Measurements of Ambipolar Seebeck Coefficients in High-Mobility Diketopyrrolopyrrole Donor–Acceptor Copolymers

Katharina Broch; Deepak Venkateshvaran; Vincent Lemaur; Yoann Olivier; David Beljonne; Mateusz Zelazny; Iyad Nasrallah; David J. Harkin; Martin Statz; Riccardo Di Pietro; Auke Jisk Kronemeijer; Henning Sirringhaus

doi:10.1002/aelm.201700225

Measurements of Ambipolar Seebeck Coefficients in High-Mobility Diketopyrrolopyrrole Donor–Acceptor Copolymers

Katharina Broch
, Deepak Venkateshvaran
, Vincent Lemaur
, Yoann Olivier
, David Beljonne
, Mateusz Zelazny
, Iyad Nasrallah
, David J. Harkin
, Martin Statz
, Riccardo Di Pietro
, Auke Jisk Kronemeijer
, Henning Sirringhaus

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

The Seebeck coefficient of both electrons and holes in a family of ambipolar diketopyrrolopyrrole copolymers is investigated using field-effect gated measurements. It is found that at high carrier concentrations the magnitude of the Seebeck coefficients is not strongly dependent on the molecular structure of the backbone within this family of polymers. Additionally, the Seebeck coefficients of electrons and holes have very similar magnitudes showing that electrons and holes experience a similar energetic landscape. Subtle differences in the carrier concentration dependence between the polymers are observed, which are interpreted in terms of different degrees of energetic disorder on the basis of molecular dynamics and electronic structure simulations.

langue originale	Anglais
Numéro d'article	1700225
journal	Advanced Electronic Materials
Volume	3
Numéro de publication	11
Les DOIs	https://doi.org/10.1002/aelm.201700225
Etat de la publication	Publié - 1 nov. 2017
Modification externe	Oui

Financement

The authors gratefully acknowledge financial support from the European Research Council (ERC) through a synergy grant (No. 610115) and the Engineering and Physical Sciences Research Council (EPSRC). The work in the Laboratory for Chemistry of Novel Materials was supported by the European Commission/R\u00E9gion Wallonne (FEDER \u2013 BIORGEL project), the Interuniversity Attraction Pole program of the Belgian Federal Science Policy Office (PAI 7/05), the Programme d\u2019Excellence de la R\u00E9gion Wallonne (OPTI2MAT project), the Consortium des \u00C9quipements de Calcul Intensif (C\u00C9CI), funded by the Fonds de la Recherche Scientifique de Belgique (F.R.S.-FNRS) under Grant No. 2.5020.11, and FRS-FNRS, the European Unions Horizon 2020 research and innovation program under Grant Agreement No. 646176 (EXTMOS project). D.B. is an FNRS Research Director. K.B. gratefully acknowledges financial support from the German Research Foundation (BR 4869/1-1) and the Institutional Strategy of the University of Tuebingen (Deutsche Forschungsgemeinschaft ZUK63).

Bailleurs de fonds	Numéro du bailleur de fonds
European Commission/Région Wallonne
European commission
Consortium des Équipements de Calcul Intensif
University of Tuebingen
Engineering and Physical Sciences Research Council
European Research Council
European Regional Development Fund
Horizon 2020
Fonds De La Recherche Scientifique - FNRS	2.5020.11
Belgian Science Policy Office	PAI 7/05
Seventh Framework Programme	610115
Deutsche Forschungsgemeinschaft	ZUK63, BR 4869/1-1
Horizon 2020 Framework Programme	646176

Accès au document

10.1002/aelm.201700225

Autres fichiers et liens

Link to publication in Scopus

Contient cette citation

Broch, K., Venkateshvaran, D., Lemaur, V., Olivier, Y., Beljonne, D., Zelazny, M., Nasrallah, I., Harkin, D. J., Statz, M., Pietro, R. D., Kronemeijer, A. J., & Sirringhaus, H. (2017). Measurements of Ambipolar Seebeck Coefficients in High-Mobility Diketopyrrolopyrrole Donor–Acceptor Copolymers. Advanced Electronic Materials, 3(11), Article 1700225. https://doi.org/10.1002/aelm.201700225

@article{b3f3544f073d467eac49b281d8337df7,

title = "Measurements of Ambipolar Seebeck Coefficients in High-Mobility Diketopyrrolopyrrole Donor–Acceptor Copolymers",

abstract = "The Seebeck coefficient of both electrons and holes in a family of ambipolar diketopyrrolopyrrole copolymers is investigated using field-effect gated measurements. It is found that at high carrier concentrations the magnitude of the Seebeck coefficients is not strongly dependent on the molecular structure of the backbone within this family of polymers. Additionally, the Seebeck coefficients of electrons and holes have very similar magnitudes showing that electrons and holes experience a similar energetic landscape. Subtle differences in the carrier concentration dependence between the polymers are observed, which are interpreted in terms of different degrees of energetic disorder on the basis of molecular dynamics and electronic structure simulations.",

keywords = "ambipolar transport, organic semiconductors, organic thermoelectrics, Seebeck coefficient",

author = "Katharina Broch and Deepak Venkateshvaran and Vincent Lemaur and Yoann Olivier and David Beljonne and Mateusz Zelazny and Iyad Nasrallah and Harkin, \{David J.\} and Martin Statz and Pietro, \{Riccardo Di\} and Kronemeijer, \{Auke Jisk\} and Henning Sirringhaus",

year = "2017",

month = nov,

day = "1",

doi = "10.1002/aelm.201700225",

language = "English",

volume = "3",

journal = "Advanced Electronic Materials",

publisher = "John Wiley and Sons Inc.",

number = "11",

}

Broch, K, Venkateshvaran, D, Lemaur, V, Olivier, Y, Beljonne, D, Zelazny, M, Nasrallah, I, Harkin, DJ, Statz, M, Pietro, RD, Kronemeijer, AJ & Sirringhaus, H 2017, 'Measurements of Ambipolar Seebeck Coefficients in High-Mobility Diketopyrrolopyrrole Donor–Acceptor Copolymers', Advanced Electronic Materials, VOL. 3, Numéro 11, 1700225. https://doi.org/10.1002/aelm.201700225

TY - JOUR

T1 - Measurements of Ambipolar Seebeck Coefficients in High-Mobility Diketopyrrolopyrrole Donor–Acceptor Copolymers

AU - Broch, Katharina

AU - Venkateshvaran, Deepak

AU - Lemaur, Vincent

AU - Olivier, Yoann

AU - Beljonne, David

AU - Zelazny, Mateusz

AU - Nasrallah, Iyad

AU - Harkin, David J.

AU - Statz, Martin

AU - Pietro, Riccardo Di

AU - Kronemeijer, Auke Jisk

AU - Sirringhaus, Henning

PY - 2017/11/1

Y1 - 2017/11/1

N2 - The Seebeck coefficient of both electrons and holes in a family of ambipolar diketopyrrolopyrrole copolymers is investigated using field-effect gated measurements. It is found that at high carrier concentrations the magnitude of the Seebeck coefficients is not strongly dependent on the molecular structure of the backbone within this family of polymers. Additionally, the Seebeck coefficients of electrons and holes have very similar magnitudes showing that electrons and holes experience a similar energetic landscape. Subtle differences in the carrier concentration dependence between the polymers are observed, which are interpreted in terms of different degrees of energetic disorder on the basis of molecular dynamics and electronic structure simulations.

AB - The Seebeck coefficient of both electrons and holes in a family of ambipolar diketopyrrolopyrrole copolymers is investigated using field-effect gated measurements. It is found that at high carrier concentrations the magnitude of the Seebeck coefficients is not strongly dependent on the molecular structure of the backbone within this family of polymers. Additionally, the Seebeck coefficients of electrons and holes have very similar magnitudes showing that electrons and holes experience a similar energetic landscape. Subtle differences in the carrier concentration dependence between the polymers are observed, which are interpreted in terms of different degrees of energetic disorder on the basis of molecular dynamics and electronic structure simulations.

KW - ambipolar transport

KW - organic semiconductors

KW - organic thermoelectrics

KW - Seebeck coefficient

UR - https://www.scopus.com/pages/publications/85028017682

U2 - 10.1002/aelm.201700225

DO - 10.1002/aelm.201700225

M3 - Article

AN - SCOPUS:85028017682

VL - 3

JO - Advanced Electronic Materials

JF - Advanced Electronic Materials

IS - 11

M1 - 1700225

ER -

Measurements of Ambipolar Seebeck Coefficients in High-Mobility Diketopyrrolopyrrole Donor–Acceptor Copolymers

Résumé

Financement

Accès au document

Autres fichiers et liens

Empreinte digitale

Contient cette citation