Mechanism of the reaction of some organometallic compounds with α-enones

J. Lucchetti; A. Krief

Mechanism of the reaction of some organometallic compounds with α-enones

J. Lucchetti, A. Krief

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Résumé

The stereochemistry of the C-1 and C-3 adducts formed in the reaction of 1-metallo-1-selenopropionates with cyclohexenone is reported as well as the first evidence in favour of the occurrence of a dissociation into two independent species during the base-promoted isomerization of the C-1 to the C-3 adduct.

langue originale	Anglais
Pages (de - à)	127-128
Nombre de pages	2
journal	Journal of the Chemical Society, Chemical Communications
Numéro de publication	2
Etat de la publication	Publié - 1 janv. 1982

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title = "Mechanism of the reaction of some organometallic compounds with α-enones",

abstract = "The stereochemistry of the C-1 and C-3 adducts formed in the reaction of 1-metallo-1-selenopropionates with cyclohexenone is reported as well as the first evidence in favour of the occurrence of a dissociation into two independent species during the base-promoted isomerization of the C-1 to the C-3 adduct.",

author = "J. Lucchetti and A. Krief",

year = "1982",

month = jan,

day = "1",

language = "English",

pages = "127--128",

journal = "J. Chem. Soc.",

issn = "0022-4936",

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T1 - Mechanism of the reaction of some organometallic compounds with α-enones

AU - Lucchetti, J.

AU - Krief, A.

PY - 1982/1/1

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N2 - The stereochemistry of the C-1 and C-3 adducts formed in the reaction of 1-metallo-1-selenopropionates with cyclohexenone is reported as well as the first evidence in favour of the occurrence of a dissociation into two independent species during the base-promoted isomerization of the C-1 to the C-3 adduct.

AB - The stereochemistry of the C-1 and C-3 adducts formed in the reaction of 1-metallo-1-selenopropionates with cyclohexenone is reported as well as the first evidence in favour of the occurrence of a dissociation into two independent species during the base-promoted isomerization of the C-1 to the C-3 adduct.

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M3 - Article

AN - SCOPUS:37049107854

SN - 0022-4936

SP - 127

EP - 128

JO - J. Chem. Soc.

JF - J. Chem. Soc.

IS - 2

ER -

Mechanism of the reaction of some organometallic compounds with α-enones

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