Modulating electronic interactions between closely spaced complementary p surfaces with different outcomes: Regio- and diastereomerically pure subphthalocyanine-C60 tris adducts

David Gonzalez-Rodriguez, Esther Carbonell Llopis, Dirk M. Guldi, Tomas Torres

Résultats de recherche: Contribution à un journal/une revueArticleRevue par des pairs

Résumé

Tightly coupled, regio- and diastereomerically pure subphthalocyanine- C60 dyads (see spacefilling depiction; B orange, C light blue, H gray, N blue, O red), tethered by means of a trisaddition reaction, can follow different mechanisms on photoexcitation (electron transfer or energy transfer), depending on the spacing between the two complementary π surfaces.

langue originaleAnglais
Pages (de - à)8032-8036
Nombre de pages5
journalAngewandte Chemie. International edition
Volume48
Numéro de publication43
Les DOIs
Etat de la publicationPublié - 12 oct. 2009
Modification externeOui

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