Innovative in Situ Ball Mill for X-ray Diffraction

Voraksmy Ban, Yolanda Sadikin, Michael Lange, Nikolay Tumanov, Yaroslav Filinchuk, Radovan Černý, Nicola Casati

Résultats de recherche: Contribution à un journal/une revueArticle

Résumé

The renewed interest of mechanochemistry as an ecofriendly synthetic route has inspired original methodologies to probe reactions, with the aim to rationalize unknown mechanisms. Recently, Friščić et al. (Nat. Chem. 2013, 5, 66-73, DOI: 10.1038/nchem.1505) monitored the progress of milling reactions by synchrotron X-ray powder diffraction (XRPD). For the first time, it was possible to acquire directly information during a mechanochemical process. This new methodology is still in its early stages, and its development will definitively transform the fundamental understanding of mechanochemistry. A new type of in situ ball mill setup has been developed at the Materials Science beamline (Swiss Light Source, Paul Scherrer Institute, Switzerland). Its particular geometry, described here in detail, results in XRPD data displaying significantly lower background and much sharper Bragg peaks, which in turn allow more sophisticated analysis of mechanochemical processes, extending the limits of the technique.

langue originaleAnglais
Pages (de - à)13176-13181
Nombre de pages6
journalAnalytical Chemistry
Volume89
Numéro de publication24
Les DOIs
étatPublié - 19 déc. 2017

Empreinte digitale

Ball mills
X ray powder diffraction
X ray diffraction
Materials science
Synchrotrons
Light sources
Geometry

Citer ceci

Ban, V., Sadikin, Y., Lange, M., Tumanov, N., Filinchuk, Y., Černý, R., & Casati, N. (2017). Innovative in Situ Ball Mill for X-ray Diffraction. Analytical Chemistry, 89(24), 13176-13181. https://doi.org/10.1021/acs.analchem.7b02871
Ban, Voraksmy ; Sadikin, Yolanda ; Lange, Michael ; Tumanov, Nikolay ; Filinchuk, Yaroslav ; Černý, Radovan ; Casati, Nicola. / Innovative in Situ Ball Mill for X-ray Diffraction. Dans: Analytical Chemistry. 2017 ; Vol 89, Numéro 24. p. 13176-13181.
@article{259602600e194fffadfa31e2dd47cb31,
title = "Innovative in Situ Ball Mill for X-ray Diffraction",
abstract = "The renewed interest of mechanochemistry as an ecofriendly synthetic route has inspired original methodologies to probe reactions, with the aim to rationalize unknown mechanisms. Recently, Friščić et al. (Nat. Chem. 2013, 5, 66-73, DOI: 10.1038/nchem.1505) monitored the progress of milling reactions by synchrotron X-ray powder diffraction (XRPD). For the first time, it was possible to acquire directly information during a mechanochemical process. This new methodology is still in its early stages, and its development will definitively transform the fundamental understanding of mechanochemistry. A new type of in situ ball mill setup has been developed at the Materials Science beamline (Swiss Light Source, Paul Scherrer Institute, Switzerland). Its particular geometry, described here in detail, results in XRPD data displaying significantly lower background and much sharper Bragg peaks, which in turn allow more sophisticated analysis of mechanochemical processes, extending the limits of the technique.",
author = "Voraksmy Ban and Yolanda Sadikin and Michael Lange and Nikolay Tumanov and Yaroslav Filinchuk and Radovan Čern{\'y} and Nicola Casati",
year = "2017",
month = "12",
day = "19",
doi = "10.1021/acs.analchem.7b02871",
language = "English",
volume = "89",
pages = "13176--13181",
journal = "Analytical Chemistry",
issn = "0003-2700",
publisher = "American Chemical Society",
number = "24",

}

Ban, V, Sadikin, Y, Lange, M, Tumanov, N, Filinchuk, Y, Černý, R & Casati, N 2017, 'Innovative in Situ Ball Mill for X-ray Diffraction', Analytical Chemistry, VOL. 89, Numéro 24, p. 13176-13181. https://doi.org/10.1021/acs.analchem.7b02871

Innovative in Situ Ball Mill for X-ray Diffraction. / Ban, Voraksmy; Sadikin, Yolanda; Lange, Michael; Tumanov, Nikolay; Filinchuk, Yaroslav; Černý, Radovan; Casati, Nicola.

Dans: Analytical Chemistry, Vol 89, Numéro 24, 19.12.2017, p. 13176-13181.

Résultats de recherche: Contribution à un journal/une revueArticle

TY - JOUR

T1 - Innovative in Situ Ball Mill for X-ray Diffraction

AU - Ban, Voraksmy

AU - Sadikin, Yolanda

AU - Lange, Michael

AU - Tumanov, Nikolay

AU - Filinchuk, Yaroslav

AU - Černý, Radovan

AU - Casati, Nicola

PY - 2017/12/19

Y1 - 2017/12/19

N2 - The renewed interest of mechanochemistry as an ecofriendly synthetic route has inspired original methodologies to probe reactions, with the aim to rationalize unknown mechanisms. Recently, Friščić et al. (Nat. Chem. 2013, 5, 66-73, DOI: 10.1038/nchem.1505) monitored the progress of milling reactions by synchrotron X-ray powder diffraction (XRPD). For the first time, it was possible to acquire directly information during a mechanochemical process. This new methodology is still in its early stages, and its development will definitively transform the fundamental understanding of mechanochemistry. A new type of in situ ball mill setup has been developed at the Materials Science beamline (Swiss Light Source, Paul Scherrer Institute, Switzerland). Its particular geometry, described here in detail, results in XRPD data displaying significantly lower background and much sharper Bragg peaks, which in turn allow more sophisticated analysis of mechanochemical processes, extending the limits of the technique.

AB - The renewed interest of mechanochemistry as an ecofriendly synthetic route has inspired original methodologies to probe reactions, with the aim to rationalize unknown mechanisms. Recently, Friščić et al. (Nat. Chem. 2013, 5, 66-73, DOI: 10.1038/nchem.1505) monitored the progress of milling reactions by synchrotron X-ray powder diffraction (XRPD). For the first time, it was possible to acquire directly information during a mechanochemical process. This new methodology is still in its early stages, and its development will definitively transform the fundamental understanding of mechanochemistry. A new type of in situ ball mill setup has been developed at the Materials Science beamline (Swiss Light Source, Paul Scherrer Institute, Switzerland). Its particular geometry, described here in detail, results in XRPD data displaying significantly lower background and much sharper Bragg peaks, which in turn allow more sophisticated analysis of mechanochemical processes, extending the limits of the technique.

UR - http://www.scopus.com/inward/record.url?scp=85038863660&partnerID=8YFLogxK

U2 - 10.1021/acs.analchem.7b02871

DO - 10.1021/acs.analchem.7b02871

M3 - Article

AN - SCOPUS:85038863660

VL - 89

SP - 13176

EP - 13181

JO - Analytical Chemistry

JF - Analytical Chemistry

SN - 0003-2700

IS - 24

ER -

Ban V, Sadikin Y, Lange M, Tumanov N, Filinchuk Y, Černý R et al. Innovative in Situ Ball Mill for X-ray Diffraction. Analytical Chemistry. 2017 déc. 19;89(24):13176-13181. https://doi.org/10.1021/acs.analchem.7b02871