Hierarchically Dual-Mesoporous TiO2 Microspheres for Enhanced Photocatalytic Properties and Lithium Storage

Sa Xiao, Yi Lu, Xin Li, Bing Yu Xiao, Liang Wu, Jian Ping Song, Yu Xuan Xiao, Si Ming Wu, Jie Hu, Yong Wang, Gang Gang Chang, Ge Tian, Silvia Lenaerts, Christoph Janiak, Xiao Yu Yang, Bao Lian Su

Résultats de recherche: Contribution à un journal/une revueArticle

Résumé

Hierarchically dual-mesoporous TiO2 microspheres have been synthesized by a solvothermal process in the presence of 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm][BF4]) and diethylenetriamine (DETA) as co-templates. Secondary mesostructured defects in the hierarchical TiO2 microspheres produce oxygen vacancies, which not only significantly enhance photocatalytic activity in the degradation of methylene blue (1.7 times that with P25) and acetone (2.9 times that with P25), but are also beneficial for lithium storage. Moreover, we propose a mechanism to rationalize the role of this dual mesoporosity of the TiO2 microspheres in enhancing molecular diffusion, ion transportation, and electronic transitions.

langue originaleAnglais
Pages (de - à)13246-13252
Nombre de pages7
journalChemistry - A European Journal
Volume24
Numéro de publication50
Les DOIs
Etat de la publicationPublié - 6 sept. 2018

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