Mechanistic insights into aerobic oxidative cleavage of glycol catalyzed by an Anderson-type polyoxometalate [IMo₆O₂₄]⁵⁻

Chemistry

• Energetics 100%
• Polyoxometalate 100%
• Oxidative Elimination Reaction 100%
• Oxidation Reaction 50%
• Diol 50%
• Dioxygen 50%
• Oxygen Atom 50%
• Hydroxyl Group 50%
• Iodine Ion 50%
• Natural Bond Orbital 50%
• Hydrogen Atom 50%
• Acetonitrile 50%

Keyphrases

• Aerobic Oxidative Cleavage 100%
• Anderson-type Polyoxometalate 100%
• Heteropolyanion 50%
• WB97XD 25%
• C-C Bond Cleavage 25%
• Iodine Ion 25%
• Natural Bond Orbital 25%
• Anderson-type 25%
• Aerobic Oxidative 25%

INIS

• heteropolyanions 33%
• iodine ions 16%