Polymorphic and Isomorphic Cocrystals of a N-Salicylidene-3-aminopyridine with Dicarboxylic Acids: Tuning of Solid-State Photo- and Thermochromism

Andréa Carletta, Xavier Buol, Tom Leyssens, Benoît Champagne, Johan Wouters

Résultats de recherche: Contribution à un journal/une revueArticle

Résumé

The crystal structures and optical properties of (E)-2-methoxy-6-(pyridin-3-yliminomethyl)phenol (1), a N-salicylidene-3-aminopyridine, and its 2:1 dimorphic cocrystals with fumaric acid (2 and 3) and succinic acid (4 and 5) were studied at solid state in order to understand the effects of cocrystallization and molecular packing on their photo- and thermochromic behavior. New criteria for prediction of the chromic properties, based on the rationalization of the intermolecular interaction in the crystal, are also proposed. These results confirm once more the influence of the molecular packing on the chromic properties of solids and extend it to polymorphic and isomorphic cocrystals.
langue originaleAnglais
Pages (de - à)10001
Nombre de pages10008
journalJ. Phys. Chem. C
Volume120
Numéro de publication18
Les DOIs
étatPublié - 20 avr. 2016

Empreinte digitale

Dicarboxylic Acids
dicarboxylic acids
Tuning
tuning
solid state
Acids
Succinic Acid
Phenol
Phenols
acids
Optical properties
Crystal structure
phenols
Crystals
optical properties
crystal structure
predictions
crystals
3-aminopyridine
interactions

Citer ceci

@article{9964046db23441739746ff5f815eb860,
title = "Polymorphic and Isomorphic Cocrystals of a N-Salicylidene-3-aminopyridine with Dicarboxylic Acids: Tuning of Solid-State Photo- and Thermochromism",
abstract = "The crystal structures and optical properties of (E)-2-methoxy-6-(pyridin-3-yliminomethyl)phenol (1), a N-salicylidene-3-aminopyridine, and its 2:1 dimorphic cocrystals with fumaric acid (2 and 3) and succinic acid (4 and 5) were studied at solid state in order to understand the effects of cocrystallization and molecular packing on their photo- and thermochromic behavior. New criteria for prediction of the chromic properties, based on the rationalization of the intermolecular interaction in the crystal, are also proposed. These results confirm once more the influence of the molecular packing on the chromic properties of solids and extend it to polymorphic and isomorphic cocrystals.",
author = "Andr{\'e}a Carletta and Xavier Buol and Tom Leyssens and Beno{\^i}t Champagne and Johan Wouters",
year = "2016",
month = "4",
day = "20",
doi = "10.1021/acs.jpcc.6b02734",
language = "English",
volume = "120",
pages = "10001",
journal = "Journal of physical chemistry. C",
issn = "1932-7447",
publisher = "American Chemical Society",
number = "18",

}

Polymorphic and Isomorphic Cocrystals of a N-Salicylidene-3-aminopyridine with Dicarboxylic Acids : Tuning of Solid-State Photo- and Thermochromism. / Carletta, Andréa; Buol, Xavier; Leyssens, Tom; Champagne, Benoît; Wouters, Johan.

Dans: J. Phys. Chem. C, Vol 120 , Numéro 18, 20.04.2016, p. 10001.

Résultats de recherche: Contribution à un journal/une revueArticle

TY - JOUR

T1 - Polymorphic and Isomorphic Cocrystals of a N-Salicylidene-3-aminopyridine with Dicarboxylic Acids

T2 - Tuning of Solid-State Photo- and Thermochromism

AU - Carletta, Andréa

AU - Buol, Xavier

AU - Leyssens, Tom

AU - Champagne, Benoît

AU - Wouters, Johan

PY - 2016/4/20

Y1 - 2016/4/20

N2 - The crystal structures and optical properties of (E)-2-methoxy-6-(pyridin-3-yliminomethyl)phenol (1), a N-salicylidene-3-aminopyridine, and its 2:1 dimorphic cocrystals with fumaric acid (2 and 3) and succinic acid (4 and 5) were studied at solid state in order to understand the effects of cocrystallization and molecular packing on their photo- and thermochromic behavior. New criteria for prediction of the chromic properties, based on the rationalization of the intermolecular interaction in the crystal, are also proposed. These results confirm once more the influence of the molecular packing on the chromic properties of solids and extend it to polymorphic and isomorphic cocrystals.

AB - The crystal structures and optical properties of (E)-2-methoxy-6-(pyridin-3-yliminomethyl)phenol (1), a N-salicylidene-3-aminopyridine, and its 2:1 dimorphic cocrystals with fumaric acid (2 and 3) and succinic acid (4 and 5) were studied at solid state in order to understand the effects of cocrystallization and molecular packing on their photo- and thermochromic behavior. New criteria for prediction of the chromic properties, based on the rationalization of the intermolecular interaction in the crystal, are also proposed. These results confirm once more the influence of the molecular packing on the chromic properties of solids and extend it to polymorphic and isomorphic cocrystals.

U2 - 10.1021/acs.jpcc.6b02734

DO - 10.1021/acs.jpcc.6b02734

M3 - Article

VL - 120

SP - 10001

JO - Journal of physical chemistry. C

JF - Journal of physical chemistry. C

SN - 1932-7447

IS - 18

ER -