Influence of the organic linker substituent on the catalytic activity of MIL-101(Cr) for the oxidative coupling of benzylamines to imines

Andrea Santiago-Portillo; Juan F. Blandez; Sergio Navalón; Mercedes Álvaro; Hermenegildo García

doi:10.1039/c6cy02577c

Influence of the organic linker substituent on the catalytic activity of MIL-101(Cr) for the oxidative coupling of benzylamines to imines

Andrea Santiago-Portillo, Juan F. Blandez, Sergio Navalón, Mercedes Álvaro, Hermenegildo García

Research output: Contribution to journal › Article › peer-review

Abstract

MIL-101(Cr) having substituents at the terephthalate linker (X = H, NO₂, SO₃H, Cl, CH₃ and NH₂) promotes the aerobic oxidation of benzylamines to the corresponding N-benzylidene benzylamines at different rates. MIL-101(Cr)-NO₂ was the most active catalyst, about 6-fold more active than the parent MIL-101(Cr). MIL-101(Cr)-NO₂ does not deactivate significantly upon five consecutive reuses, does not leach the metal to the solution and maintains its crystallinity. MIL-101(Cr)-NO₂ is active for a wide range of benzylamines including para-substituted, heterocyclic benzylamines and di- and tribenzylamines.

Original language	English
Pages (from-to)	1351-1362
Number of pages	12
Journal	Catalysis Science and Technology
Volume	7
Issue number	6
DOIs	https://doi.org/10.1039/c6cy02577c
Publication status	Published - 2017
Externally published	Yes

Access to Document

10.1039/c6cy02577c

Cite this

@article{584d28ec6b424e01b509eeb18e3a83cf,

title = "Influence of the organic linker substituent on the catalytic activity of MIL-101(Cr) for the oxidative coupling of benzylamines to imines",

abstract = "MIL-101(Cr) having substituents at the terephthalate linker (X = H, NO2, SO3H, Cl, CH3 and NH2) promotes the aerobic oxidation of benzylamines to the corresponding N-benzylidene benzylamines at different rates. MIL-101(Cr)-NO2 was the most active catalyst, about 6-fold more active than the parent MIL-101(Cr). MIL-101(Cr)-NO2 does not deactivate significantly upon five consecutive reuses, does not leach the metal to the solution and maintains its crystallinity. MIL-101(Cr)-NO2 is active for a wide range of benzylamines including para-substituted, heterocyclic benzylamines and di- and tribenzylamines.",

author = "Andrea Santiago-Portillo and Blandez, {Juan F.} and Sergio Naval{\'o}n and Mercedes {\'A}lvaro and Hermenegildo Garc{\'i}a",

note = "Funding Information: Financial support by the Spanish Ministry of Economy and Competitiveness (CTQ 2015-69153-CO2-1, CTQ2014-53292-R, Severo Ochoa) and Generalitat Valenciana (Prometeo 2013-014) is gratefully acknowledged. Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2017. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.",

year = "2017",

doi = "10.1039/c6cy02577c",

language = "English",

volume = "7",

pages = "1351--1362",

journal = "Catalysis Science and Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

number = "6",

}

TY - JOUR

T1 - Influence of the organic linker substituent on the catalytic activity of MIL-101(Cr) for the oxidative coupling of benzylamines to imines

AU - Santiago-Portillo, Andrea

AU - Blandez, Juan F.

AU - Navalón, Sergio

AU - Álvaro, Mercedes

AU - García, Hermenegildo

N1 - Funding Information: Financial support by the Spanish Ministry of Economy and Competitiveness (CTQ 2015-69153-CO2-1, CTQ2014-53292-R, Severo Ochoa) and Generalitat Valenciana (Prometeo 2013-014) is gratefully acknowledged. Publisher Copyright: © The Royal Society of Chemistry 2017. Copyright: Copyright 2017 Elsevier B.V., All rights reserved.

PY - 2017

Y1 - 2017

N2 - MIL-101(Cr) having substituents at the terephthalate linker (X = H, NO2, SO3H, Cl, CH3 and NH2) promotes the aerobic oxidation of benzylamines to the corresponding N-benzylidene benzylamines at different rates. MIL-101(Cr)-NO2 was the most active catalyst, about 6-fold more active than the parent MIL-101(Cr). MIL-101(Cr)-NO2 does not deactivate significantly upon five consecutive reuses, does not leach the metal to the solution and maintains its crystallinity. MIL-101(Cr)-NO2 is active for a wide range of benzylamines including para-substituted, heterocyclic benzylamines and di- and tribenzylamines.

AB - MIL-101(Cr) having substituents at the terephthalate linker (X = H, NO2, SO3H, Cl, CH3 and NH2) promotes the aerobic oxidation of benzylamines to the corresponding N-benzylidene benzylamines at different rates. MIL-101(Cr)-NO2 was the most active catalyst, about 6-fold more active than the parent MIL-101(Cr). MIL-101(Cr)-NO2 does not deactivate significantly upon five consecutive reuses, does not leach the metal to the solution and maintains its crystallinity. MIL-101(Cr)-NO2 is active for a wide range of benzylamines including para-substituted, heterocyclic benzylamines and di- and tribenzylamines.

UR - http://www.scopus.com/inward/record.url?scp=85018407147&partnerID=8YFLogxK

U2 - 10.1039/c6cy02577c

DO - 10.1039/c6cy02577c

M3 - Article

AN - SCOPUS:85018407147

SN - 2044-4753

VL - 7

SP - 1351

EP - 1362

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

IS - 6

ER -

Influence of the organic linker substituent on the catalytic activity of MIL-101(Cr) for the oxidative coupling of benzylamines to imines

Abstract

Access to Document

Other files and links

Fingerprint

Cite this