Single-walled metal-organic nanotube built from a simple synthon

Nayarassery N. Adarsh; Marinela M. Dîrtu; Anil D. Naik; Alexandre F. Léonard; Nicolo Campagnol; Koen Robeyns; Johan Snauwaert; Jan Fransaer; Bao Lian Su; Yann Garcia

doi:10.1002/chem.201405859

Single-walled metal-organic nanotube built from a simple synthon

Nayarassery N. Adarsh, Marinela M. Dîrtu, Anil D. Naik, Alexandre F. Léonard, Nicolo Campagnol, Koen Robeyns, Johan Snauwaert, Jan Fransaer, Bao Lian Su, Yann Garcia

Unite de recherche en chimie des nanomateriaux

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

A conformationally flexible triazole-carboxylic acid ligand derived from an l-amino acid, namely, 4 H-1,2,4-triazol-4-yl-acetic acid (αHGlytrz), has been exploited to synthesize a structurally diverse and functionally intriguing metal-organic framework with CuSiF₆. The crystal structure reveals a novel single-walled metal-organic nanotube (SWMONT), namely, {[Cu₃(μ₃-OH)(H₂O)₃(Glytrz)₃]·SiF₆·₈H₂O·X}_∞ (1), (where X=disordered lattice water molecules) having a pore size as large as zeolites. Compound 1 was synthesized as crystals, as powder, or as layers by precipitation/electrodeposition. Mercury intrusion porosimetry demonstrates the ability of this material to store metallic mercury, after a pressure treatment, contrary to previous literature examples.

langue originale	Anglais
Pages (de - à)	4300-4307
Nombre de pages	8
journal	Chemistry: A European Journal
Volume	21
Numéro de publication	11
Les DOIs	https://doi.org/10.1002/chem.201405859
Etat de la publication	Publié - 2015

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10.1002/chem.201405859

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Physico-chimie et caractérisation (PC2)
Wouters, J. (!!Manager) & Aprile, C. (!!Manager)
Plateforme technologique Caracterisation physico-chimiques
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CCDC 908386: Experimental Crystal Structure Determination
Adarsh, N. N. (Contributeur), Dîrtu, M. M. (Contributeur), Naik, A. D. (Contributeur), Léonard, A. F. (Contributeur), Campagnol, N. (Contributeur), Robeyns, K. (Contributeur), Snauwaert, J. (Contributeur), Fransaer, J. (Contributeur), Su, B. L. (Contributeur) & Garcia, Y. (Contributeur), Cambridge Crystallographic Data Centre, 1 janv. 2015
DOI: 10.5517/cczh7sg, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cczh7sg&sid=DataCite
Ensemble de données

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title = "Single-walled metal-organic nanotube built from a simple synthon",

abstract = "A conformationally flexible triazole-carboxylic acid ligand derived from an l-amino acid, namely, 4 H-1,2,4-triazol-4-yl-acetic acid (αHGlytrz), has been exploited to synthesize a structurally diverse and functionally intriguing metal-organic framework with CuSiF6. The crystal structure reveals a novel single-walled metal-organic nanotube (SWMONT), namely, {[Cu3(μ3-OH)(H2O)3(Glytrz)3]·SiF6·8H2O·X}∞ (1), (where X=disordered lattice water molecules) having a pore size as large as zeolites. Compound 1 was synthesized as crystals, as powder, or as layers by precipitation/electrodeposition. Mercury intrusion porosimetry demonstrates the ability of this material to store metallic mercury, after a pressure treatment, contrary to previous literature examples.",

keywords = "Crystal engineering, Electrodeposition, Mercury intrusion, Metal-organic frameworks, Supramolecular chemistry",

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year = "2015",

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AU - Adarsh, Nayarassery N.

AU - Dîrtu, Marinela M.

AU - Naik, Anil D.

AU - Léonard, Alexandre F.

AU - Campagnol, Nicolo

AU - Robeyns, Koen

AU - Snauwaert, Johan

AU - Fransaer, Jan

AU - Su, Bao Lian

AU - Garcia, Yann

PY - 2015

Y1 - 2015

N2 - A conformationally flexible triazole-carboxylic acid ligand derived from an l-amino acid, namely, 4 H-1,2,4-triazol-4-yl-acetic acid (αHGlytrz), has been exploited to synthesize a structurally diverse and functionally intriguing metal-organic framework with CuSiF6. The crystal structure reveals a novel single-walled metal-organic nanotube (SWMONT), namely, {[Cu3(μ3-OH)(H2O)3(Glytrz)3]·SiF6·8H2O·X}∞ (1), (where X=disordered lattice water molecules) having a pore size as large as zeolites. Compound 1 was synthesized as crystals, as powder, or as layers by precipitation/electrodeposition. Mercury intrusion porosimetry demonstrates the ability of this material to store metallic mercury, after a pressure treatment, contrary to previous literature examples.

AB - A conformationally flexible triazole-carboxylic acid ligand derived from an l-amino acid, namely, 4 H-1,2,4-triazol-4-yl-acetic acid (αHGlytrz), has been exploited to synthesize a structurally diverse and functionally intriguing metal-organic framework with CuSiF6. The crystal structure reveals a novel single-walled metal-organic nanotube (SWMONT), namely, {[Cu3(μ3-OH)(H2O)3(Glytrz)3]·SiF6·8H2O·X}∞ (1), (where X=disordered lattice water molecules) having a pore size as large as zeolites. Compound 1 was synthesized as crystals, as powder, or as layers by precipitation/electrodeposition. Mercury intrusion porosimetry demonstrates the ability of this material to store metallic mercury, after a pressure treatment, contrary to previous literature examples.

KW - Crystal engineering

KW - Electrodeposition

KW - Mercury intrusion

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KW - Supramolecular chemistry

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Single-walled metal-organic nanotube built from a simple synthon

Résumé

Accès au document

Autres fichiers et liens

Empreinte digitale

Équipement

Physico-chimie et caractérisation (PC2)

Ensembles de données

CCDC 908386: Experimental Crystal Structure Determination

Contient cette citation