Versatile Catalyst Materials Fabrication by Low-Pressure Plasma Treatments

Y. Busby, M. da Silva Pires, E. Haye, V. Stergiopulos, N. Job, J. J. Pireaux, L. Houssiau

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Résumé

An alternative solvent-free method is explored for the processing of Pt/C, Ni/C and Pt-Ni catalysts based on a low-pressure radio-frequency plasma treatment of solid (powder) precursors. A porous carbon xerogel is used as catalyst support, mixed with an organometallic precursor and treated in a plasma discharge at different power and in different plasma chemical environments. The nucleation of metal nanoparticles, their morphology evolution and chemical state are characterized by combining in-situ optical emission spectroscopy, transmission electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy. Results show that the plasma processing offers a high flexibility in tuning the size and oxidation state of Ni and Pt nanoparticles and also allows for a controlled functionalization of the carbon support; these properties demonstrate the high potential of plasma processing route for the fabrication of green and efficient catalysts nanomaterials.

langue originaleAnglais
titreEFC 2017 - Proceedings of the 7th European Fuel Cell Piero Lunghi Conference
rédacteurs en chefViviana Cigolotti, Chiara Barchiesi, Michela Chianella
EditeurENEA
Pages67-68
Nombre de pages2
ISBN (Electronique)9788882863241
Etat de la publicationPublié - 2017
Evénement7th European Fuel Cell Piero Lunghi Conference, EFC 2017 - Naples, Italie
Durée: 12 déc. 201715 déc. 2017

Série de publications

NomEFC 2017 - Proceedings of the 7th European Fuel Cell Piero Lunghi Conference

Une conférence

Une conférence7th European Fuel Cell Piero Lunghi Conference, EFC 2017
Pays/TerritoireItalie
La villeNaples
période12/12/1715/12/17

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