First structurally characterized self-assembly of bipodal N-thiophosphorylated bis-thiourea with CoII: Magnetic properties and thermal decomposition

Damir A. Safin; Maria G. Babashkina; Antoine P. Railliet; Nikolay A. Tumanov; Koen Robeyns; Eamonn Devlin; Yiannis Sanakis; Yaroslav Filinchuk; Yann Garcia

doi:10.1039/c3dt50254f

First structurally characterized self-assembly of bipodal N-thiophosphorylated bis-thiourea with Co^II: Magnetic properties and thermal decomposition

Damir A. Safin, Maria G. Babashkina, Antoine P. Railliet, Nikolay A. Tumanov, Koen Robeyns, Eamonn Devlin, Yiannis Sanakis, Yaroslav Filinchuk, Yann Garcia

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

Résumé

Reaction of piperazine with isothiocyanate (iPrO)₂P(S)NCS leads to N-thiophosphorylated bis-thiourea (iPrO)₂P(S)NHC(S)NC ₄H₈NC(S)NHP(S)(OiPr)₂ (H₂L). Recrystallization of H₂L from DMSO leads to the formation of the new ligand (iPrO)₂P(S)NC₄H₈NP(S)(OiPr)₂ (1). Reaction of doubly deprotonated L with Co^II leads to the [Co₂L₂] complex. The thermal properties of [Co ₂L₂] in an air atmosphere were studied by means of TGA with the observed final residue corresponding to [CoPS₃]₂. The crystal structure of [Co₂L₂] was elucidated by single crystal X-ray diffraction. Two metal cations are in a tetrahedral 1,5-S ₂S′₂ environment formed by the CS and PS sulfur atoms. Investigation of the temperature dependence of the magnetic susceptibility is consistent with two effectively non-interacting Co ^II S = 3/2 ions.

langue originale	Anglais
Pages (de - à)	5532-5538
Nombre de pages	7
journal	Dalton Transactions
Volume	42
Numéro de publication	15
Les DOIs	https://doi.org/10.1039/c3dt50254f
Etat de la publication	Publié - 21 avr. 2013
Modification externe	Oui

Accès au document

10.1039/c3dt50254f

Autres fichiers et liens

Link to publication in Scopus

CCDC 911408: Experimental Crystal Structure Determination
Babashkina, M. G. (Contributeur), Devlin, E. (Contributeur), Filinchuk, Y. (Contributeur), Garcia, Y. (Contributeur), Railliet, A. P. (Contributeur), Robeyns, K. (Contributeur), Safin, D. A. (Contributeur), Sanakis, Y. (Contributeur) & Tumanov, N. (Contributeur), Cambridge Crystallographic Data Centre, 1 janv. 2013
DOI: 10.5517/cczld86, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cczld86&sid=DataCite
Ensemble de données
CCDC 911409: Experimental Crystal Structure Determination
Babashkina, M. G. (Contributeur), Devlin, E. (Contributeur), Filinchuk, Y. (Contributeur), Garcia, Y. (Contributeur), Railliet, A. P. (Contributeur), Robeyns, K. (Contributeur), Safin, D. A. (Contributeur), Sanakis, Y. (Contributeur) & Tumanov, N. (Contributeur), Cambridge Crystallographic Data Centre, 1 janv. 2013
DOI: 10.5517/cczld97, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cczld97&sid=DataCite
Ensemble de données
CCDC 911407: Experimental Crystal Structure Determination
Babashkina, M. G. (Contributeur), Devlin, E. (Contributeur), Filinchuk, Y. (Contributeur), Garcia, Y. (Contributeur), Railliet, A. P. (Contributeur), Robeyns, K. (Contributeur), Safin, D. A. (Contributeur), Sanakis, Y. (Contributeur) & Tumanov, N. (Contributeur), Cambridge Crystallographic Data Centre, 1 janv. 2013
DOI: 10.5517/cczld75, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cczld75&sid=DataCite
Ensemble de données

Contient cette citation

@article{8fd3d7a128074f138e3bf004ebcffe14,

title = "First structurally characterized self-assembly of bipodal N-thiophosphorylated bis-thiourea with CoII: Magnetic properties and thermal decomposition",

abstract = "Reaction of piperazine with isothiocyanate (iPrO)2P(S)NCS leads to N-thiophosphorylated bis-thiourea (iPrO)2P(S)NHC(S)NC 4H8NC(S)NHP(S)(OiPr)2 (H2L). Recrystallization of H2L from DMSO leads to the formation of the new ligand (iPrO)2P(S)NC4H8NP(S)(OiPr)2 (1). Reaction of doubly deprotonated L with CoII leads to the [Co2L2] complex. The thermal properties of [Co 2L2] in an air atmosphere were studied by means of TGA with the observed final residue corresponding to [CoPS3]2. The crystal structure of [Co2L2] was elucidated by single crystal X-ray diffraction. Two metal cations are in a tetrahedral 1,5-S 2S′2 environment formed by the CS and PS sulfur atoms. Investigation of the temperature dependence of the magnetic susceptibility is consistent with two effectively non-interacting Co II S = 3/2 ions.",

author = "Safin, {Damir A.} and Babashkina, {Maria G.} and Railliet, {Antoine P.} and Tumanov, {Nikolay A.} and Koen Robeyns and Eamonn Devlin and Yiannis Sanakis and Yaroslav Filinchuk and Yann Garcia",

year = "2013",

month = apr,

day = "21",

doi = "10.1039/c3dt50254f",

language = "English",

volume = "42",

pages = "5532--5538",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "15",

}

First structurally characterized self-assembly of bipodal N-thiophosphorylated bis-thiourea with Co^II: Magnetic properties and thermal decomposition. / Safin, Damir A.; Babashkina, Maria G.; Railliet, Antoine P. et al.
Dans: Dalton Transactions, Vol 42, Numéro 15, 21.04.2013, p. 5532-5538.

Résultats de recherche: Contribution à un journal/une revue › Article › Revue par des pairs

TY - JOUR

T1 - First structurally characterized self-assembly of bipodal N-thiophosphorylated bis-thiourea with CoII

T2 - Magnetic properties and thermal decomposition

AU - Safin, Damir A.

AU - Babashkina, Maria G.

AU - Railliet, Antoine P.

AU - Tumanov, Nikolay A.

AU - Robeyns, Koen

AU - Devlin, Eamonn

AU - Sanakis, Yiannis

AU - Filinchuk, Yaroslav

AU - Garcia, Yann

PY - 2013/4/21

Y1 - 2013/4/21

N2 - Reaction of piperazine with isothiocyanate (iPrO)2P(S)NCS leads to N-thiophosphorylated bis-thiourea (iPrO)2P(S)NHC(S)NC 4H8NC(S)NHP(S)(OiPr)2 (H2L). Recrystallization of H2L from DMSO leads to the formation of the new ligand (iPrO)2P(S)NC4H8NP(S)(OiPr)2 (1). Reaction of doubly deprotonated L with CoII leads to the [Co2L2] complex. The thermal properties of [Co 2L2] in an air atmosphere were studied by means of TGA with the observed final residue corresponding to [CoPS3]2. The crystal structure of [Co2L2] was elucidated by single crystal X-ray diffraction. Two metal cations are in a tetrahedral 1,5-S 2S′2 environment formed by the CS and PS sulfur atoms. Investigation of the temperature dependence of the magnetic susceptibility is consistent with two effectively non-interacting Co II S = 3/2 ions.

AB - Reaction of piperazine with isothiocyanate (iPrO)2P(S)NCS leads to N-thiophosphorylated bis-thiourea (iPrO)2P(S)NHC(S)NC 4H8NC(S)NHP(S)(OiPr)2 (H2L). Recrystallization of H2L from DMSO leads to the formation of the new ligand (iPrO)2P(S)NC4H8NP(S)(OiPr)2 (1). Reaction of doubly deprotonated L with CoII leads to the [Co2L2] complex. The thermal properties of [Co 2L2] in an air atmosphere were studied by means of TGA with the observed final residue corresponding to [CoPS3]2. The crystal structure of [Co2L2] was elucidated by single crystal X-ray diffraction. Two metal cations are in a tetrahedral 1,5-S 2S′2 environment formed by the CS and PS sulfur atoms. Investigation of the temperature dependence of the magnetic susceptibility is consistent with two effectively non-interacting Co II S = 3/2 ions.

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DO - 10.1039/c3dt50254f

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First structurally characterized self-assembly of bipodal N-thiophosphorylated bis-thiourea with CoII: Magnetic properties and thermal decomposition

Résumé

Accès au document

Autres fichiers et liens

Empreinte digitale

Ensembles de données

CCDC 911408: Experimental Crystal Structure Determination

CCDC 911409: Experimental Crystal Structure Determination

CCDC 911407: Experimental Crystal Structure Determination

Contient cette citation

First structurally characterized self-assembly of bipodal N-thiophosphorylated bis-thiourea with Co^II: Magnetic properties and thermal decomposition