TY - JOUR
T1 - Stereoselective synthesis of methyl trans-chrysanthemate and related derivatives
AU - Krief, A.
AU - Provins, L.
PY - 1998/4/2
Y1 - 1998/4/2
N2 - γ-hydroxyalkenylstannanes, readily available from α,β- unsaturated esters, α,β-unsaturated aldehydes and tri(n- butyl)stannyllithium, react with boron trifluoride etherate to produce vinyl cyclopropane carboxylic esters. An original highly convergent synthesis of chrysanthemic acid is reported.
AB - γ-hydroxyalkenylstannanes, readily available from α,β- unsaturated esters, α,β-unsaturated aldehydes and tri(n- butyl)stannyllithium, react with boron trifluoride etherate to produce vinyl cyclopropane carboxylic esters. An original highly convergent synthesis of chrysanthemic acid is reported.
UR - http://www.scopus.com/inward/record.url?scp=0032473908&partnerID=8YFLogxK
U2 - 10.1016/S0040-4039(98)00160-9
DO - 10.1016/S0040-4039(98)00160-9
M3 - Article
AN - SCOPUS:0032473908
SN - 0040-4039
VL - 39
SP - 2017
EP - 2020
JO - Tetrahedron Letters
JF - Tetrahedron Letters
IS - 14
ER -