Silsesquioxane - Terpyridine Nano Building Blocks for the Design of 3D Polymeric Networks

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Résumé

Novel Polyhedral Oligomeric Silsesquioxanes (POSS) decorated with terpyridine moieties were synthetized in a one-pot procedure via Heck coupling reaction in order to study the formation of 3D supramolecular structure. The self-assembly between these nano-caged building blocks and two different metal ions (Zn2+, Fe2+) was investigated via 1H NMR as well as absorption and emission spectroscopy. Octa-fuctionalized POSS displayed interesting photophysical properties. Moreover, under selected conditions, they form stable gels at room temperature and it can be easily shaped in form of films presenting potential applications in nanotechnology.
langueAnglais
Publication spécialiséeChemistry: A European Journal
étatSoumis - 8 janv. 2017

Empreinte digitale

Emission spectroscopy
Absorption spectroscopy
Nanotechnology
Self assembly
Nuclear magnetic resonance spectroscopy
Metal ions
Gels
Temperature

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title = "Silsesquioxane - Terpyridine Nano Building Blocks for the Design of 3D Polymeric Networks",
abstract = "Novel Polyhedral Oligomeric Silsesquioxanes (POSS) decorated with terpyridine moieties were synthetized in a one-pot procedure via Heck coupling reaction in order to study the formation of 3D supramolecular structure. The self-assembly between these nano-caged building blocks and two different metal ions (Zn2+, Fe2+) was investigated via 1H NMR as well as absorption and emission spectroscopy. Octa-fuctionalized POSS displayed interesting photophysical properties. Moreover, under selected conditions, they form stable gels at room temperature and it can be easily shaped in form of films presenting potential applications in nanotechnology.",
author = "Carmela Aprile and {Carbonell Llopis}, Esther and Luca Fusaro and Lucia Bivona",
year = "2017",
month = "1",
day = "8",
language = "English",
journal = "Chemistry: A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",

}

TY - GEN

T1 - Silsesquioxane - Terpyridine Nano Building Blocks for the Design of 3D Polymeric Networks

AU - Aprile, Carmela

AU - Carbonell Llopis, Esther

AU - Fusaro, Luca

AU - Bivona, Lucia

PY - 2017/1/8

Y1 - 2017/1/8

N2 - Novel Polyhedral Oligomeric Silsesquioxanes (POSS) decorated with terpyridine moieties were synthetized in a one-pot procedure via Heck coupling reaction in order to study the formation of 3D supramolecular structure. The self-assembly between these nano-caged building blocks and two different metal ions (Zn2+, Fe2+) was investigated via 1H NMR as well as absorption and emission spectroscopy. Octa-fuctionalized POSS displayed interesting photophysical properties. Moreover, under selected conditions, they form stable gels at room temperature and it can be easily shaped in form of films presenting potential applications in nanotechnology.

AB - Novel Polyhedral Oligomeric Silsesquioxanes (POSS) decorated with terpyridine moieties were synthetized in a one-pot procedure via Heck coupling reaction in order to study the formation of 3D supramolecular structure. The self-assembly between these nano-caged building blocks and two different metal ions (Zn2+, Fe2+) was investigated via 1H NMR as well as absorption and emission spectroscopy. Octa-fuctionalized POSS displayed interesting photophysical properties. Moreover, under selected conditions, they form stable gels at room temperature and it can be easily shaped in form of films presenting potential applications in nanotechnology.

M3 - Article

JO - Chemistry: A European Journal

T2 - Chemistry: A European Journal

JF - Chemistry: A European Journal

SN - 0947-6539

ER -