Calix[6]arenes with halogen bond donor groups as selective and efficient anion transporters

Anurag Singh; Aaron Torres-Huerta; Tom Vanderlinden; Nathan Renier; Luis Martínez-Crespo; Nikolay Tumanov; Johan Wouters; Kristin Bartik; Ivan Jabin; Hennie Valkenier

doi:10.1039/d2cc00847e

Calix[6]arenes with halogen bond donor groups as selective and efficient anion transporters

Anurag Singh, Aaron Torres-Huerta, Tom Vanderlinden, Nathan Renier, Luis Martínez-Crespo, Nikolay Tumanov, Johan Wouters, Kristin Bartik, Ivan Jabin, Hennie Valkenier

Research output: Contribution to journal › Article › peer-review

34 Downloads (Pure)

Abstract

Here we present the anion binding and anion transport properties of a series of calix[6]arenes decorated on their small rim with either halogen bond or hydrogen bond donating groups. We show that the halogen bond donating iodotriazole groups enable highly selective transport of chloride and nitrate anions, without transport of protons or hydroxide, at rates similar to those observed with thiourea or squaramide groups.

Original language	English
Pages (from-to)	6255-6258
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	42
DOIs	https://doi.org/10.1039/d2cc00847e
Publication status	Published - 6 May 2022

Access to Document

10.1039/d2cc00847e

SinghA_article_2022Final published version, 2.56 MB

Cite this

@article{aa5256c10252434882171f9467731989,

title = "Calix[6]arenes with halogen bond donor groups as selective and efficient anion transporters",

abstract = "Here we present the anion binding and anion transport properties of a series of calix[6]arenes decorated on their small rim with either halogen bond or hydrogen bond donating groups. We show that the halogen bond donating iodotriazole groups enable highly selective transport of chloride and nitrate anions, without transport of protons or hydroxide, at rates similar to those observed with thiourea or squaramide groups.",

author = "Anurag Singh and Aaron Torres-Huerta and Tom Vanderlinden and Nathan Renier and Luis Mart{\'i}nez-Crespo and Nikolay Tumanov and Johan Wouters and Kristin Bartik and Ivan Jabin and Hennie Valkenier",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry",

year = "2022",

month = may,

day = "6",

doi = "10.1039/d2cc00847e",

language = "English",

volume = "58",

pages = "6255--6258",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "The Royal Society of Chemistry",

number = "42",

}

TY - JOUR

T1 - Calix[6]arenes with halogen bond donor groups as selective and efficient anion transporters

AU - Singh, Anurag

AU - Torres-Huerta, Aaron

AU - Vanderlinden, Tom

AU - Renier, Nathan

AU - Martínez-Crespo, Luis

AU - Tumanov, Nikolay

AU - Wouters, Johan

AU - Bartik, Kristin

AU - Jabin, Ivan

AU - Valkenier, Hennie

PY - 2022/5/6

Y1 - 2022/5/6

N2 - Here we present the anion binding and anion transport properties of a series of calix[6]arenes decorated on their small rim with either halogen bond or hydrogen bond donating groups. We show that the halogen bond donating iodotriazole groups enable highly selective transport of chloride and nitrate anions, without transport of protons or hydroxide, at rates similar to those observed with thiourea or squaramide groups.

AB - Here we present the anion binding and anion transport properties of a series of calix[6]arenes decorated on their small rim with either halogen bond or hydrogen bond donating groups. We show that the halogen bond donating iodotriazole groups enable highly selective transport of chloride and nitrate anions, without transport of protons or hydroxide, at rates similar to those observed with thiourea or squaramide groups.

UR - http://www.scopus.com/inward/record.url?scp=85131017672&partnerID=8YFLogxK

U2 - 10.1039/d2cc00847e

DO - 10.1039/d2cc00847e

M3 - Article

C2 - 35521967

AN - SCOPUS:85131017672

SN - 1359-7345

VL - 58

SP - 6255

EP - 6258

JO - Chemical Communications

JF - Chemical Communications

IS - 42

ER -

Calix[6]arenes with halogen bond donor groups as selective and efficient anion transporters

Abstract

Access to Document

Other files and links

Fingerprint

Cite this