Selective Syntheses of A2B-Type meso-Triarylcorroles

Eduard Dolusic, Wim Dehaen

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A two-step synthesis of sterically encumbered triarylcorroles by acid-catalyzed [2+1] condensation of dipyrromethanes and aromatic aldehydes followed by oxidation with p-chloranil (or DDQ) is described. Careful monitoring of temperature, solvent, acidic catalyst and reaction time ultimately gave a reliable yield of 15-20% of the corroles, which is a significant improvement as compared to the procedures published earlier. The triarylcorroles prepared are intended for use (I) as sensor elements for anions and neutral molecules in membranes of self-assembled monolayers and (II) as labels for indoles thus providing novel probes for indole-binding proteins.
langue originaleAnglais
PagesAbstracts, Sixth Sigma-Aldrich Organic Synthesis Meeting, Spa, Belgium, 5-6 December 2002, pp. 12-12
Nombre de pages1
Etat de la publicationPublié - 2002
Evénement6th Sigma-Aldrich Symposium - Spa, Belgique
Durée: 5 déc. 2002 → …

Une conférence

Une conférence6th Sigma-Aldrich Symposium
La villeSpa
période5/12/02 → …

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