Nanocoating of Hydrophobic Mesoporous Silica around MIL-101Cr for Enhanced Catalytic Activity and Stability

Jie Ying; Annika Herbst; Yu Xuan Xiao; Hao Wei; Ge Tian; Zhaofei Li; Xiao Yu Yang; Bao Lian Su; Christoph Janiak

doi:10.1021/acs.inorgchem.7b01992

Nanocoating of Hydrophobic Mesoporous Silica around MIL-101Cr for Enhanced Catalytic Activity and Stability

Jie Ying, Annika Herbst, Yu Xuan Xiao, Hao Wei, Ge Tian, Zhaofei Li, Xiao Yu Yang, Bao Lian Su, Christoph Janiak

Universite de Namur

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

© 2018 American Chemical Society. The metal-organic framework (MOF) MIL-101Cr was readily encapsulated by a very thin shell (around 30 nm) of hydrophobic mesoporous silica, which replicates the irregular shape of the MOF nanocrystals. Such a silica shell facilitates the diffusion of hydrophobic reactants with enhancement of the catalytic activity of the MOF and significantly improved catalytic stability of the MOF in the oxidation of indene.

langue originale	Anglais
Pages (de - à)	899-902
Nombre de pages	4
journal	Inorganic Chemistry
Volume	57
Numéro de publication	3
Les DOIs	https://doi.org/10.1021/acs.inorgchem.7b01992
Etat de la publication	Publié - 5 févr. 2018

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10.1021/acs.inorgchem.7b01992

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title = "Nanocoating of Hydrophobic Mesoporous Silica around MIL-101Cr for Enhanced Catalytic Activity and Stability",

abstract = "{\textcopyright} 2018 American Chemical Society. The metal-organic framework (MOF) MIL-101Cr was readily encapsulated by a very thin shell (around 30 nm) of hydrophobic mesoporous silica, which replicates the irregular shape of the MOF nanocrystals. Such a silica shell facilitates the diffusion of hydrophobic reactants with enhancement of the catalytic activity of the MOF and significantly improved catalytic stability of the MOF in the oxidation of indene.",

author = "Jie Ying and Annika Herbst and Xiao, {Yu Xuan} and Hao Wei and Ge Tian and Zhaofei Li and Yang, {Xiao Yu} and Su, {Bao Lian} and Christoph Janiak",

note = "Funding Information: This work was supported by the National Key R&D Program of China (2017YFC1103800), NSFC (U1663225, U1662134, 51472190, 51611530672, 51503166, and 51611530672), ISTCP (2015DFE52870), PCSIRT (IRT_15R52), HPNSF (2016CFA033 and 2017CFB487), BMBF Project OptiMat 03SF0492C, and the DAAD through PPP Project 57053987 (China 2j ab 14). Funding Information: This work was supported by the National Key R&D Program of China (2017YFC1103800) NSFC (U1663225, U1662134, 51472190, 51611530672, 51503166, and 51611530672) ISTCP (2015DFE52870), PCSIRT (IRT-15R52), HPNSF (2016CFA033 and 2017CFB487) BMBF Project OptiMat 03SF0492C, and the DAAD through PPP Project 57053987 (China 2j ab 14). Publisher Copyright: {\textcopyright} 2018 American Chemical Society. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.",

year = "2018",

month = feb,

day = "5",

doi = "10.1021/acs.inorgchem.7b01992",

language = "English",

volume = "57",

pages = "899--902",

journal = "Inorganic Chemistry",

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T1 - Nanocoating of Hydrophobic Mesoporous Silica around MIL-101Cr for Enhanced Catalytic Activity and Stability

AU - Ying, Jie

AU - Herbst, Annika

AU - Xiao, Yu Xuan

AU - Wei, Hao

AU - Tian, Ge

AU - Li, Zhaofei

AU - Yang, Xiao Yu

AU - Su, Bao Lian

AU - Janiak, Christoph

N1 - Funding Information: This work was supported by the National Key R&D Program of China (2017YFC1103800), NSFC (U1663225, U1662134, 51472190, 51611530672, 51503166, and 51611530672), ISTCP (2015DFE52870), PCSIRT (IRT_15R52), HPNSF (2016CFA033 and 2017CFB487), BMBF Project OptiMat 03SF0492C, and the DAAD through PPP Project 57053987 (China 2j ab 14). Funding Information: This work was supported by the National Key R&D Program of China (2017YFC1103800) NSFC (U1663225, U1662134, 51472190, 51611530672, 51503166, and 51611530672) ISTCP (2015DFE52870), PCSIRT (IRT-15R52), HPNSF (2016CFA033 and 2017CFB487) BMBF Project OptiMat 03SF0492C, and the DAAD through PPP Project 57053987 (China 2j ab 14). Publisher Copyright: © 2018 American Chemical Society. Copyright: Copyright 2018 Elsevier B.V., All rights reserved.

PY - 2018/2/5

Y1 - 2018/2/5

N2 - © 2018 American Chemical Society. The metal-organic framework (MOF) MIL-101Cr was readily encapsulated by a very thin shell (around 30 nm) of hydrophobic mesoporous silica, which replicates the irregular shape of the MOF nanocrystals. Such a silica shell facilitates the diffusion of hydrophobic reactants with enhancement of the catalytic activity of the MOF and significantly improved catalytic stability of the MOF in the oxidation of indene.

AB - © 2018 American Chemical Society. The metal-organic framework (MOF) MIL-101Cr was readily encapsulated by a very thin shell (around 30 nm) of hydrophobic mesoporous silica, which replicates the irregular shape of the MOF nanocrystals. Such a silica shell facilitates the diffusion of hydrophobic reactants with enhancement of the catalytic activity of the MOF and significantly improved catalytic stability of the MOF in the oxidation of indene.

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Nanocoating of Hydrophobic Mesoporous Silica around MIL-101Cr for Enhanced Catalytic Activity and Stability

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