"Magic" surface clustering of borazines driven by repulsive intermolecular forces

Simon Kervyn De Meerendre; Nataliya Kalashnyk; Massimo Riello; Ben Moreton; Jonathan Tasseroul; Johan Wouters; Tim S. Jones; Alessandro De Vita; Giovanni Costantini; Davide Bonifazi

doi:10.1002/anie.201300948

"Magic" surface clustering of borazines driven by repulsive intermolecular forces

Simon Kervyn De Meerendre, Nataliya Kalashnyk, Massimo Riello, Ben Moreton, Jonathan Tasseroul, Johan Wouters, Tim S. Jones, Alessandro De Vita, Giovanni Costantini, Davide Bonifazi

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

It's a kind of magic: Hydroxy pentaaryl borazine molecules self-assemble into small clusters (see structure) on Cu(111) surfaces, whereas with symmetric hexaaryl borazine molecules large islands are obtained. Simulations indicate that the observed "magic" cluster sizes result from long-range repulsive Coulomb forces arising from the deprotonation of the B-OH groups of the hydroxy pentaaryl borazine.

langue originale	Anglais
Pages (de - à)	7410-7414
Nombre de pages	5
journal	Angewandte Chemie. International edition
Volume	52
Numéro de publication	29
Les DOIs	https://doi.org/10.1002/anie.201300948
Etat de la publication	Publié - 15 juil. 2013

Accès au document

10.1002/anie.201300948

Autres fichiers et liens

Link to publication in Scopus

Physico-chimie et caractérisation (PC2)
Wouters, J. (!!Manager), Aprile, C. (!!Manager) & Fusaro, L. (!!Manager)
Plateforme technologique Caracterisation physico-chimiques
Equipement/installations: Plateforme technolgique

CCDC 897051: Experimental Crystal Structure Determination
Kervyn, S. (Contributeur), Kalashnyk, N. (Contributeur), Riello, M. (Contributeur), Moreton, B. (Contributeur), Tasseroul, J. (Contributeur), Wouters, J. (Contributeur), Jones, T. S. (Contributeur), De Vita, A. (Contributeur), Costantini, G. (Contributeur) & Bonifazi, D. (Contributeur), Cambridge Crystallographic Data Centre, 1 janv. 2013
DOI: 10.5517/ccz3g4n, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccz3g4n&sid=DataCite
Ensemble de données

Synthesis of Boron and Nitrogen-doped pi-Conjugated Carbon Nanostructures
Tasseroul, J. (Auteur)Bonifazi, D. (Promoteur), avr. 2016
Student thesis: Doc types › Docteur en Sciences

Contient cette citation

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title = "{"}Magic{"} surface clustering of borazines driven by repulsive intermolecular forces",

abstract = "It's a kind of magic: Hydroxy pentaaryl borazine molecules self-assemble into small clusters (see structure) on Cu(111) surfaces, whereas with symmetric hexaaryl borazine molecules large islands are obtained. Simulations indicate that the observed {"}magic{"} cluster sizes result from long-range repulsive Coulomb forces arising from the deprotonation of the B-OH groups of the hydroxy pentaaryl borazine.",

keywords = "borazine, scanning tunneling microscopy, self-assembly, supramolecular chemistry",

author = "{Kervyn De Meerendre}, Simon and Nataliya Kalashnyk and Massimo Riello and Ben Moreton and Jonathan Tasseroul and Johan Wouters and Jones, {Tim S.} and {De Vita}, Alessandro and Giovanni Costantini and Davide Bonifazi",

year = "2013",

month = jul,

day = "15",

doi = "10.1002/anie.201300948",

language = "English",

volume = "52",

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journal = "Angewandte Chemie. International edition",

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T1 - "Magic" surface clustering of borazines driven by repulsive intermolecular forces

AU - Kervyn De Meerendre, Simon

AU - Kalashnyk, Nataliya

AU - Riello, Massimo

AU - Moreton, Ben

AU - Tasseroul, Jonathan

AU - Wouters, Johan

AU - Jones, Tim S.

AU - De Vita, Alessandro

AU - Costantini, Giovanni

AU - Bonifazi, Davide

PY - 2013/7/15

Y1 - 2013/7/15

N2 - It's a kind of magic: Hydroxy pentaaryl borazine molecules self-assemble into small clusters (see structure) on Cu(111) surfaces, whereas with symmetric hexaaryl borazine molecules large islands are obtained. Simulations indicate that the observed "magic" cluster sizes result from long-range repulsive Coulomb forces arising from the deprotonation of the B-OH groups of the hydroxy pentaaryl borazine.

AB - It's a kind of magic: Hydroxy pentaaryl borazine molecules self-assemble into small clusters (see structure) on Cu(111) surfaces, whereas with symmetric hexaaryl borazine molecules large islands are obtained. Simulations indicate that the observed "magic" cluster sizes result from long-range repulsive Coulomb forces arising from the deprotonation of the B-OH groups of the hydroxy pentaaryl borazine.

KW - borazine

KW - scanning tunneling microscopy

KW - self-assembly

KW - supramolecular chemistry

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U2 - 10.1002/anie.201300948

DO - 10.1002/anie.201300948

M3 - Article

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JO - Angewandte Chemie. International edition

JF - Angewandte Chemie. International edition

IS - 29

ER -

"Magic" surface clustering of borazines driven by repulsive intermolecular forces

Résumé

Accès au document

Autres fichiers et liens

Empreinte digitale

Équipement

Physico-chimie et caractérisation (PC2)

Ensembles de données

CCDC 897051: Experimental Crystal Structure Determination

Thèses de l'étudiant

Synthesis of Boron and Nitrogen-doped pi-Conjugated Carbon Nanostructures

Contient cette citation