On the synthesis of aryl cyclopropanes from γ-benzenesulfonylalkyl tin derivatives and n-butyllithium

A. Krief; M. Hobe

doi:10.1016/S0040-4039(00)79033-2

On the synthesis of aryl cyclopropanes from γ-benzenesulfonylalkyl tin derivatives and n-butyllithium

A. Krief, M. Hobe

Unite de recherche en chimie organique

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

γ-Benzenesulfonyloxyalkyl tin derivatives readily available from γ-hydroxyalkyl selenides, n-butyllithium and trialkyl tin chlorides react with n-butyllithium and stereospecifically lead to aryl cyclopropanes. The transformation is quite general and allows the synthesis of α,β-di- and trisubstituted ones.

langue originale	Anglais
Pages (de - à)	6527-6528
Nombre de pages	2
journal	Tetrahedron Letters
Volume	33
Numéro de publication	43
Les DOIs	https://doi.org/10.1016/S0040-4039(00)79033-2
Etat de la publication	Publié - 1 janv. 1992

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10.1016/S0040-4039(00)79033-2

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title = "On the synthesis of aryl cyclopropanes from γ-benzenesulfonylalkyl tin derivatives and n-butyllithium",

abstract = "γ-Benzenesulfonyloxyalkyl tin derivatives readily available from γ-hydroxyalkyl selenides, n-butyllithium and trialkyl tin chlorides react with n-butyllithium and stereospecifically lead to aryl cyclopropanes. The transformation is quite general and allows the synthesis of α,β-di- and trisubstituted ones.",

author = "A. Krief and M. Hobe",

year = "1992",

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doi = "10.1016/S0040-4039(00)79033-2",

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T1 - On the synthesis of aryl cyclopropanes from γ-benzenesulfonylalkyl tin derivatives and n-butyllithium

AU - Krief, A.

AU - Hobe, M.

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N2 - γ-Benzenesulfonyloxyalkyl tin derivatives readily available from γ-hydroxyalkyl selenides, n-butyllithium and trialkyl tin chlorides react with n-butyllithium and stereospecifically lead to aryl cyclopropanes. The transformation is quite general and allows the synthesis of α,β-di- and trisubstituted ones.

AB - γ-Benzenesulfonyloxyalkyl tin derivatives readily available from γ-hydroxyalkyl selenides, n-butyllithium and trialkyl tin chlorides react with n-butyllithium and stereospecifically lead to aryl cyclopropanes. The transformation is quite general and allows the synthesis of α,β-di- and trisubstituted ones.

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U2 - 10.1016/S0040-4039(00)79033-2

DO - 10.1016/S0040-4039(00)79033-2

M3 - Article

AN - SCOPUS:0026675211

SN - 0040-4039

VL - 33

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EP - 6528

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 43

ER -

On the synthesis of aryl cyclopropanes from γ-benzenesulfonylalkyl tin derivatives and n-butyllithium

Résumé

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