Spontaneous Tl(i)-to-Tl(iii) oxidation in dynamic heterobimetallic Hg(ii)/Tl(i) porphyrin complexes

Victoria Ndoyom; Luca Fusaro; Thierry Roisnel; Stéphane Le Gac; Bernard Boitrel

doi:10.1039/c5cc07828h

Spontaneous Tl(i)-to-Tl(iii) oxidation in dynamic heterobimetallic Hg(ii)/Tl(i) porphyrin complexes

Victoria Ndoyom, Luca Fusaro, Thierry Roisnel, Stéphane Le Gac, Bernard Boitrel

Unite de recherche en chimie des nanomateriaux

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

Strapped heterobimetallic Hg(ii)/Tl(i) porphyrin complexes, with both metal ions bridged by the N-core in a dynamic way, undergo spontaneous Tl(i)-to-Tl(iii) oxidation leading to a mono-Tl(iii) complex and a mixed valence Tl(i)/Tl(iii) bimetallic complex. It provides a new opportunity to tune metal ion translocations in bimetallic porphyrin systems.

langue originale	Anglais
Pages (de - à)	517-520
Nombre de pages	4
journal	Chemical Communications
Volume	52
Numéro de publication	3
Les DOIs	https://doi.org/10.1039/c5cc07828h
Etat de la publication	Publié - 30 oct. 2015

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10.1039/c5cc07828h

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CCDC 1422859: Experimental Crystal Structure Determination
Boitrel, B. (Contributeur), Fusaro, L. (Contributeur), Le Gac, S. (Contributeur), Ndoyom, V. (Contributeur) & Roisnel, T. (Contributeur), Cambridge Crystallographic Data Centre, 1 janv. 2015
DOI: 10.5517/cc1jrlpk, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc1jrlpk&sid=DataCite
Ensemble de données

Contient cette citation

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abstract = "Strapped heterobimetallic Hg(ii)/Tl(i) porphyrin complexes, with both metal ions bridged by the N-core in a dynamic way, undergo spontaneous Tl(i)-to-Tl(iii) oxidation leading to a mono-Tl(iii) complex and a mixed valence Tl(i)/Tl(iii) bimetallic complex. It provides a new opportunity to tune metal ion translocations in bimetallic porphyrin systems.",

author = "Victoria Ndoyom and Luca Fusaro and Thierry Roisnel and {Le Gac}, St{\'e}phane and Bernard Boitrel",

year = "2015",

month = oct,

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doi = "10.1039/c5cc07828h",

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T1 - Spontaneous Tl(i)-to-Tl(iii) oxidation in dynamic heterobimetallic Hg(ii)/Tl(i) porphyrin complexes

AU - Ndoyom, Victoria

AU - Fusaro, Luca

AU - Roisnel, Thierry

AU - Le Gac, Stéphane

AU - Boitrel, Bernard

PY - 2015/10/30

Y1 - 2015/10/30

N2 - Strapped heterobimetallic Hg(ii)/Tl(i) porphyrin complexes, with both metal ions bridged by the N-core in a dynamic way, undergo spontaneous Tl(i)-to-Tl(iii) oxidation leading to a mono-Tl(iii) complex and a mixed valence Tl(i)/Tl(iii) bimetallic complex. It provides a new opportunity to tune metal ion translocations in bimetallic porphyrin systems.

AB - Strapped heterobimetallic Hg(ii)/Tl(i) porphyrin complexes, with both metal ions bridged by the N-core in a dynamic way, undergo spontaneous Tl(i)-to-Tl(iii) oxidation leading to a mono-Tl(iii) complex and a mixed valence Tl(i)/Tl(iii) bimetallic complex. It provides a new opportunity to tune metal ion translocations in bimetallic porphyrin systems.

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U2 - 10.1039/c5cc07828h

DO - 10.1039/c5cc07828h

M3 - Article

SN - 1359-7345

VL - 52

SP - 517

EP - 520

JO - Chemical Communications

JF - Chemical Communications

IS - 3

ER -

Spontaneous Tl(i)-to-Tl(iii) oxidation in dynamic heterobimetallic Hg(ii)/Tl(i) porphyrin complexes

Résumé

Accès au document

Autres fichiers et liens

Document sous embargo

Empreinte digitale

Équipement

Physico-chimie et caractérisation (PC2)

Ensembles de données

CCDC 1422859: Experimental Crystal Structure Determination

Contient cette citation