Résumé
The orientation of thiophenol adsorbed on silver is determined by comparing ab initio calculated and experimental sum-frequency generation (SFG) spectra measured between 9 and 20 μm using a tandem KTP/ CdSe optical parametric oscillator. The molecule S-C bond is tilted ∼37° from the surface normal with the aromatic ring plane perpendicular to the surface.
langue originale | Anglais |
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Pages (de - à) | 16135-16138 |
Nombre de pages | 4 |
journal | Journal of physical chemistry B |
Volume | 108 |
Numéro de publication | 41 |
Les DOIs | |
Etat de la publication | Publié - 14 oct. 2004 |