Synergistic effect on corrosion resistance of phynox substrates grafted with surface-initiated ATRP (Co)polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC) and 2-hydroxyethyl methacrylate (HEMA)

Bastien Barthélémy, Simon Maheux, Sébastien Devillers, Frédéric Kanoufi, Catherine Combellas, Joseph Delhalle, Zineb Mekhalif

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Résumé

Phynox is of high interest for biomedical applications due to its biocompatibility and corrosion resistance. However, some Phynox applications require specific surface properties. These can be imparted with suitable surface functionalizations of its oxide layer. The present work investigates the surface-initiated atom transfer radical polymerization (ATRP) of 2-methacryloyoxyethyl phosphorylcholine (MPC), 2-hydroxyethyl methacrylate (HEMA), and ATRP copolymerization of (HEMA-co-MPC) (block and statistic copolymerization with different molar ratios) on grafted Phynox substrates modified with 11-(2-bromoisobutyrate)-undecyl-1-phosphonic acid (BUPA) as initiator. It is found that ATRP (co)polymerization of these monomers is feasible and forms hydrophilic layers, while improving the corrosion resistance of the system.

langue originaleAnglais
Pages (de - à)10060-10071
Nombre de pages12
journalACS Applied Materials & Interfaces
Volume6
Numéro de publication13
Les DOIs
Etat de la publicationPublié - 9 juil. 2014

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