ZIF-8 as Nonlinear Optical Material: Influence of Structure and Synthesis

Stijn Van Cleuvenbergen; Ivo Stassen; Elena Gobechiya; Yuexing Zhang; Karen Markey; Dirk E. De Vos; Christine Kirschhock; Benoît Champagne; Thierry Verbiest; Monique A. Van Der Veen

doi:10.1021/acs.chemmater.6b01087

ZIF-8 as Nonlinear Optical Material: Influence of Structure and Synthesis

Stijn Van Cleuvenbergen, Ivo Stassen, Elena Gobechiya, Yuexing Zhang, Karen Markey, Dirk E. De Vos, Christine Kirschhock, Benoît Champagne, Thierry Verbiest, Monique A. Van Der Veen

Unite de recherche en chimie physique, theorique et structurale

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

Metal-organic framework ZIF-8, from the zeolitic imidazolate framework family, shows a large intrinsic second-order nonlinear optical (NLO) response. In addition, ZIF-8 is a stable, inexpensive material that is transparent in the visible (vis) and near-infrared (NIR) window. This is crucial for NLO applications. The second-order NLO activity is due to the noncentrosymmetric octupolar symmetry of the material. We found that fast syntheses lead to a lower second-order NLO response. Consistent with polarized second-harmonic generation (SHG) microscopy measurements, we ascribe this to defects that create local centers of centrosymmetry but do not affect the orientation of the crystal lattice. Syntheses with slow nucleation lead to quasi-perfect crystals with a large average second-order NLO coefficient 〈d_eff〉 of 0.25 pm/V, which is explained and supported by ab initio theoretical calculations.

langue originale	Anglais
Pages (de - à)	3203-3209
Nombre de pages	7
journal	Chemistry of Materials
Volume	28
Numéro de publication	9
Les DOIs	https://doi.org/10.1021/acs.chemmater.6b01087
Etat de la publication	Publié - 10 mai 2016

Accès au document

10.1021/acs.chemmater.6b01087

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Link to publication in Scopus

Subvention - Professeur de recherche Francqui
Nakano, M. & Castet, F.
1/09/12 → 31/12/15
Projet: Recherche
PAI n°P7/05 - FS2: Systèmes supramoléculaires fonctionnels (PAI P7/05)
Champagne, B., De Vos, D., Van der Auweraer, M., Jérôme, C., Lazzaroni, R., Marin, G., Jonas, A., Du Prez, F., Vanderzande, D., Van Tendeloo, G., Van Speybroeck, V., NENON, S. & STAELENS, N.
1/04/12 → 30/09/17
Projet: Recherche
Atomic Scale Optoelectronics and Surface Modifications from First Principles Simulations of STM Experiments
Champagne, B. & ZHANG, Y.
1/10/11 → 30/09/13
Projet: Recherche

Plateforme Technologique Calcul Intensif
Benoît Champagne (!!Manager)
Plateforme technologique Calcul intensif
Equipement/installations: Plateforme technolgique

CCDC 1484037: Experimental Crystal Structure Determination
Van Cleuvenbergen, S. (Contributeur), Stassen, I. (Contributeur), Gobechiya, E. (Contributeur), Zhang, Y. (Contributeur), Markey, K. (Contributeur), De Vos, D. E. (Contributeur), Kirschhock, C. (Contributeur), Champagne, B. (Contributeur), Verbiest, T. (Contributeur) & Van Der Veen, M. A. (Contributeur), Cambridge Crystallographic Data Centre, 1 janv. 2016
DOI: 10.5517/ccdc.csd.cc1lt85v, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1lt85v&sid=DataCite
Ensemble de données

Contient cette citation

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title = "ZIF-8 as Nonlinear Optical Material: Influence of Structure and Synthesis",

abstract = "Metal-organic framework ZIF-8, from the zeolitic imidazolate framework family, shows a large intrinsic second-order nonlinear optical (NLO) response. In addition, ZIF-8 is a stable, inexpensive material that is transparent in the visible (vis) and near-infrared (NIR) window. This is crucial for NLO applications. The second-order NLO activity is due to the noncentrosymmetric octupolar symmetry of the material. We found that fast syntheses lead to a lower second-order NLO response. Consistent with polarized second-harmonic generation (SHG) microscopy measurements, we ascribe this to defects that create local centers of centrosymmetry but do not affect the orientation of the crystal lattice. Syntheses with slow nucleation lead to quasi-perfect crystals with a large average second-order NLO coefficient 〈deff〉 of 0.25 pm/V, which is explained and supported by ab initio theoretical calculations.",

author = "{Van Cleuvenbergen}, Stijn and Ivo Stassen and Elena Gobechiya and Yuexing Zhang and Karen Markey and {De Vos}, {Dirk E.} and Christine Kirschhock and Beno{\^i}t Champagne and Thierry Verbiest and {Van Der Veen}, {Monique A.}",

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doi = "10.1021/acs.chemmater.6b01087",

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T2 - Influence of Structure and Synthesis

AU - Van Cleuvenbergen, Stijn

AU - Stassen, Ivo

AU - Gobechiya, Elena

AU - Zhang, Yuexing

AU - Markey, Karen

AU - De Vos, Dirk E.

AU - Kirschhock, Christine

AU - Champagne, Benoît

AU - Verbiest, Thierry

AU - Van Der Veen, Monique A.

PY - 2016/5/10

Y1 - 2016/5/10

N2 - Metal-organic framework ZIF-8, from the zeolitic imidazolate framework family, shows a large intrinsic second-order nonlinear optical (NLO) response. In addition, ZIF-8 is a stable, inexpensive material that is transparent in the visible (vis) and near-infrared (NIR) window. This is crucial for NLO applications. The second-order NLO activity is due to the noncentrosymmetric octupolar symmetry of the material. We found that fast syntheses lead to a lower second-order NLO response. Consistent with polarized second-harmonic generation (SHG) microscopy measurements, we ascribe this to defects that create local centers of centrosymmetry but do not affect the orientation of the crystal lattice. Syntheses with slow nucleation lead to quasi-perfect crystals with a large average second-order NLO coefficient 〈deff〉 of 0.25 pm/V, which is explained and supported by ab initio theoretical calculations.

AB - Metal-organic framework ZIF-8, from the zeolitic imidazolate framework family, shows a large intrinsic second-order nonlinear optical (NLO) response. In addition, ZIF-8 is a stable, inexpensive material that is transparent in the visible (vis) and near-infrared (NIR) window. This is crucial for NLO applications. The second-order NLO activity is due to the noncentrosymmetric octupolar symmetry of the material. We found that fast syntheses lead to a lower second-order NLO response. Consistent with polarized second-harmonic generation (SHG) microscopy measurements, we ascribe this to defects that create local centers of centrosymmetry but do not affect the orientation of the crystal lattice. Syntheses with slow nucleation lead to quasi-perfect crystals with a large average second-order NLO coefficient 〈deff〉 of 0.25 pm/V, which is explained and supported by ab initio theoretical calculations.

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SN - 0897-4756

VL - 28

SP - 3203

EP - 3209

JO - Chemistry of Materials

JF - Chemistry of Materials

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ER -

ZIF-8 as Nonlinear Optical Material: Influence of Structure and Synthesis

Résumé

Accès au document

Autres fichiers et liens

Empreinte digitale

Projets

Subvention - Professeur de recherche Francqui

PAI n°P7/05 - FS2: Systèmes supramoléculaires fonctionnels (PAI P7/05)

Atomic Scale Optoelectronics and Surface Modifications from First Principles Simulations of STM Experiments

Équipement

Plateforme Technologique Calcul Intensif

Ensembles de données

CCDC 1484037: Experimental Crystal Structure Determination

Contient cette citation