Olefin synthesis by reductive elimination of β-heterosubstituted alkylhalides

K. Sevrin; J.N. Denis; A. Krief

Olefin synthesis by reductive elimination of β-heterosubstituted alkylhalides

K. Sevrin, J.N. Denis, A. Krief

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Résumé

Terminal and disubstituted olefins are formed on reaction of methyl-or phenylselenolate with vic-dibromides, β-halogenoselenides, β-iodo-and β-bromo-alkylchlorides and vic-dichlorides. The reaction occurs stereoselectively by formal anti elimination in the three first cases and by formal syn elimination in the last one.

langue originale	Anglais
Pages (de - à)	1877-1880
Nombre de pages	4
journal	Tetrahedron Letters
Volume	21
Numéro de publication	19
Etat de la publication	Publié - 1 janv. 1980

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title = "Olefin synthesis by reductive elimination of β-heterosubstituted alkylhalides",

abstract = "Terminal and disubstituted olefins are formed on reaction of methyl-or phenylselenolate with vic-dibromides, β-halogenoselenides, β-iodo-and β-bromo-alkylchlorides and vic-dichlorides. The reaction occurs stereoselectively by formal anti elimination in the three first cases and by formal syn elimination in the last one.",

author = "K. Sevrin and J.N. Denis and A. Krief",

year = "1980",

month = jan,

day = "1",

language = "English",

volume = "21",

pages = "1877--1880",

journal = "Tetrahedron Letters",

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T1 - Olefin synthesis by reductive elimination of β-heterosubstituted alkylhalides

AU - Sevrin, K.

AU - Denis, J.N.

AU - Krief, A.

PY - 1980/1/1

Y1 - 1980/1/1

N2 - Terminal and disubstituted olefins are formed on reaction of methyl-or phenylselenolate with vic-dibromides, β-halogenoselenides, β-iodo-and β-bromo-alkylchlorides and vic-dichlorides. The reaction occurs stereoselectively by formal anti elimination in the three first cases and by formal syn elimination in the last one.

AB - Terminal and disubstituted olefins are formed on reaction of methyl-or phenylselenolate with vic-dibromides, β-halogenoselenides, β-iodo-and β-bromo-alkylchlorides and vic-dichlorides. The reaction occurs stereoselectively by formal anti elimination in the three first cases and by formal syn elimination in the last one.

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M3 - Article

AN - SCOPUS:0343729820

SN - 0040-4039

VL - 21

SP - 1877

EP - 1880

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 19

ER -

Olefin synthesis by reductive elimination of β-heterosubstituted alkylhalides

Résumé

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