"Magic" surface clustering of borazines driven by repulsive intermolecular forces

Simon Kervyn De Meerendre, Nataliya Kalashnyk, Massimo Riello, Ben Moreton, Jonathan Tasseroul, Johan Wouters, Tim S. Jones, Alessandro De Vita, Giovanni Costantini, Davide Bonifazi

Résultats de recherche: Contribution à un journal/une revueArticle

Résumé

It's a kind of magic: Hydroxy pentaaryl borazine molecules self-assemble into small clusters (see structure) on Cu(111) surfaces, whereas with symmetric hexaaryl borazine molecules large islands are obtained. Simulations indicate that the observed "magic" cluster sizes result from long-range repulsive Coulomb forces arising from the deprotonation of the B-OH groups of the hydroxy pentaaryl borazine.

langue originaleAnglais
Pages (de - à)7410-7414
Nombre de pages5
journalAngewandte Chemie. International edition
Volume52
Numéro de publication29
Les DOIs
étatPublié - 15 juil. 2013

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Deprotonation
Molecules
borazine

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Kervyn De Meerendre, Simon ; Kalashnyk, Nataliya ; Riello, Massimo ; Moreton, Ben ; Tasseroul, Jonathan ; Wouters, Johan ; Jones, Tim S. ; De Vita, Alessandro ; Costantini, Giovanni ; Bonifazi, Davide. / "Magic" surface clustering of borazines driven by repulsive intermolecular forces. Dans: Angewandte Chemie. International edition. 2013 ; Vol 52, Numéro 29. p. 7410-7414.
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"Magic" surface clustering of borazines driven by repulsive intermolecular forces. / Kervyn De Meerendre, Simon; Kalashnyk, Nataliya; Riello, Massimo; Moreton, Ben; Tasseroul, Jonathan; Wouters, Johan; Jones, Tim S.; De Vita, Alessandro; Costantini, Giovanni; Bonifazi, Davide.

Dans: Angewandte Chemie. International edition, Vol 52, Numéro 29, 15.07.2013, p. 7410-7414.

Résultats de recherche: Contribution à un journal/une revueArticle

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