Full assignment of the 1H NMR spectrum of heteroleptic polyazaaromatic Ru(II) complexes based on long-range interligand NOEs.

Epiphanie Mugeniwabagara; Luca Fusaro; Michel. Luhmer

doi:10.1002/mrc.3931

Full assignment of the 1H NMR spectrum of heteroleptic polyazaaromatic Ru(II) complexes based on long-range interligand NOEs.

Epiphanie Mugeniwabagara, Luca Fusaro, Michel. Luhmer

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Résumé

Chem. equivalence in sym. polyazaarom. ligands is not necessarily retained in the corresponding heteroleptic Ru(II) complexes, and the assignment of the 1H NMR spectrum of these octahedral metallic compds. is therefore not straightforward. Full assignment of [Ru(L)2(L')]2+ (L, L' = sym. polyazaarom. bidentate ligands) can be achieved from long-range interligand NOE measurements. Copyright © 2013 John Wiley and Sons, Ltd. [on SciFinder(R)]

langue originale	Anglais
Pages (de - à)	308-311
Nombre de pages	4
journal	Magnetic Resonance in Chemistry
Volume	51
Numéro de publication	5
Les DOIs	https://doi.org/10.1002/mrc.3931
Etat de la publication	Publié - 2013
Modification externe	Oui

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title = "Full assignment of the 1H NMR spectrum of heteroleptic polyazaaromatic Ru(II) complexes based on long-range interligand NOEs.",

abstract = "Chem. equivalence in sym. polyazaarom. ligands is not necessarily retained in the corresponding heteroleptic Ru(II) complexes, and the assignment of the 1H NMR spectrum of these octahedral metallic compds. is therefore not straightforward. Full assignment of [Ru(L)2(L')]2+ (L, L' = sym. polyazaarom. bidentate ligands) can be achieved from long-range interligand NOE measurements. Copyright {\textcopyright} 2013 John Wiley and Sons, Ltd. [on SciFinder(R)]",

keywords = "proton NMR heteroleptic polyazaarom ruthenium complex long range NOE, heteroleptic phenanthroline tetraazaphenanthrene hexaazatriphenylene ruthenium complex proton NMR NOE",

author = "Epiphanie Mugeniwabagara and Luca Fusaro and Michel. Luhmer",

year = "2013",

doi = "10.1002/mrc.3931",

language = "English",

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journal = "Magnetic Resonance in Chemistry",

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T1 - Full assignment of the 1H NMR spectrum of heteroleptic polyazaaromatic Ru(II) complexes based on long-range interligand NOEs.

AU - Mugeniwabagara, Epiphanie

AU - Fusaro, Luca

AU - Luhmer, Michel.

PY - 2013

Y1 - 2013

N2 - Chem. equivalence in sym. polyazaarom. ligands is not necessarily retained in the corresponding heteroleptic Ru(II) complexes, and the assignment of the 1H NMR spectrum of these octahedral metallic compds. is therefore not straightforward. Full assignment of [Ru(L)2(L')]2+ (L, L' = sym. polyazaarom. bidentate ligands) can be achieved from long-range interligand NOE measurements. Copyright © 2013 John Wiley and Sons, Ltd. [on SciFinder(R)]

AB - Chem. equivalence in sym. polyazaarom. ligands is not necessarily retained in the corresponding heteroleptic Ru(II) complexes, and the assignment of the 1H NMR spectrum of these octahedral metallic compds. is therefore not straightforward. Full assignment of [Ru(L)2(L')]2+ (L, L' = sym. polyazaarom. bidentate ligands) can be achieved from long-range interligand NOE measurements. Copyright © 2013 John Wiley and Sons, Ltd. [on SciFinder(R)]

KW - proton NMR heteroleptic polyazaarom ruthenium complex long range NOE

KW - heteroleptic phenanthroline tetraazaphenanthrene hexaazatriphenylene ruthenium complex proton NMR NOE

U2 - 10.1002/mrc.3931

DO - 10.1002/mrc.3931

M3 - Article

SN - 0749-1581

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SP - 308

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JO - Magnetic Resonance in Chemistry

JF - Magnetic Resonance in Chemistry

IS - 5

ER -

Full assignment of the 1H NMR spectrum of heteroleptic polyazaaromatic Ru(II) complexes based on long-range interligand NOEs.

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