Synthesis of Optically Active Arylcyclopentanes by Carbocyclisation of ω-Alkenylbenzyllithiums Involving Diastereofacial Differentiation

A. Krief; J. Bousbaa

Synthesis of Optically Active Arylcyclopentanes by Carbocyclisation of ω-Alkenylbenzyllithiums Involving Diastereofacial Differentiation

A. Krief, J. Bousbaa

Unite de recherche en chimie organique

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

ω-Alkenylbenzyllithiums, bearing a chiral alkoxy group in suitable position cyclise to arylcyclopentanes with very high control of the relative stereochemistry and very high stereofacial differentiation. This reaction has been used in the synthesis of enantiopure arylcyclopentanes derivatives.

langue originale	Anglais
Pages (de - à)	1007-1009
Nombre de pages	3
journal	Synlett
Volume	1996
Numéro de publication	10
Etat de la publication	Publié - 1 janv. 1996

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title = "Synthesis of Optically Active Arylcyclopentanes by Carbocyclisation of ω-Alkenylbenzyllithiums Involving Diastereofacial Differentiation",

abstract = "ω-Alkenylbenzyllithiums, bearing a chiral alkoxy group in suitable position cyclise to arylcyclopentanes with very high control of the relative stereochemistry and very high stereofacial differentiation. This reaction has been used in the synthesis of enantiopure arylcyclopentanes derivatives.",

author = "A. Krief and J. Bousbaa",

year = "1996",

month = jan,

day = "1",

language = "English",

volume = "1996",

pages = "1007--1009",

journal = "Synlett",

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publisher = "Georg Thieme Verlag",

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T1 - Synthesis of Optically Active Arylcyclopentanes by Carbocyclisation of ω-Alkenylbenzyllithiums Involving Diastereofacial Differentiation

AU - Krief, A.

AU - Bousbaa, J.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - ω-Alkenylbenzyllithiums, bearing a chiral alkoxy group in suitable position cyclise to arylcyclopentanes with very high control of the relative stereochemistry and very high stereofacial differentiation. This reaction has been used in the synthesis of enantiopure arylcyclopentanes derivatives.

AB - ω-Alkenylbenzyllithiums, bearing a chiral alkoxy group in suitable position cyclise to arylcyclopentanes with very high control of the relative stereochemistry and very high stereofacial differentiation. This reaction has been used in the synthesis of enantiopure arylcyclopentanes derivatives.

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M3 - Article

AN - SCOPUS:0007884867

SN - 0936-5214

VL - 1996

SP - 1007

EP - 1009

JO - Synlett

JF - Synlett

IS - 10

ER -

Synthesis of Optically Active Arylcyclopentanes by Carbocyclisation of ω-Alkenylbenzyllithiums Involving Diastereofacial Differentiation

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