Selective recognition of small hydrogen bond acceptors by a calix[6]arene-based molecular container

Roy Lavendomme; Florent Desroches; Steven Moerkerke; Filip Topić; Johan Wouters; Kari Rissanen; Michel Luhmer; Ivan Jabin

doi:10.1080/10610278.2019.1679374

Selective recognition of small hydrogen bond acceptors by a calix[6]arene-based molecular container

Roy Lavendomme, Florent Desroches, Steven Moerkerke, Filip Topić, Johan Wouters, Kari Rissanen, Michel Luhmer, Ivan Jabin

Unite de recherche en chimie physique, theorique et structurale

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

Selective molecular recognition is of primary importance for applications such as sensing and separation of chemicals. This work describes the host-guest and crystallisation properties of a penta-carbamated calix[6]arene designed as a molecular container with a H-donating recognition group directed towards the heart of the cavity. As demonstrated by NMR spectroscopy and X-ray diffraction studies, this macrocyclic receptor can selectively recognise small H-bond acceptors through one or two hydrogen bonds, the guests nesting inside the polyaromatic cavity surrounded by eleven bulky tert-butyl groups.

langue originale	Anglais
Pages (de - à)	23-29
Nombre de pages	7
journal	Supramolecular Chemistry
Volume	32
Numéro de publication	1
Les DOIs	https://doi.org/10.1080/10610278.2019.1679374
Etat de la publication	Publié - 2 janv. 2020

Accès au document

10.1080/10610278.2019.1679374

Autres fichiers et liens

Link to publication in Scopus

Physico-chimie et caractérisation (PC2)
Wouters, J. (!!Manager), Aprile, C. (!!Manager) & Fusaro, L. (!!Manager)
Plateforme technologique Caracterisation physico-chimiques
Equipement/installations: Plateforme technolgique

CCDC 1959492: Experimental Crystal Structure Determination
Lavendomme, R. (Créateur), Desroches, F. (Créateur), Moerkerke, S. (Créateur), Topić, F. (Créateur), Wouters, J. (Contributeur), Rissanen, K. (Créateur), Luhmer, M. (Créateur) & Jabin, I. (Créateur), University of Namur, 2 janv. 2020
DOI: 10.5517/ccdc.csd.cc23s0fc, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc23s0fc&sid=DataCite
Ensemble de données
CCDC 1952601: Experimental Crystal Structure Determination
Lavendomme, R. (Créateur), Desroches, F. (Créateur), Moerkerke, S. (Créateur), Topić, F. (Créateur), Wouters, J. (Contributeur), Rissanen, K. (Créateur), Luhmer, M. (Créateur) & Jabin, I. (Créateur), University of Namur, 2 janv. 2020
DOI: 10.5517/ccdc.csd.cc23jv4n, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc23jv4n&sid=DataCite
Ensemble de données

Contient cette citation

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title = "Selective recognition of small hydrogen bond acceptors by a calix[6]arene-based molecular container",

abstract = "Selective molecular recognition is of primary importance for applications such as sensing and separation of chemicals. This work describes the host-guest and crystallisation properties of a penta-carbamated calix[6]arene designed as a molecular container with a H-donating recognition group directed towards the heart of the cavity. As demonstrated by NMR spectroscopy and X-ray diffraction studies, this macrocyclic receptor can selectively recognise small H-bond acceptors through one or two hydrogen bonds, the guests nesting inside the polyaromatic cavity surrounded by eleven bulky tert-butyl groups.",

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author = "Roy Lavendomme and Florent Desroches and Steven Moerkerke and Filip Topi{\'c} and Johan Wouters and Kari Rissanen and Michel Luhmer and Ivan Jabin",

note = "Funding Information: This work was supported by the Universit{\'e} libre de Bruxelles (ULB) and the Fonds pour la Formation {\`a} la Recherche dans l{\textquoteright}Industrie et dans l{\textquoteright}Agriculture (FRIA). The crystallographic study benefited from equipment available at UNamur as part of the “Plateforme de Caract{\'e}risation PC2” and from valuable technical support of Mrs B. Norberg. We thank Diamond Light Source for time on Beamline I19 (CY21497). Funding Information: This work was supported by the Fonds pour la Formation ? la Recherche dans l?Industrie et dans l?Agriculture?. This work was supported by the Universit? libre de Bruxelles (ULB) and the Fonds pour la Formation ? la Recherche dans l?Industrie et dans l?Agriculture (FRIA). The crystallographic study benefited from equipment available at UNamur as part of the ?Plateforme de Caract?risation PC2? and from valuable technical support of Mrs B. Norberg. We thank Diamond Light Source for time on Beamline I19 (CY21497). Publisher Copyright: {\textcopyright} 2019, {\textcopyright} 2019 Informa UK Limited, trading as Taylor & Francis Group.",

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AU - Topić, Filip

AU - Wouters, Johan

AU - Rissanen, Kari

AU - Luhmer, Michel

AU - Jabin, Ivan

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N2 - Selective molecular recognition is of primary importance for applications such as sensing and separation of chemicals. This work describes the host-guest and crystallisation properties of a penta-carbamated calix[6]arene designed as a molecular container with a H-donating recognition group directed towards the heart of the cavity. As demonstrated by NMR spectroscopy and X-ray diffraction studies, this macrocyclic receptor can selectively recognise small H-bond acceptors through one or two hydrogen bonds, the guests nesting inside the polyaromatic cavity surrounded by eleven bulky tert-butyl groups.

AB - Selective molecular recognition is of primary importance for applications such as sensing and separation of chemicals. This work describes the host-guest and crystallisation properties of a penta-carbamated calix[6]arene designed as a molecular container with a H-donating recognition group directed towards the heart of the cavity. As demonstrated by NMR spectroscopy and X-ray diffraction studies, this macrocyclic receptor can selectively recognise small H-bond acceptors through one or two hydrogen bonds, the guests nesting inside the polyaromatic cavity surrounded by eleven bulky tert-butyl groups.

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Selective recognition of small hydrogen bond acceptors by a calix[6]arene-based molecular container

Résumé

Accès au document

Autres fichiers et liens

Empreinte digitale

Équipement

Physico-chimie et caractérisation (PC2)

Ensembles de données

CCDC 1959492: Experimental Crystal Structure Determination

CCDC 1952601: Experimental Crystal Structure Determination

Contient cette citation