Unusual reactivity of selenoboranes towards epoxides: new selective routes to b-hydroxyselenides and allylalcohols

A. Cravador; A. Krief

Unusual reactivity of selenoboranes towards epoxides: new selective routes to b-hydroxyselenides and allylalcohols

A. Cravador, A. Krief

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

Selenoboranes react with terminal α,β- di- and trisubstituted epoxides to produce β-hydroxylenides, (or olefins) in the two first cases and allyl alcohols in the last one. A very high stereodescrimination has been observed for α,β-disubstituted epoxides: the cis epoxide being much more reactive.

langue originale	Anglais
Pages (de - à)	2491-2494
Nombre de pages	4
journal	Tetrahedron Letters
Volume	22
Numéro de publication	26
Etat de la publication	Publié - 1 janv. 1981

Autres fichiers et liens

Link to publication in Scopus

Contient cette citation

@article{4206222d142a47dfb1ca72d877769779,

title = "Unusual reactivity of selenoboranes towards epoxides: new selective routes to b-hydroxyselenides and allylalcohols",

abstract = "Selenoboranes react with terminal α,β- di- and trisubstituted epoxides to produce β-hydroxylenides, (or olefins) in the two first cases and allyl alcohols in the last one. A very high stereodescrimination has been observed for α,β-disubstituted epoxides: the cis epoxide being much more reactive.",

author = "A. Cravador and A. Krief",

year = "1981",

month = jan,

day = "1",

language = "English",

volume = "22",

pages = "2491--2494",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "26",

}

TY - JOUR

T1 - Unusual reactivity of selenoboranes towards epoxides

T2 - new selective routes to b-hydroxyselenides and allylalcohols

AU - Cravador, A.

AU - Krief, A.

PY - 1981/1/1

Y1 - 1981/1/1

N2 - Selenoboranes react with terminal α,β- di- and trisubstituted epoxides to produce β-hydroxylenides, (or olefins) in the two first cases and allyl alcohols in the last one. A very high stereodescrimination has been observed for α,β-disubstituted epoxides: the cis epoxide being much more reactive.

AB - Selenoboranes react with terminal α,β- di- and trisubstituted epoxides to produce β-hydroxylenides, (or olefins) in the two first cases and allyl alcohols in the last one. A very high stereodescrimination has been observed for α,β-disubstituted epoxides: the cis epoxide being much more reactive.

UR - http://www.scopus.com/inward/record.url?scp=0005924041&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0005924041

SN - 0040-4039

VL - 22

SP - 2491

EP - 2494

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 26

ER -

Unusual reactivity of selenoboranes towards epoxides: new selective routes to b-hydroxyselenides and allylalcohols

Résumé

Autres fichiers et liens

Empreinte digitale

Contient cette citation