Gas-phase ultraviolet photoelectron spectroscopic study of the 3,7-diphenyl- and 3,7-bis(dimethylamino)-1,5-dithia-2,4,6,8-tetrazocines

Jean-Pol BOUTIQUE, Roberto LAZZARONI, Joseph Riga, Jacques Verbist, [No Value] PFISTER-GUILLOUZO, Joseph Delhalle, Joseph Fripiat, [No Value] HADDON, [No Value] KAPLAN

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    Résumé

    The HeI and HeII photoelectron spectra of 3,7-diphenyl-and 3,7-bis(dimethylamino)-1,5-dithia-2,4,6,8-tetrazocines are reported. Experimental results are in qualitative agreement with previously reported STO-3G and STO-3G + 5D calculations. An analysis of the spectral features confirms the predicted difference in the nature of the HOMO for the two compounds.
    langue originaleAnglais
    Pages (de - à)259-262
    Nombre de pages4
    journalJournal of the Chemical Society. Perkin Transactions 2
    Numéro de publication3
    Les DOIs
    Etat de la publicationPublié - 1987

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