TY - JOUR
T1 - Regioselective end-functionalization of polylactide oligomers with D-glucose and D-galactose
AU - Bernard, Katty
AU - Degée, Philippe
AU - Dubois, Philippe
PY - 2003/3/1
Y1 - 2003/3/1
N2 - D-glucose and D-galactose end-functionalized polylactide oligomers were synthesized by controlled ring-opening polymerization of lactide using aluminium triisopropoxide, triethyl-aluminium or stannous octoate as promoter. Accordingly, two selectively protected monosaccharides were studied as co-initiators, either 1,2;5,6-di-O-isopropylidene-α-D-glucofuranose (1) and 1,2;3,4-di-O-isopropylidene-α-D-galactopyranose (2). In contrast to what is known in polymerization of ε-caprolactone, both protected monosaccharides proved to be efficient co-initiators and yielded end-functionalized polylactide chains with controlled regioselectivity (C-3 or C-6 linkage), predictable molecular weights and narrow molecular weight distributions.
AB - D-glucose and D-galactose end-functionalized polylactide oligomers were synthesized by controlled ring-opening polymerization of lactide using aluminium triisopropoxide, triethyl-aluminium or stannous octoate as promoter. Accordingly, two selectively protected monosaccharides were studied as co-initiators, either 1,2;5,6-di-O-isopropylidene-α-D-glucofuranose (1) and 1,2;3,4-di-O-isopropylidene-α-D-galactopyranose (2). In contrast to what is known in polymerization of ε-caprolactone, both protected monosaccharides proved to be efficient co-initiators and yielded end-functionalized polylactide chains with controlled regioselectivity (C-3 or C-6 linkage), predictable molecular weights and narrow molecular weight distributions.
KW - Functionalization
KW - Polylactide
KW - Ring-opening polymerization
KW - Saccharide
UR - http://www.scopus.com/inward/record.url?scp=0037343814&partnerID=8YFLogxK
U2 - 10.1002/pi.1050
DO - 10.1002/pi.1050
M3 - Article
AN - SCOPUS:0037343814
SN - 0959-8103
VL - 52
SP - 406
EP - 411
JO - Polymer international
JF - Polymer international
IS - 3
ER -