Regulating iminophosphorane P=N bond reactivity through geometric constraints with cage-shaped triarylphosphines

Sayandip Chakraborty; Lei Hu; Nikolay Tumanov; Johan Wouters; Raphaël Robiette; Guillaume Berionni

doi:10.1039/d4cc01868k

Regulating iminophosphorane P=N bond reactivity through geometric constraints with cage-shaped triarylphosphines

Sayandip Chakraborty, Lei Hu, Nikolay Tumanov, Johan Wouters, Raphaël Robiette, Guillaume Berionni

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Résumé

Structure–reactivity investigations and quantum-chemical parametrization of steric and electronic properties of geometrically constrained iminophosphoranes enabled the design of new frustrated Lewis pairs and revealed unusual properties at the phosphonium center embedded in the cage-shaped triptycene tricyclic scaffold.

langue originale	Anglais
Pages	7073-7076
Nombre de pages	4
Volume	60
Non	55
Publication spécialisée	Chemical Communications
Les DOIs	https://doi.org/10.1039/d4cc01868k
Etat de la publication	Publié - 18 juin 2024

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10.1039/d4cc01868k

d4cc01868kVersion finale publiée, 983 KBLicense: CC BY

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Geometrically constrained phosphines and fluorophosphonium ions for frustrated Lewis pairs catalysis
Berionni, G. (Orateur)
4 mars 2024
Activité: Discours ou présentation › Discours invité

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title = "Regulating iminophosphorane P=N bond reactivity through geometric constraints with cage-shaped triarylphosphines",

abstract = "Structure–reactivity investigations and quantum-chemical parametrization of steric and electronic properties of geometrically constrained iminophosphoranes enabled the design of new frustrated Lewis pairs and revealed unusual properties at the phosphonium center embedded in the cage-shaped triptycene tricyclic scaffold.",

author = "Sayandip Chakraborty and Lei Hu and Nikolay Tumanov and Johan Wouters and Rapha{\"e}l Robiette and Guillaume Berionni",

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AU - Hu, Lei

AU - Tumanov, Nikolay

AU - Wouters, Johan

AU - Robiette, Raphaël

AU - Berionni, Guillaume

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N2 - Structure–reactivity investigations and quantum-chemical parametrization of steric and electronic properties of geometrically constrained iminophosphoranes enabled the design of new frustrated Lewis pairs and revealed unusual properties at the phosphonium center embedded in the cage-shaped triptycene tricyclic scaffold.

AB - Structure–reactivity investigations and quantum-chemical parametrization of steric and electronic properties of geometrically constrained iminophosphoranes enabled the design of new frustrated Lewis pairs and revealed unusual properties at the phosphonium center embedded in the cage-shaped triptycene tricyclic scaffold.

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JO - Chemical Communications

JF - Chemical Communications

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Regulating iminophosphorane P=N bond reactivity through geometric constraints with cage-shaped triarylphosphines

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Geometrically constrained phosphines and fluorophosphonium ions for frustrated Lewis pairs catalysis

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