Synthesis of a Bimetallic Dodecaborate LiNaB12H12 with Outstanding Superionic Conductivity

Liqing He, Hai Wen Li, Hironori Nakajima, Nikolay Tumanov, Yaroslav Filinchuk, Son Jong Hwang, Manish Sharma, Hans Hagemann, Etsuo Akiba

Résultats de recherche: Contribution à un journal/une revueArticle

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Résumé

A study was conducted to demonstrate synthesis of a bimetallic dodecaborate LiNaB12H12 with significant superionic conductivity. LiNaB12H12 was prepared through sintering of LiBH4, NaBH4, and B10H14 with a stoichiometric molar ratio of 1:1:1. The successful synthesis was confirmed by X-ray diffraction, Raman spectra, and solid state nuclear magnetic resonance (NMR) measurements. The phase transition of LiNaB12H12 examined by differential scanning calorimetry (DSC) occurred at the temperature of 488 K, which is substantially lower than those reported for pure LiNaB12H12 and Na2B12H12.

langue originaleAnglais
Pages (de - à)5483-5486
Nombre de pages4
journalChemistry of Materials
Volume27
Numéro de publication16
Les DOIs
étatPublié - 2015
Modification externeOui

Empreinte digitale

Magnetic resonance measurement
Raman scattering
Differential scanning calorimetry
Sintering
Phase transitions
Nuclear magnetic resonance
X ray diffraction
Temperature
dodecaborate

Citer ceci

He, Liqing ; Li, Hai Wen ; Nakajima, Hironori ; Tumanov, Nikolay ; Filinchuk, Yaroslav ; Hwang, Son Jong ; Sharma, Manish ; Hagemann, Hans ; Akiba, Etsuo. / Synthesis of a Bimetallic Dodecaborate LiNaB12H12 with Outstanding Superionic Conductivity. Dans: Chemistry of Materials. 2015 ; Vol 27, Numéro 16. p. 5483-5486.
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title = "Synthesis of a Bimetallic Dodecaborate LiNaB12H12 with Outstanding Superionic Conductivity",
abstract = "A study was conducted to demonstrate synthesis of a bimetallic dodecaborate LiNaB12H12 with significant superionic conductivity. LiNaB12H12 was prepared through sintering of LiBH4, NaBH4, and B10H14 with a stoichiometric molar ratio of 1:1:1. The successful synthesis was confirmed by X-ray diffraction, Raman spectra, and solid state nuclear magnetic resonance (NMR) measurements. The phase transition of LiNaB12H12 examined by differential scanning calorimetry (DSC) occurred at the temperature of 488 K, which is substantially lower than those reported for pure LiNaB12H12 and Na2B12H12.",
author = "Liqing He and Li, {Hai Wen} and Hironori Nakajima and Nikolay Tumanov and Yaroslav Filinchuk and Hwang, {Son Jong} and Manish Sharma and Hans Hagemann and Etsuo Akiba",
year = "2015",
doi = "10.1021/acs.chemmater.5b01568",
language = "English",
volume = "27",
pages = "5483--5486",
journal = "Chemistry of Materials",
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He, L, Li, HW, Nakajima, H, Tumanov, N, Filinchuk, Y, Hwang, SJ, Sharma, M, Hagemann, H & Akiba, E 2015, 'Synthesis of a Bimetallic Dodecaborate LiNaB12H12 with Outstanding Superionic Conductivity', Chemistry of Materials, VOL. 27, Numéro 16, p. 5483-5486. https://doi.org/10.1021/acs.chemmater.5b01568

Synthesis of a Bimetallic Dodecaborate LiNaB12H12 with Outstanding Superionic Conductivity. / He, Liqing; Li, Hai Wen; Nakajima, Hironori; Tumanov, Nikolay; Filinchuk, Yaroslav; Hwang, Son Jong; Sharma, Manish; Hagemann, Hans; Akiba, Etsuo.

Dans: Chemistry of Materials, Vol 27, Numéro 16, 2015, p. 5483-5486.

Résultats de recherche: Contribution à un journal/une revueArticle

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T1 - Synthesis of a Bimetallic Dodecaborate LiNaB12H12 with Outstanding Superionic Conductivity

AU - He, Liqing

AU - Li, Hai Wen

AU - Nakajima, Hironori

AU - Tumanov, Nikolay

AU - Filinchuk, Yaroslav

AU - Hwang, Son Jong

AU - Sharma, Manish

AU - Hagemann, Hans

AU - Akiba, Etsuo

PY - 2015

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AB - A study was conducted to demonstrate synthesis of a bimetallic dodecaborate LiNaB12H12 with significant superionic conductivity. LiNaB12H12 was prepared through sintering of LiBH4, NaBH4, and B10H14 with a stoichiometric molar ratio of 1:1:1. The successful synthesis was confirmed by X-ray diffraction, Raman spectra, and solid state nuclear magnetic resonance (NMR) measurements. The phase transition of LiNaB12H12 examined by differential scanning calorimetry (DSC) occurred at the temperature of 488 K, which is substantially lower than those reported for pure LiNaB12H12 and Na2B12H12.

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