luhmer, M. (Contributor), Najjari, B. (Contributor) & Roisnel, T. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/ccxqqw6, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxqqw6&sid=DataCite
Dataset
CCDC 845672: Experimental Crystal Structure Determination
Boitrel, B. (Contributor), Dorcet, V. (Contributor), Furet, E. (Contributor), Fusaro, L. (Contributor), Halet, J. (Contributor), Le Gac, S. (Contributor), Luhmer, M. (Contributor), Najjari, B. (Contributor) & Roisnel, T. (Contributor), Cambridge Crystallographic Data Centre, 1 Jan 2013
DOI: 10.5517/ccxczrz, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccxczrz&sid=DataCite
Dataset

Cite this

@article{a79677706ee84c0195579196550f1134,

title = "Translocation-coupled transmetalation at the origin of a dinuclear lead porphyrin complex: implication of a hanging-atop coordination mode.",

abstract = "Translocation of a lead cation from the N-core of a porphyrin to a hanging carboxylate group (I) is coupled to a transmetalation process with a 2nd lead cation, leading to a dinuclear species (II). A novel hanging-atop coordination mode is responsible for the dynamic and stereo-controlled binding of lead to the porphyrin core. [on SciFinder(R)]",

keywords = "translocation coupled transmetalation dinuclear porphyrin hanging atop coordination mode, crystal structure lead porphyrin mononuclear dinuclear",

author = "{Le Gac}, Stephane and Btissam Najjari and Luca Fusaro and Thierry Roisnel and Vincent Dorcet and Michel Luhmer and Eric Furet and Jean-Francois Halet and Bernard. Boitrel",

year = "2012",

doi = "10.1039/c2cc00067a",

language = "English",

volume = "48",

pages = "3724--3726",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "31",

}

TY - JOUR

T1 - Translocation-coupled transmetalation at the origin of a dinuclear lead porphyrin complex: implication of a hanging-atop coordination mode.

AU - Le Gac, Stephane

AU - Najjari, Btissam

AU - Fusaro, Luca

AU - Roisnel, Thierry

AU - Dorcet, Vincent

AU - Luhmer, Michel

AU - Furet, Eric

AU - Halet, Jean-Francois

AU - Boitrel, Bernard.

PY - 2012

Y1 - 2012

N2 - Translocation of a lead cation from the N-core of a porphyrin to a hanging carboxylate group (I) is coupled to a transmetalation process with a 2nd lead cation, leading to a dinuclear species (II). A novel hanging-atop coordination mode is responsible for the dynamic and stereo-controlled binding of lead to the porphyrin core. [on SciFinder(R)]

AB - Translocation of a lead cation from the N-core of a porphyrin to a hanging carboxylate group (I) is coupled to a transmetalation process with a 2nd lead cation, leading to a dinuclear species (II). A novel hanging-atop coordination mode is responsible for the dynamic and stereo-controlled binding of lead to the porphyrin core. [on SciFinder(R)]

KW - translocation coupled transmetalation dinuclear porphyrin hanging atop coordination mode

KW - crystal structure lead porphyrin mononuclear dinuclear

U2 - 10.1039/c2cc00067a

DO - 10.1039/c2cc00067a

M3 - Article

SN - 1359-7345

VL - 48

SP - 3724

EP - 3726

JO - Chemical Communications

JF - Chemical Communications

IS - 31

ER -

Translocation-coupled transmetalation at the origin of a dinuclear lead porphyrin complex: implication of a hanging-atop coordination mode.

Abstract

Keywords

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Datasets

CCDC 855999: Experimental Crystal Structure Determination

CCDC 845672: Experimental Crystal Structure Determination

Cite this