Stereochemistry of the intramolecular carbolithiation of vinyl sulfides

R.W. Hoffmann; R. Koberstein; B. Remacle; A. Krief

Stereochemistry of the intramolecular carbolithiation of vinyl sulfides

R.W. Hoffmann, R. Koberstein, B. Remacle, A. Krief

Unit of organic chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Intramolecular carbolithiation of vinyl sulfides to generate configurationally stable α-durylthioalkyllithium compounds at -105°C in THF showed carbolithiation to be nonstereospecific regarding the newly formed lithium bearing stereocentre.

Original language	English
Pages (from-to)	2189-2190
Number of pages	2
Journal	Chemical Communications
Issue number	22
Publication status	Published - 1 Jan 1997

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title = "Stereochemistry of the intramolecular carbolithiation of vinyl sulfides",

abstract = "Intramolecular carbolithiation of vinyl sulfides to generate configurationally stable α-durylthioalkyllithium compounds at -105°C in THF showed carbolithiation to be nonstereospecific regarding the newly formed lithium bearing stereocentre.",

author = "R.W. Hoffmann and R. Koberstein and B. Remacle and A. Krief",

year = "1997",

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journal = "Chemical Communications",

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T1 - Stereochemistry of the intramolecular carbolithiation of vinyl sulfides

AU - Hoffmann, R.W.

AU - Koberstein, R.

AU - Remacle, B.

AU - Krief, A.

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Y1 - 1997/1/1

N2 - Intramolecular carbolithiation of vinyl sulfides to generate configurationally stable α-durylthioalkyllithium compounds at -105°C in THF showed carbolithiation to be nonstereospecific regarding the newly formed lithium bearing stereocentre.

AB - Intramolecular carbolithiation of vinyl sulfides to generate configurationally stable α-durylthioalkyllithium compounds at -105°C in THF showed carbolithiation to be nonstereospecific regarding the newly formed lithium bearing stereocentre.

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M3 - Article

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SP - 2189

EP - 2190

JO - Chemical Communications

JF - Chemical Communications

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Stereochemistry of the intramolecular carbolithiation of vinyl sulfides

Abstract

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