Novel enantioselective syntheses of optically active (1R)-cis- and (1R)-trans-chrysanthemic acids

A. Krief; D. Surleraux; N. Ropson

doi:10.1016/S0957-4166(00)86070-X

Novel enantioselective syntheses of optically active (1R)-cis- and (1R)-trans-chrysanthemic acids

A. Krief, D. Surleraux, N. Ropson

Unite de recherche en chimie organique

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

Dimethyl dimedone, a non chiral and cheap compound, has been converted to the optically active 1-(R)-cis- and 1-(R)-trans-chrysanthemic acids possessing high economic value. These processes involve as the key steps (i) a cyclopropanation reaction (ii) a Grob fragmentation and (iii) a lipase monitored hydrolysis of the prochiral diacetate.

langue originale	Anglais
Pages (de - à)	289-292
Nombre de pages	4
journal	Tetrahedron: Asymmetry
Volume	4
Numéro de publication	3
Les DOIs	https://doi.org/10.1016/S0957-4166(00)86070-X
Etat de la publication	Publié - 1 janv. 1993

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10.1016/S0957-4166(00)86070-X

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title = "Novel enantioselective syntheses of optically active (1R)-cis- and (1R)-trans-chrysanthemic acids",

abstract = "Dimethyl dimedone, a non chiral and cheap compound, has been converted to the optically active 1-(R)-cis- and 1-(R)-trans-chrysanthemic acids possessing high economic value. These processes involve as the key steps (i) a cyclopropanation reaction (ii) a Grob fragmentation and (iii) a lipase monitored hydrolysis of the prochiral diacetate.",

author = "A. Krief and D. Surleraux and N. Ropson",

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AU - Surleraux, D.

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PY - 1993/1/1

Y1 - 1993/1/1

N2 - Dimethyl dimedone, a non chiral and cheap compound, has been converted to the optically active 1-(R)-cis- and 1-(R)-trans-chrysanthemic acids possessing high economic value. These processes involve as the key steps (i) a cyclopropanation reaction (ii) a Grob fragmentation and (iii) a lipase monitored hydrolysis of the prochiral diacetate.

AB - Dimethyl dimedone, a non chiral and cheap compound, has been converted to the optically active 1-(R)-cis- and 1-(R)-trans-chrysanthemic acids possessing high economic value. These processes involve as the key steps (i) a cyclopropanation reaction (ii) a Grob fragmentation and (iii) a lipase monitored hydrolysis of the prochiral diacetate.

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Novel enantioselective syntheses of optically active (1R)-cis- and (1R)-trans-chrysanthemic acids

Résumé

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