@article{60b25f841284412f8082aac3514e66b9,
title = "Subphthalocyanine encapsulated within MIL-101(Cr)-NH2 as a solar light photoredox catalyst for dehalogenation of α-haloacetophenones",
abstract = "Subphthalocyanine has been incorporated into a robust metal-organic framework having amino groups as binding sites. The resulting SubPc@MIL-101(Cr)-NH2 composite has a loading of 2 wt%. Adsorption of subphthalocyanine does not deteriorate host crystallinity, but decreases the surface area and porosity of MIL-101(Cr)-NH2. The resulting SubPc@MIL-101(Cr)-NH2 composite exhibits a 575 nm absorption band responsible for the observed photoredox catalytic activity under simulated sunlight irradiation for hydrogenative dehalogenation of α-haloacetophenones and for the coupling of α-bromoacetophenone and styrene. The material undergoes a slight deactivation upon reuse. In comparison to the case of phthalocyanines the present study is one of the few cases showing the use of subphthalocyanine as a photoredox catalyst, with its activity derived from site isolation within the MOF cavities.",
author = "Andrea Santiago-Portillo and Sonia Remiro-Buenama{\~n}ana and Sergio Naval{\'o}n and Hermenegildo Garc{\'i}a",
note = "Funding Information: Financial support from the Spanish Ministry of Economy and Competitiveness (Severo Ochoa and RTI2018-098237-B-C21) and Generalitat Valenciana (Prometeo 2017-083) is gratefully acknowledged. S. N. is thankful for the financial support from the Fundaci{\'o}n Ram{\'o}n Areces (XVIII Concurso Nacional para la Adjudicaci{\'o}n de Ayudas a la Investigaci{\'o}n en Ciencias de la Vida y de la Materia, 2016), the Ministerio de Ciencia, Innovaci{\'o}n y Universidades RTI 2018-099482-A-I00 project and the Generalitat Valenciana grupos de investigaci{\'o}n consolid-ables 2019 (ref: AICO/2019/214) project. S. R.-B. also thanks the Research Executive Agency (REA) and the European Commission for the funding received under the Marie Sk{\l}odowska Curie actions (H2020-MSCA-IF-2015/Grant agreement number 709023/ZESMO). Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry. Copyright: Copyright 2019 Elsevier B.V., All rights reserved.",
year = "2019",
doi = "10.1039/c9dt04004h",
language = "English",
volume = "48",
pages = "17735--17740",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "48",
}